OMB APPROVAL OMB Number: 3235-0570 Expires: November 30, 2005 Estimated average burden hours per response..... 5.0 UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM N-CSR CERTIFIED SHAREHOLDER REPORT OF REGISTERED MANAGEMENT INVESTMENT COMPANIES 		Investment Company Act file number 811-07611 Pioneer Value Fund (Exact name of registrant as specified in charter) 60 State Street, Boston, MA 02109 (Address of principal executive offices) (ZIP code) Dorothy E. Bourassa, Pioneer Investment Management, Inc., 60 State Street, Boston, MA 02109 (Name and address of agent for service) Registrant's telephone number, including area code: (617) 742-7825 Date of fiscal year end: September 30 Date of reporting period: October 1, 2004 through September 30, 2005 Form N-CSR is to be used by management investment companies to file reports with the Commission not later than 10 days after the transmission to stockholders of any report that is required to be transmitted to stockholders under Rule 30e-1 under the Investment Company Act of 1940 (17 CFR 270.30e-1). The Commission may use the information provided on Form N-CSR in its regulatory, disclosure review, inspection, and policymaking roles. A registrant is required to disclose the information specified by Form N-CSR, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-CSR unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. ss. 3507. ITEM 1. REPORTS TO SHAREOWNERS. - -------------------------------------------------------------------------------- PIONEER ----------------------- VALUE FUND Annual Report 9/30/05 [Logo] PIONEER Investments(R) Table of Contents - -------------------------------------------------------------------------------- Letter to Shareowners 1 Portfolio Summary 2 Prices and Distributions 3 Performance Update 4 Comparing Ongoing Fund Expenses 10 Portfolio Management Discussion 12 Schedule of Investments 15 Financial Statements 22 Notes to Financial Statements 32 Report of Independent Registered Public Accounting Firm 42 Trustees, Officers and Service Providers 43 Pioneer Value Fund - -------------------------------------------------------------------------------- LETTER TO SHAREOWNERS 9/30/05 - -------------------------------------------------------------------------------- Dear Shareowner, - -------------------------------------------------------------------------------- Questions about the economic outlook moved from theoretical to real when Hurricanes Katrina and Rita wreaked devastation on people and property across much of the Gulf Coast. Before the storms struck, the economy had been motoring forward, with strong profit growth and good jobs numbers being reported across a range of sectors. Despite ten straight hikes by the Federal Reserve Board, interest rates were at tolerable levels, and businesses and households were managing to live with rising energy costs. The Fed raised rates again in September, suggesting continued concern that inflationary fires are merely banked, not extinguished. The stimulative effect of massive recovery spending may have been a factor in the Fed's decision. Damage to many Gulf area facilities may also keep oil and gasoline supplies tight and restrain GDP growth for a time. By late in the third quarter, energy prices had backed off peak levels, but remained high enough to prompt worries over their impact on consumers and the economy in general. Consumers are key to the economy's direction. The national savings rate stands near zero, leaving households with little financial slack to continue absorbing punishing prices at the pump and in their heating and utility bills; confidence understandably sagged after the storms. However, U.S. consumers are notably resilient. If conditions in the job market rebound from storm-induced disruptions, their behavior seems unlikely to change very much. Barring surprises, the hurricanes have not undercut our favorable expectations for the rest of the year. We believe carefully selected, high-quality stocks and bonds still show potential for solid results even in a slower-growth environment. With that in mind, our global investment experts are well positioned to seek attractive opportunities around the world. Another Fund Group Joins the Pioneer Family Pioneer Investment Management recently completed the acquisition of AmSouth Bancorporation's mutual fund management business. This transaction, our fifth in two years, adds seven new funds to our lineup and expands assets under management by over $5 billion. Transactions such as these increase our ability to offer competitively priced products to our shareholders and other investors through the services of their financial advisors. Please consider the Fund's investment objectives, risks, charges and expenses. Contact your advisor or Pioneer investments for a prospectus containing this information. Please read the information carefully. Respectfully, /s/ Osbert M. Hood Osbert M. Hood, President Pioneer Investment Management, Inc. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of the opinion of Fund management as of the date of this report. These statements should not be relied upon for any other purposes. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. 1 Pioneer Value Fund - -------------------------------------------------------------------------------- PORTFOLIO SUMMARY 9/30/05 - -------------------------------------------------------------------------------- Portfolio Diversification - -------------------------------------------------------------------------------- (As a percentage of total investment portfolio) [The following was represented as a pie chart in the printed materials.] U.S. Common Stocks 89.2% International Common Stocks 0.5% Depositary Receipts for International Stocks 2.9% Temporary Cash Investments 7.4% Sector Distribution - -------------------------------------------------------------------------------- (As a percentage of equity holdings) [The following was represented as a pie chart in the printed materials.] Materials 3.3% Telecommunication Services 5.8% Consumer Staples 5.9% Utilities 6.4% Industrials 7.2% Health Care 8.5% Consumer Discretionary 8.9% Information Technology 9.6% Energy 20.2% Financials 24.2% 10 Largest Holdings - -------------------------------------------------------------------------------- (As a percentage of equity holdings)* 1. Citigroup, Inc. 4.01% 6. Bank of America Corp. 2.88% 2. Altria Group, Inc. 3.75 7. Tyco International, Ltd. 2.87 3. ConocoPhillips 3.66 8. American International 2.59 Group, Inc. 4. Merrill Lynch & Co., Inc. 3.20 9. First Data Corp. 2.55 5. Exxon Mobil Corp. 3.15 10. Cardinal Health, Inc. 2.48 * This list excludes temporary cash and derivative instruments. The Portfolio is actively managed, and current holdings may be different. 2 Pioneer Value Fund - -------------------------------------------------------------------------------- PRICES AND DISTRIBUTIONS - -------------------------------------------------------------------------------- Net Asset Value Per Share Class 9/30/05 9/30/04 - ------- --------- -------- A $17.55 $18.83 B $16.40 $17.87 C $16.39 $17.87 R $17.10 $18.64 Y $17.59 $18.84 Class 9/30/05 12/11/04 - ----------------- --------- ----------- Investor Class Shares $17.57 $17.30 Distributions Per Share - -------------------------------------------------------------------------------- 10/1/04 - 9/30/05 ------------------------------------------- Net Investment Short-Term Long-Term Class Income Capital Gains Capital Gains - --------------------------------------------------- A $ 0.116 $0.425 $3.1323 B $ - $0.425 $3.1323 C $ - $0.425 $3.1323 R $ - $0.425 $3.1323 Y $0.1808 $0.425 $3.1323 12/11/04 - 9/30/05 ------------------------------------------- Net Investment Short-Term Long-Term Class Income Capital Gains Capital Gains - ---------------------------------------------------------------------- Investor Class Shares $ 0.070 $ 0.170 $ 0.790 - -------------------------------------------------------------------------------- INDEX DEFINITIONS - -------------------------------------------------------------------------------- The Russell 1000 Value Index measures the performance of large-cap U.S. value stocks. Index returns assume reinvestment of dividends and, unlike Fund returns, do not reflect any fees, expenses or sales charges. You cannot invest directly in an index. The index defined here pertains to the Value of $10,000 Investment charts on pages 4-9. 3 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 CLASS A SHARES Investment Returns - -------------------------------------------------------------------------------- The mountain chart below shows the change in value of a $10,000 investment made in Pioneer Value Fund at public offering price, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2005) Public Net Asset Offering Period Value (NAV) Price (POP) 10 Years 7.24% 7.24% 5 Years 4.43 3.20 1 Year 13.81 7.26 [The following was represented as a mountain chart in the printed materials.] Value of $10,000 Investment Pioneer Russell 1000 Value Fund Value Index 9/95 9425 10000 11223 11795 9/97 16381 16785 12455 17389 9/99 13932 20644 16203 22484 9/01 14765 20480 12287 17009 9/03 15105 21154 17680 25494 9/05 20121 29748 Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. NAV results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. POP returns reflect deduction of maximum 5.75% sales charge. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 4 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 CLASS B SHARES - -------------------------------------------------------------------------------- Investment Returns - -------------------------------------------------------------------------------- The mountain chart below shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2005) If If Period Held Redeemed Life-of-Class (7/1/96) 5.56% 5.56% 5 Years 3.26 3.26 1 Year 12.66 8.99 [The following was represented as a mountain chart in the printed materials.] Value of $10,000 Investment Pioneer Russell 1000 Value Fund Value Index 7/96 10000 10000 10926 10695 9/97 15797 15220 11886 15767 9/99 13149 18719 15097 20387 9/01 13611 18571 11205 15423 9/03 13570 19181 15735 23117 9/05 17727 26974 Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. "If Redeemed" returns reflect the deduction of applicable contingent deferred sales charge (CSDC). Effective December 1, 2004, the period during which a CDSC is applied to withdrawals was shortened to 5 years. The maximum CDSC for class B shares continues to be 4%. For more complete information, please see the prospectus for details. Note: Shares purchased prior to December 1, 2004 remain subject to the CDSC in effect at the time you purchased those shares. For performance information for shares purchased prior to December 1, 2004, please visit www.pioneerfunds.com/bshares. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 5 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 CLASS C SHARES - -------------------------------------------------------------------------------- Investment Returns - -------------------------------------------------------------------------------- The mountain chart below shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2005) If If Period Held Redeemed Life-of-Class (7/1/96) 5.55% 5.55% 5 Years 3.23 3.23 1 Year 12.60 12.60 [The following was represented as a mountain chart in the printed materials.] Value of $10,000 Investment Pioneer Russell 1000 Value Fund Value Index 7/96 10000 10000 9/96 10921 10695 15781 15220 9/98 11897 15767 9/99 13166 18719 15119 20387 9/01 13610 18571 11190 15423 9/03 13607 19181 15737 23117 9/05 17721 26974 Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Class C shares held for less than one year are also subject to a 1% contingent deferred sales charge (CDSC). The performance of Class C shares does not reflect the 1% front-end sales charge in effect prior to February 1, 2004. If you paid a 1% sales charge, your returns would be lower than those shown above. "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 6 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 INVESTOR CLASS SHARES - -------------------------------------------------------------------------------- Investment Returns - -------------------------------------------------------------------------------- Average Annual Total Returns (As of September 30, 2005) If If Period Held Redeemed Life-of-Class (12/11/04) 7.54% 7.54% Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Certain Pioneer funds (the "Funds") issued Investor Class shares in connection with the reorganization of Safeco mutual funds. The Funds are not offering additional Investor Class shares except in connection with the reinvestment of dividends on the Funds' outstanding Investor Class shares. All Investor Class shares of the Funds, whenever issued, convert to Class A shares of their respective Funds on December 10, 2006. Investor Class shares are not subject to sales charges. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table does not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 7 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 CLASS R SHARES - -------------------------------------------------------------------------------- Investment Returns - -------------------------------------------------------------------------------- The mountain chart below shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2005) If If Period Held Redeemed 10 Years 6.49% 6.49% 5 Years 3.50 3.50 1 Year 11.65 11.65 [The following was represented as a mountain chart in the printed materials.] Value of a $10,000 Investment Pioneer Russell 1000 Value Fund Value Index 9/95 10000 10000 11159 11795 9/97 16203 16785 12264 17389 9/99 13645 20644 15793 22484 9/01 14323 20480 11854 17009 9/03 14528 21154 16800 25494 9/05 18757 29748 Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. The performance of Class R shares for the period prior to the commencement of operations of Class R shares on 4/1/03 is based on the performance of Class A shares, reduced to reflect the higher distribution and service fees of Class R shares. For the period after April 1, 2003, the actual performance of Class R shares is reflected, which performance may be influenced by the smaller asset size of Class R shares compared to Class A shares. The performance of Class R shares does not reflect the 1% CDSC that was in effect prior to July 1, 2004. Class R shares are not subject to sales charges and are available for limited groups of investors. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 8 Pioneer Value Fund - -------------------------------------------------------------------------------- PERFORMANCE UPDATE 9/30/05 CLASS Y SHARES - -------------------------------------------------------------------------------- Investment Returns - -------------------------------------------------------------------------------- The mountain chart below shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2005) If If Period Held Redeemed 10 Years 7.30% 7.30% 5 Years 4.55 4.55 1 Year 14.40 14.40 [The following was represented as a mountain chart in the printed materials.] Value of a $10,000 Investment Pioneer Russell 1000 Value Fund Value Index 9/95 10000 10000 11218 11795 9/97 16373 16785 12449 17389 9/99 13926 20644 16195 22484 9/01 14757 20480 12281 17009 9/03 15098 21154 17680 25494 9/05 20226 29748 Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Performance for periods prior to the inception of Y shares reflects the NAV performance of the Fund's A shares. The performance does not reflect differences in expenses, including the Rule 12b-1 fees applicable to Class A shares. Since fees for Class A shares are generally higher than those of Class Y shares, the performance shown for Y shares prior to their inception (8/11/04) would have been higher. Class Y shares are not subject to sales charges and are available for limited groups of eligible investors, including institutional investors. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 9 Pioneer Value Fund - -------------------------------------------------------------------------------- COMPARING ONGOING FUND EXPENSES - -------------------------------------------------------------------------------- As a shareowner in the Fund, you incur two types of costs: (1) ongoing costs, including management fees, distribution and/or service (12b-1) fees, and other Fund expenses; and (2) transaction costs, including sales charges (loads) on purchase payments. This example is intended to help you understand your ongoing expenses (in dollars) of investing in the Fund and to compare these costs with the ongoing costs of investing in other mutual funds. The example is based on an investment of $1,000 at the beginning of the Fund's latest six-month period and held throughout the six months. Using the Tables Actual Expenses The first table below provides information about actual account values and actual expenses. You may use the information in this table, together with the amount you invested, to estimate the expenses that you paid over the period as follows: 1. Divide your account value by $1,000 Example: an $8,600 account value - $1,000 = 8.6 2. Multiply the result in (1) above by the corresponding share class's number in the third row under the heading entitled "Expenses Paid During Period" to estimate the expenses you paid on your account during this period. Expenses Paid on a $1,000 Investment in Pioneer Value Fund Based on actual returns from April 1, 2005 through September 30, 2005 Share Class A B C I R Y - ------------------------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 $1,000.00 $1,000.00 $1,000.00 Value On 4/1/05 Ending Account $1,061.56 $1,056.15 $1,056.09 $1,049.38 $1,050.13 $1,063.89 Value On 9/30/05 Expenses Paid $ 5.01 $ 10.45 $ 10.53 $ 6.23 $ 18.44 $ 3.04 During Period* * Expenses are equal to the Fund's annualized expense ratio of 0.98%, 2.03%, 2.08%, 3.05%, 0.59% and 0.75% for Class A, Class B, Class C, Class R, Class Y and Class I, respectively, multiplied by the average account value over the period, multiplied by 182/365 (to reflect the one-half year period). 10 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Hypothetical Example for Comparison Purposes The table below provides information about hypothetical account values and hypothetical expenses based on the Fund's actual expense ratio and an assumed rate of return of 5% per year before expenses, which is not the Fund's actual return. The hypothetical account values and expenses may not be used to estimate the actual ending account balance or expenses you paid for the period. You may use this information to compare the ongoing costs of investing in the Fund and other funds. To do so, compare this 5% hypothetical example with the 5% hypothetical examples that appear in the shareholder reports of the other funds. Please note that the expenses shown in the tables are meant to highlight your ongoing costs only and do not reflect any transaction costs, such as sales charges (loads) that are charged at the time of the transaction. Therefore, the table below is useful in comparing ongoing costs only and will not help you determine the relative total costs of owning different funds. In addition, if these transaction costs were included, your costs would have been higher. Expenses Paid on a $1,000 Investment in Pioneer Value Fund Based on a hypothetical 5% per year return before expenses, reflecting the period from April 1, 2005 through September 30, 2005 Share Class A B C I R Y - -------------------------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 $1,000.00 $1,000.00 $1,000.00 Value On 4/1/05 Ending Account $1,020.17 $1,014.87 $1,014.65 $1,021.32 $1,009.76 $1,022.11 Value On 9/30/05 Expenses Paid $ 4.91 $ 10.24 $ 10.32 $ 6.14 $ 18.08 $ 2.97 During Period* * Expenses are equal to the Fund's annualized expense ratio of 0.98%, 2.03%, 2.08%, 3.05%, 0.59% and 0.75% for Class A, Class B, Class C, Class R, Class Y and Class I, respectively, multiplied by the average account value over the period, multiplied by 182/365 (to reflect the one-half year period). 11 Pioneer Value Fund - -------------------------------------------------------------------------------- PORTFOLIO MANAGEMENT DISCUSSION 9/30/05 - -------------------------------------------------------------------------------- U.S. equity markets peaked last spring, then stalled as the high cost of energy and rising interest rates gave investors pause. Large-cap value stocks once again led large-cap growth issues, as measured by Russell's 1000 Value and 1000 Growth Indexes, respectively. In the following discussion, Rod Wright, lead portfolio manager and strategy director of Pioneer's value team, and portfolio manager Aaron Clark review the market and the economy and describe the factors that affected the Fund's performance for this 12-month period. Q: Please describe the investment background over the last 12 months. A: For the first half of this period, stocks trended higher despite fast-rising energy costs and repeated hikes in interest rates. But the market lost steam last spring when it became clear that the Federal Reserve Board was determined to keep inflation at bay through further rate increases and that energy prices weren't about to retreat. For the rest of the period, investors have been assessing the possible impact of these macroeconomic forces on corporate earnings and consumer spending patterns, resulting in directionless equity markets, often reacting reflexively to short-term movements in energy prices. As is often the case during periods of uncertainty, value stocks delivered better results than more volatile growth issues. Q: How did Pioneer Value Fund perform against that background? A: For the 12 months ended September 30, 2005, Pioneer Value Fund's Class A shares had a total return at net asset value of 13.81%. This figure lagged the 16.69% return of the Russell 1000 Value Index, the Fund's benchmark, for the same period. During the 12-month period, the average return of the 443 funds in Lipper's large-cap value category was 13.36%. Call 1-800-225-6292 or visit www.pioneerfunds.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. 12 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Q: Which of your decisions or strategies had a positive impact on performance? A: Continuing increases in oil and gas prices made the energy sector the period's number one performer and boosted several Fund holdings. Among them were independent producer Devon Energy, Conoco Phillips, an integrated energy company, and Suncor, which needs high prices to extract oil profitably from petroleum-rich shale. But holding an underweight position in ExxonMobil at a time of rising prices tempered sector results. Shares of London-based Vodafone, a global operator of mobile phone networks, rose as wireless telephony continues to take business from wireline phones. Our avoidance of the slumping Regional Bell Companies also helped relative returns. In technology, Symantec's announced acquisition of Veritas Software provided a performance boost. And Finland's Nokia, a leading manufacturer of mobile telephones, has made a strong turnaround following a period of disappointments. In health care, shares of IVAX, a maker of generic medications, rose when Israel's Teva Pharmaceutical announced plans to acquire it. Shares of Cardinal Health continued to rise following our opportunistic purchase. Cardinal, which operates chiefly as a middleman between drug companies and healthcare providers, has prospered under a revised business model that removes the risks of holding costly inventory. Q: Which of the Fund's positions held back results? A: Our benchmark's strong performance was fueled in part by high-yielding issues. Because income generation is not a primary mandate for the Fund, we were underweighted among utilities, the period's second-best sector and one known for traditionally high yields. Performance suffered as a result. We were correctly positioned with an underweight stance - compared to our benchmark - in the weak financial services sector, but unsuccessful stock selection offset that advantage. Insurance broker Marsh McLennan dropped abruptly when New York State's Attorney General brought charges of bid-rigging and other improprieties; rather than await uncertain legal developments, we took a loss in the position. The cloudy insurance outlook also pressured shares of Berkshire Hathaway, which has many commitments in that industry. Regulatory questions also hung over Freddie Mac, the Federal Home Loan Mortgage Corporation. Lackluster 13 Pioneer Value Fund - -------------------------------------------------------------------------------- PORTFOLIO MANAGEMENT DISCUSSION 9/30/05 (continued) - -------------------------------------------------------------------------------- performance at First Data Corporation, a processor of credit card transactions, hurt comparative results. Results among materials companies benefited from our not owning chemical giants Dow Chemical and DuPont. However, failure to own Monsanto was a negative, as shares rose. Tyco, an industrial conglomerate and long-time Fund holding, slumped after failing to meet management's forecasts. Tyco appears attractively positioned for the future, and we are retaining the Fund's position. Q: What is your outlook for the economy and for value stocks? A: While undeniably devastating, the Gulf hurricanes will have, we think, only temporary economic repercussions. In the short term, construction, machinery and other industries involved in the massive rebuilding effort will benefit. Taking a longer view, although energy prices were declining as the period ended, they are significantly higher than a year ago; high energy prices often foreshadow a cooling economy. The long string of interest rate hikes also points to slowing growth, as does evidence of inflation that is popping up in many areas. Consumer spending constitutes the bulk of U.S. economic activity. High energy prices and rising interest rates are bound to have an impact on household outlays over the next few quarters, especially given prevailing low rates of saving. Other imponderables include the policies that the new head of the Federal Reserve Board will pursue. More positively, many corporations are in good financial shape to continue hiring and current interest rates appear manageable. We are positioning the Fund cautiously given our concerns, but we believe growth will continue at a more moderate pace. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making it more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. Investing in foreign and/or emerging markets securities involves risks relating to interest rates, currency exchange rates, economic, and political conditions. These risks may increase share price volatility. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of the opinion of Fund management as of the date of this report. These statements should not be relied upon for any other purposes. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. 14 Pioneer Value Fund - -------------------------------------------------------------------------------- SCHEDULE OF INVESTMENTS 9/30/05 - -------------------------------------------------------------------------------- Shares Value COMMON STOCKS - 94.1% Energy - 17.9% Integrated Oil & Gas - 11.4% 1,487,000 Chevron Corp. $ 96,253,510 2,214,170 ConocoPhillips 154,792,625 2,092,912 Exxon Mobil Corp. 132,983,628 1,024,400 Occidental Petroleum Corp. 87,514,492 700,000 Suncor Energy, Inc. 42,371,000 -------------- $ 513,915,255 -------------- Oil & Gas Drilling - 2.1% 775,000 ENSCO International, Inc. $ 36,107,250 405,000 Nabors Industries, Inc.* 29,091,150 450,000 Transocean Offshore Inc.* 27,589,500 -------------- $ 92,787,900 -------------- Oil & Gas Equipment & Services - 0.6% 354,000 Halliburton Co.* $ 24,256,080 -------------- Oil & Gas Exploration & Production - 3.8% 630,000 Apache Corp. $ 47,388,600 400,000 Anadarko Petroleum Corp. 38,300,000 1,265,000 Devon Energy Corp. 86,829,600 -------------- $ 172,518,200 -------------- Total Energy $ 803,477,435 -------------- Materials - 4.1% Diversified Metals & Mining - 1.2% 1,125,000 Freeport-McMoRan Copper & Gold, Inc. (Class B) $ 54,663,750 -------------- Forest Products - 1.2% 775,500 Weyerhaeuser Co. $ 53,315,625 -------------- Industrial Gases - 1.1% 1,072,800 Praxair, Inc. $ 51,419,304 -------------- Metal & Glass Containers - 0.6% 720,600 Ball Corp. $ 26,474,844 -------------- Total Materials $ 185,873,523 -------------- The accompanying notes are an integral part of these financial statements. 15 Pioneer Value Fund - -------------------------------------------------------------------------------- SCHEDULE OF INVESTMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- Shares Value Capital Goods - 6.1% Aerospace & Defense - 1.2% 1,078,600 United Technologies Corp. $ 55,914,624 -------------- Construction & Farm Machinery & Heavy Trucks - 2.2% 1,616,000 Deere & Co. $ 98,899,200 -------------- Industrial Conglomerates - 2.7% 4,354,400 Tyco International, Ltd. $ 121,270,040 -------------- Total Capital Goods $ 276,083,864 -------------- Transportation - 0.6% Air Freight & Couriers - 0.6% 410,600 United Parcel Service $ 28,384,778 -------------- Total Transportation $ 28,384,778 -------------- Media - 7.6% Broadcasting & Cable TV - 4.1% 3,022,800 Clear Channel Communications, Inc. $ 99,419,892 2,875,000 Comcast Corp.* 84,467,500 -------------- $ 183,887,392 -------------- Movies & Entertainment - 3.5% 5,100,000 Time Warner, Inc. $ 92,361,000 1,956,000 Viacom, Inc. (Class B) 64,567,560 -------------- $ 156,928,560 -------------- Total Media $ 340,815,952 -------------- Retailing - 0.8% Specialty Stores - 0.8% 1,700,000 Foot Locker, Inc. $ 37,298,000 -------------- Total Retailing $ 37,298,000 -------------- Food, Beverage & Tobacco - 5.6% Soft Drinks - 2.1% 974,900 The Coca-Cola Co. $ 42,105,931 870,000 PepsiCo, Inc. 49,337,700 -------------- $ 91,443,631 -------------- Tobacco - 3.5% 2,150,000 Altria Group, Inc. $ 158,476,500 -------------- Total Food, Beverage & Tobacco $ 249,920,131 -------------- 16 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Shares Value Health Care Equipment & Services - 5.5% Health Care Distributors - 2.3% 1,650,000 Cardinal Health, Inc. $ 104,676,000 -------------- Health Care Equipment - 0.7% 1,395,000 Boston Scientific Corp.* $ 32,601,150 -------------- Health Care Facilities - 2.0% 802,200 HCA, Inc. $ 38,441,424 4,500,000 Tenet Healthcare Corp.* 50,535,000 -------------- $ 88,976,424 -------------- Managed Health Care - 0.5% 259,200 Wellpoint, Inc.* $ 19,652,544 -------------- Total Health Care Equipment & Services $ 245,906,118 -------------- Pharmaceuticals & Biotechnology - 2.6% Pharmaceuticals - 2.6% 1,600,000 Bristol-Myers Squibb Co. $ 38,496,000 1,950,000 Schering-Plough Corp. 41,047,500 766,000 Wyeth 35,442,820 -------------- $ 114,986,320 -------------- Total Pharmaceuticals & Biotechnology $ 114,986,320 -------------- Banks - 3.9% Diversified Banks - 3.9% 2,887,800 Bank of America Corp. $ 121,576,380 1,146,000 Wachovia Corp. 54,538,140 -------------- $ 176,114,520 -------------- Total Banks $ 176,114,520 -------------- Diversified Financials - 13.5% Asset Management & Custody Banks - 1.3% 2,098,900 The Bank of New York Co., Inc. $ 61,728,649 -------------- Consumer Finance - 1.9% 4,600,000 Providian Financial Corp.* $ 81,328,000 -------------- The accompanying notes are an integral part of these financial statements. 17 Pioneer Value Fund - -------------------------------------------------------------------------------- SCHEDULE OF INVESTMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- Shares Value Investment Banking & Brokerage - 6.5% 813,000 Goldman Sachs Group, Inc. (b) $ 98,844,540 500,000 Lehman Brothers Holdings, Inc. 58,240,000 2,203,000 Merrill Lynch & Co., Inc. 135,154,050 -------------- $ 292,238,590 -------------- Diversified Financial Services - 3.8% 3,723,600 Citigroup, Inc. $ 169,498,272 -------------- Total Diversified Financials $ 604,793,511 -------------- Insurance - 5.4% Life & Health Insurance - 1.2% 2,575,000 UNUM Corp. (b) $ 52,787,500 -------------- Multi-Line Insurance - 2.4% 1,767,000 American International Group, Inc. $ 109,483,320 -------------- Property & Casualty Insurance - 1.8% 1,430,000 Allstate Corp. $ 79,064,700 -------------- Total Insurance $ 241,335,520 -------------- Software & Services - 6.3% Data Processing & Outsourced Services - 2.4% 2,700,000 First Data Corp. $ 108,000,000 -------------- IT Consulting & Other Services - 1.0% 1,800,000 Accenture, Ltd.* $ 45,828,000 -------------- Systems Software - 2.9% 3,086,600 Microsoft Corp. $ 79,418,218 2,251,596 Symantec Corp.* 51,021,165 -------------- $ 130,439,383 -------------- Total Software & Services $ 284,267,383 -------------- Technology Hardware & Equipment - 2.7% Communications Equipment - 1.8% 1,450,000 Motorola, Inc. $ 32,030,500 2,835,000 Nokia Corp. (A.D.R.) 47,939,850 -------------- $ 79,970,350 -------------- Computer Hardware - 0.9% 1,481,500 Hewlett-Packard Co. $ 43,259,800 -------------- Total Technology Hardware & Equipment $ 123,230,150 -------------- 18 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Shares Value Telecommunication Services - 5.5% Integrated Telecommunication Services - 4.0% 600,000 Alltel Corp. $ 39,066,000 2,391,600 BellSouth Corp. 62,899,080 3,303,359 Sprint Nextel Corp.* 78,553,877 -------------- $ 180,518,957 -------------- Wireless Telecommunication Services - 1.5% 1,765,000 Vodafone Group Plc (A.D.R.) $ 45,837,050 8,000,000 Vodafone Group Plc 20,793,391 -------------- $ 66,630,441 -------------- Total Telecommunication Services $ 247,149,398 -------------- Utilities - 6.0% Electric Utilities - 4.0% 484,000 Dominion Resources, Inc. $ 41,691,760 1,100,000 Edison International 52,008,000 464,800 Entergy Corp. 34,543,936 957,400 Exelon Corp. 51,163,456 -------------- $ 179,407,152 -------------- Independent Power Producer & Energy Traders - 2.0% 259,200 Constellation Energy Group $ 15,966,720 650,000 TXU Corp. 73,372,000 -------------- $ 89,338,720 -------------- Total Utilities $ 268,745,872 -------------- TOTAL COMMON STOCKS (Cost $3,424,214,254) $4,228,382,475 -------------- The accompanying notes are an integral part of these financial statements. 19 Pioneer Value Fund - -------------------------------------------------------------------------------- SCHEDULE OF INVESTMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- Principal Amount Value TEMPORARY CASH INVESTMENTS - 7.5% Repurchase Agreement - 5.6% $250,000,000 UBS Warburg, Inc., 3.25%, dated 9/30/05, repurchase price of $250,000,000 plus accrued interest on 10/3/05 collateralized by $56,817,000 U.S Treasury Note, 3.375%, 2/28/07 and $190,510,000 U.S. Treasury Note, 6.125%, 8/15/07 $ 250,000,000 Shares Time Deposits - 1.9% 16,815,489 Bank of Nova Scotia $ 16,815,489 7,053,478 Bank of Scotland 7,053,478 18,809,272 BNP Paribas 18,809,272 18,809,272 Dresdner Bank AG 18,809,272 25,392,518 Rabobank Nederland N.V. 25,392,518 -------------- $ 86,880,029 -------------- TOTAL TEMPORARY CASH INVESTMENTS (Cost $336,880,029) $ 336,880,029 -------------- TOTAL INVESTMENTS IN SECURITIES - 101.6% (Cost $3,761,094,272) $4,565,262,504 -------------- OTHER ASSETS AND LIABILITIES - (1.6)% $ (70,370,121) -------------- TOTAL NET ASSETS - 100.0% $4,494,892,383 ============== (A.D.R.) American Depositary Receipt * Non-Income producing security (a) At September 30, 2005, the net unrealized gain on investments for federal income tax puposes of $3,772,524,521 was as follows Aggregate gross unrealized gain for all investments in which there is an excess of value over tax cost $854,416,797 ------------ Aggregate gross unrealized loss for all investments in which there is an excess of tax cost over value (61,678,814) ------------ Net unrealized gain $792,737,983 ============ 20 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- (b) At September 31, 2005, the following securities were out on loan: Shares Security Market Value 289,132 Eastman Kodak, Inc. (c) $ 7,034,582 300,000 Goldman Sachs Group, Inc. 36,474,000 2,035,241 UNUM Corp. 41,722,441 ----------- Total $85,231,023 =========== (c) Pending sale at 9/30/05 Purchases and sales of securities (excluding temporary cash investments) for the year ended September 30, 2005 aggregated $2,109,877,987 and $2,571,573,809, respectively. The accompanying notes are an integral part of these financial statements. 21 Pioneer Value Fund - -------------------------------------------------------------------------------- STATEMENT OF ASSETS AND LIABILITIES 9/30/05 - -------------------------------------------------------------------------------- ASSETS: Investment in securities (including securities loaned of $85,231,023) (cost $3,761,094,272) $4,565,262,504 Cash 28,732,162 Receivables - Investment securities sold 139,036,613 Fund shares sold 1,739,846 Dividends, interest and foreign taxes withheld 5,985,545 Other 65,646 -------------- Total assets $4,740,822,316 -------------- LIABILITIES: Payables - Investment securities purchased $ 154,371,931 Fund shares repurchased 3,232,929 Upon return of securities loaned 86,880,029 Due to affiliates 990,891 Accrued expenses 454,153 -------------- Total liabilities $ 245,929,933 -------------- NET ASSETS: Paid-in capital $3,668,949,171 Undistributed net investment income 22,048,959 Accumulated net realized gain on investments and foreign currency transactions (273,979) Net unrealized gain on investments 804,168,232 -------------- Total net assets $4,494,892,383 ============== NET ASSET VALUE PER SHARE: (Unlimited number of shares authorized) Class A (based on $3,997,849,173/227,763,026 shares) $ 17.55 ============== Class B (based on $51,163,741/3,119,200 shares) $ 16.40 ============== Class C (based on $8,926,224/544,644 shares) $ 16.39 ============== Investor Class (based on $125,647,019/7,151,014 shares) $ 17.57 ============== Class R (based on $34,045/1,991 shares) $ 17.10 ============== Class Y (based on $311,272,181/17,692,908 shares) $ 17.59 ============== MAXIMUM OFFERING PRICE: Class A ($17.55 [divided by] 94.25%) $ 18.62 ============== 22 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- STATEMENT OF OPERATIONS - -------------------------------------------------------------------------------- For the Year Ended 9/30/05 INVESTMENT INCOME: Dividends (net of foreign taxes withheld of $292,590) $ 71,851,824 Interest 1,697,522 Income from securities loaned, net 139,835 ------------ Total investment income $ 73,689,181 ------------ EXPENSES: Management fees Basic Fee $ 24,158,168 Performance Adjustment (2,848,006) Transfer agent fees and expenses Class A 6,469,789 Class B 138,925 Class C 45,989 Investor Class 181,454 Class R 473 Class Y 644 Distribution fees Class A 9,088,382 Class B 303,278 Class C 91,514 Class R 119 Administrative reimbursements 782,002 Custodian fees 141,297 Registration fees 103,595 Professional fees 202,249 Printing expense 398,068 Fees and expenses of nonaffiliated trustees 81,127 Miscellaneous 111,215 ------------ Total expenses $ 39,450,282 Less fees paid indirectly (94,446) ------------ Net expenses $ 39,355,836 ------------ Net investment income $ 34,333,345 ------------ REALIZED AND UNREALIZED GAIN (LOSS) ON INVESTMENTS AND FOREIGN CURRENCY TRANSACTIONS: Net realized gain on: Investments $364,851,453 Other assets and liabilities denominated in foreign currencies 220,678 $365,072,131 ------------ ------------ Change in net unrealized gain (loss) on: Investments $120,247,329 Other assets and liabilities denominated in foreign currencies (4,270) $120,243,059 ------------ ------------ Net gain on investments and foreign currency transactions $485,315,190 ------------ Net increase in net assets resulting from operations $519,648,535 ============ The accompanying notes are an integral part of these financial statements. 23 Pioneer Value Fund - ----------------------------------------------------------------------------- STATEMENTS OF CHANGES IN NET ASSETS - ----------------------------------------------------------------------------- For the Years Ended 9/30/05 and 9/30/04 Year Ended Year Ended 9/30/05 9/30/04 FROM OPERATIONS: Net investment income $ 34,333,345 $ 26,854,247 Net realized gain on investments and futures contracts 365,072,131 410,577,522 Change in net unrealized gain on investments 120,243,059 142,427,737 -------------- --------------- Net increase in net assets resulting from operations $ 519,648,535 $ 579,859,506 -------------- --------------- DISTRIBUTIONS TO SHAREOWNERS: Net investment income: Class A ($0.12 and $0.14 per share, respectively) $ (25,577,281) $ (28,499,251) Investor Class ($0.07 and $0.00 per share, respectively) (494,415) - Class R ($0.00 and $0.09 per share, respectively) - (18) Class Y ($0.18 and $0.00 per share, respectively) (88,697) - Net realized gain: Class A ($3.56 and $0.04 per share, respectively) $ (712,796,982) $ (8,442,480) Class B ($3.56 and $0.04 per share, respectively) (5,912,060) (57,538) Class C ($3.56 and $0.04 per share, respectively) (1,766,558) (17,230) Investor Class ($0.96 and $0.00 per share, respectively) (6,586,748) - Class R ($3.56 and $0.04 per share, respectively) (3,431) (1) Class Y ($3.56 and $0.00 per share, respectively) (1,279,809) - -------------- --------------- Total distributions to shareowners $ (754,505,981) $ (37,016,518) -------------- --------------- FROM FUND SHARE TRANSACTIONS: Net proceeds from sale of shares $ 188,636,084 $ 154,313,837 Shares issued in reorganization 567,020,957 - Reinvestment of distributions 705,941,513 33,639,128 Cost of shares repurchased (521,289,250) (394,332,655) -------------- --------------- Net increase (decrease) in net assets resulting from Fund share transactions $ 940,309,304 $(206,379,690) -------------- --------------- Net increase in net assets $ 705,451,859 $ 336,463,298 NET ASSETS: Beginning of year 3,789,440,524 3,452,977,226 -------------- --------------- End of year (including undistributed net investment income of $22,048,959 and $13,655,329 respectively) $4,494,892,383 $3,789,440,524 ============== ============== 24 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- STATEMENTS OF CHANGES IN NET ASSETS - -------------------------------------------------------------------------------- CLASS A '05 Shares '05 Amount '04 Shares '04 Amount Shares sold 9,244,764 $ 164,906,907 7,254,846 $ 132,850,875 Shares issued in reorganization 6,351,296 110,131,470 Reinvestment of distributions 39,775,790 691,163,792 1,882,875 33,571,800 Less shares repurchased (26,554,629) (476,508,621) (20,956,950) (383,611,951) ----------- -------------- ----------- -------------- Net increase (decrease) 28,817,221 $ 489,693,548 (11,819,229) $ (217,189,276) =========== ============== =========== ============== CLASS B Shares sold 338,605 $ 5,696,208 821,981 $ 14,282,504 Shares issued in reorganization 1,481,298 24,011,839 Reinvestment of distributions 329,840 5,377,266 3,250 52,391 Less shares repurchased (845,504) (14,304,832) (412,570) (7,199,035) ----------- -------------- ----------- -------------- Net increase 1,304,239 $ 20,780,481 412,661 $ 7,135,860 =========== ============== =========== ============== CLASS C Shares sold 144,059 $ 2,414,742 304,266 $ 5,316,476 Reinvestment of distributions 93,738 1,527,246 924 14,922 Less shares repurchased (206,212) (3,491,263) (202,030) 3,518,368 ----------- -------------- ----------- -------------- Net increase 31,585 $ 450,725 103,160 $ 8,849,766 =========== ============== =========== ============== INVESTOR CLASS Shares sold 7,745 $ 134,553 Shares issued in reorganization 7,975,352 137,973,598 Reinvestment of distributions 370,664 6,503,458 Less shares repurchased (1,202,747) (21,250,235) ----------- -------------- Net increase 7,151,014 $ 123,361,374 =========== ============== CLASS R Shares sold 1,614 $ 28,279 620 $ 11,646 Reinvestment of distributions 193 3,302 1 15 Less shares repurchased (355) (6,169) (118) (2,174) ----------- -------------- ----------- -------------- Net increase 1,452 $ 25,412 503 $ 9,487 =========== ============== =========== ============== CLASS Y Shares sold 863,316 $ 15,455,395 99,435 $ 1,852,336 Shares issued in reorganization 16,968,012 294,904,050 Reinvestment of distributions 78,254 1,366,449 - - Less shares repurchased (316,049) (5,728,130) (60) (1,127) ----------- -------------- ----------- -------------- Net increase 17,593,533 $ 305,997,764 99,375 $ 1,851,209 =========== ============== =========== ============== The accompanying notes are an integral part of these financial statements. 25 Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- Year Ended Year Ended CLASS A 9/30/05 9/30/04 Net asset value, beginning of period $ 18.83 $ 16.25 ---------- ---------- Increase (decrease) from investment operations: Net investment income $ 0.14 $ 0.14 Net realized and unrealized gain (loss) on investments and foreign currency transactions 2.26 2.62 ---------- ---------- Net increase (decrease) from investment operations $ 2.40 $ 2.76 Distributions to shareowners: Net investment income (0.12) (0.14) Net realized loss (3.56) (0.04) ---------- ---------- Net increase (decrease) in net asset value $ (1.28) $ 2.58 ---------- ---------- Net asset value, end of period $ 17.55 $ 18.83 ========== ========== Total return* 13.81% 17.04% Ratio of net expenses to average net assets+ 0.98% 1.02% Ratio of net investment income to average net assets+ 0.85% 0.72% Portfolio turnover rate 53% 40% Net assets, end of period (in thousands) $3,997,849 $3,745,950 Ratios assuming reduction for fees paid indirectly: Net expenses 0.97% 1.02% Net investment income 0.86% 0.72% Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- Year Ended Year Ended Year Ended CLASS A 9/30/03 9/30/02 9/30/01 Net asset value, beginning of period $ 15.29 $ 19.12 $ 22.67 ---------- --------- --------- Increase (decrease) from investment operations: Net investment income $ 0.11 $ 0.15 $ 0.17 Net realized and unrealized gain (loss) on investments and foreign currency transactions 3.20 (3.17) (2.05) ---------- --------- --------- Net increase (decrease) from investment operations $ 3.31 $ (3.02) $ (1.88) Distributions to shareowners: Net investment income (0.24) (0.09) (0.14) Net realized loss (2.11) (0.72) (1.52) ---------- --------- --------- Net increase (decrease) in net asset value $ 0.96 $ (3.83) $ (3.55) ---------- --------- --------- Net asset value, end of period $ 16.25 $ 15.29 $ 19.12 ========== ========= ========= Total return* 22.94% (16.78)% (8.88)% Ratio of net expenses to average net assets+ 1.19% 1.16% 1.01% Ratio of net investment income to average net assets+ 0.85% 0.74% 0.76% Portfolio turnover rate 40% 61% 3% Net assets, end of period (in thousands) $3,424,962 $3,016,623 $3,885,560 Ratios assuming reduction for fees paid indirectly: Net expenses 1.19% 1.16% 0.99% Net investment income 0.85% 0.74% 0.78% * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios assuming no reduction for fees paid indirectly. ** Annualized The accompanying notes are an integral part of these financial statements. 26 - -------------------------------------------------------------------------------- Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- Year Ended Year Ended Year Ended Year Ended Year Ended CLASS B 9/30/05 9/30/04 9/30/03 9/30/02 9/30/01 Net asset value, beginning of period $ 17.87 $ 15.45 $ 14.71 $ 18.53 $ 22.11 ------- ------- ------- -------- ------- Increase (decrease) from investment operations: Net investment income (loss) $ (0.04) $ (0.04) $ (0.13) $ (0.08) $ 0.01 Net realized and unrealized gain (loss) on investments and foreign currency transactions 2.13 2.50 3.08 (3.02) (2.06) ------- ------- ------- -------- ------- Net increase (decrease) from investment operations $ 2.09 $ 2.46 $ 2.95 $ (3.10) $ (2.05) Distributions to shareowners: Net investment income - - (0.10) - - Net realized loss (3.56) (0.04) (2.11) (0.72) (1.53) ------- ------- ------- -------- ------- Net increase (decrease) in net asset value $ (1.47) $ 2.42 $ 0.74 $ (3.82) $ (3.58) ------- ------- ------- -------- ------- Net asset value, end of period $ 16.40 $ 17.87 $ 15.45 $ 14.71 $ 18.53 ======= ======= ======= ======== ======= Total return* 12.66% 15.95% 21.11% (17.68)% (9.84)% Ratio of net expenses to average net assets+ 2.03% 1.89% 2.69% 2.28% 2.07% Ratio of net investment loss to average net assets+ (0.21)% (0.15)% (0.66)% (0.38)% (0.30)% Portfolio turnover rate 53% 40% 40% 61% 3% Net assets, end of period (in thousands) $51,164 $32,440 $21,666 $ 17,976 $22,372 Ratios assuming reduction for fees paid indirectly: Net expenses 2.02% 1.89% 2.68% 2.29% 2.05% Net investment loss (0.20)% (0.15)% (0.65)% (0.39)% (0.28)% * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios assuming no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 27 - -------------------------------------------------------------------------------- Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- Year Ended Year Ended Year Ended Year Ended Year Ended CLASS C 9/30/05 9/30/04 9/30/03 9/30/02 9/30/01 Net asset value, beginning of period $ 17.87 $ 15.49 $ 14.69 $ 18.53 $ 22.16 ------- ------- ------- -------- ------- Increase (decrease) from investment operations: Net investment income (loss) $ (0.04) $ (0.09) $ (0.12) $ (0.10) $ 0.04 Net realized and unrealized gain (loss) on investments and foreign currency transactions 2.12 2.51 3.13 (3.02) (2.12) ------- ------- ------- -------- ------- Net increase (decrease) from investment operations $ 2.08 $ 2.42 $ 3.01 $ (3.12) $ (2.08) Distributions to shareowners: Net investment income - - (0.10) - (0.02) Net realized gain (3.56) (0.04) (2.11) (0.72) (1.53) ------- ------- ------- -------- ------- Net increase (decrease) in net asset value $ (1.48) $ 2.38 $ 0.80 $ (3.84) $ (3.63) ------- ------- ------- -------- ------- Net asset value, end of period $ 16.39 $ 17.87 $ 15.49 $ 14.69 $ 18.53 ======= ======= ======= ======== ======= Total return* 12.60% 15.66% 21.61% (17.79)% (9.98)% Ratio of net expenses to average net assets+ 2.08% 2.21% 2.48% 2.32% 2.15% Ratio of net investment loss to average net assets+ (0.25)% (0.47)% (0.44)% (0.42)% (0.39)% Portfolio turnover rate 53% 40% 40% 61% 3% Net assets, end of period (in thousands) $ 8,926 $ 9,168 $ 6,349 $ 4,256 $ 4,431 Ratios assuming reduction for fees paid indirectly: Net expenses 2.07% 2.20% 2.47% 2.32% 2.11% Net investment loss (0.24)% (0.46)% (0.43)% (0.42)% (0.35)% * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. ** Annualized. + Ratio assuming no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 28 Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- For the period from 12/11/04 (Commencement of Operations) to INVESTOR CLASS 9/30/05 Net asset value, beginning of period $ 17.30 ------- Increase from investment operations: Net investment income $ 0.15 Net realized and unrealized gain on investments and foreign currency transactions 1.15 ------- Net increase from investment operations $ 1.30 Distributions to shareowners: Net investment income (0.07) Net realized loss (0.96) ------- Net increase in net asset value $ 0.27 ------- Net asset value, end of period $ 17.57 ======= Total return* 7.54%*** Ratio of net expenses to average net assets+ 0.75%** Ratio of net investment income to average net assets+ 1.03%** Portfolio turnover rate 53% Net assets, end of period (in thousands) $125,647 Ratios assuming reduction for fees paid indirectly: Net expenses 0.74%** Net investment income 1.04%** * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. ** Annualized. *** Not Annualized + Ratio assuming no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 29 Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- Year Ended Year Ended 4/1/03 to CLASS R 9/30/05 9/30/04 9/30/03 Net asset value, beginning of period $ 18.64 $ 16.24 $ 13.91 ------- ------- ------- Increase from investment operations: Net investment income (loss) $ (0.18) $ (0.12) $ 0.05 Net realized and unrealized gain on investments and foreign currency transactions 2.20 2.65 2.34 ------- ------- ------- Net increase from investment operations $ 2.02 $ 2.53 $ 2.39 Distributions to shareowners: Net investment income - (0.09) (0.06) Net realized loss (3.56) (0.04) - ------- ------- ------- Net increase (decrease) in net asset value $ (1.54) $ 2.40 $ 2.33 ------- ------- ------- Net asset value, end of period $ 17.10 $ 18.64 $ 16.24 ======= ======= ======= Total return* 11.65% 15.64% 17.19% Ratio of net expenses to average net assets+ 3.05% 2.79% 1.42%** Ratio of net investment income (loss) to average net assets+ (1.17)% (1.02)% 0.71%** Portfolio turnover rate 53% 40% 40% Net assets, end of period (in thousands) $ 34 $ 10 $ 1 Ratios assuming reduction for fees paid indirectly: Net expenses 3.03% 2.77% 1.42%** Net investment income (loss) (1.15)% (1.00)% 0.71%** * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. ** Annualized. + Ratio assuming no reduction for fees paid indirectly. 30 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund - -------------------------------------------------------------------------------- FINANCIAL HIGHLIGHTS - -------------------------------------------------------------------------------- For the period from 8/11/04 (Commencement Year Ended of Operations) to CLASS Y 9/30/05 9/30/04 Net asset value, beginning of period $ 18.84 $ 18.16 -------- ------- Increase from investment operations: Net investment income $ 0.12 $ 0.02 Net realized and unrealized gain on investments and foreign currency transactions 2.37 0.66 -------- ------- Net increase from investment operations $ 2.49 $ 0.68 -------- ------- Distributions to shareowners: Net investment income $ (0.18) $ - Net realized loss (3.56) -------- ------- Net increase (decrease) in net asset value $ (1.25) $ 0.68 -------- ------- Net asset value, end of period $ 17.59 $ 18.84 ======== ======= Total return* 14.40% 3.74%(a) Ratio of net expenses to average net assets+ 0.59% 0.61%** Ratio of net investment income to average net assets+ 1.50% 1.37%** Portfolio turnover rate 53% 40% Net assets, end of period (in thousands) $311,272 $ 1,872 Ratios assuming reduction for fees paid indirectly: Net expenses 0.59% 0.61%** Net investment income 1.51% 1.37%** * Assumes initial investment at net asset value at the beginning of each period, reinvestment of distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. (a) Not annualized ** Annualized. + Ratio assuming no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 31 Pioneer Value Fund - -------------------------------------------------------------------------------- NOTES TO FINANCIAL STATEMENTS 9/30/05 - -------------------------------------------------------------------------------- 1. Organization and Significant Accounting Policies Pioneer Value Fund (the Fund), is a Delaware statutory trust registered under the Investment Company Act of 1940 as a diversified, open-end management investment company. The investment objective of the Fund is reasonable income and growth of capital. The Trustees have authorized the issuance of six classes of shares of the Fund. The Fund offers six classes of shares designated as Class A, Class B, Class C, Investor Class, Class R and Class Y shares. Investor Class shares were first issued on December 10, 2004. Class R shares were first publicly offered on April 1, 2003 and Class Y shares were first publicly offered on August 11, 2004. The Fund is not offering additional Investor Class shares except in connection with the reinvestment of dividends on the Fund's outstanding Investor Class shares. Each class of shares represents an interest in the same portfolio of investments of the Fund and has equal rights to voting, redemptions, dividends and liquidation, except that each class of shares can bear different transfer agent and distribution fees and have exclusive voting rights with respect to the distribution plans that have been adopted by Class A, Class B, Class C and Class R shareowners, respectively. There is no distribution plan for Class Y and Investor Class shares. The Fund's financial statements have been prepared in conformity with U.S. generally accepted accounting principles that require the management of the Fund to, among other things, make estimates and assumptions that affect the reported amounts of assets and liabilities, the disclosure of contingent assets and liabilities at the date of the financial statements, and the reported amounts of income, expenses and gains and losses on investments during the reporting period. Actual results could differ from those estimates. The following is a summary of significant accounting policies followed by the Fund in preparation of its financial statements, which are consistent with those policies generally accepted in the investment company industry: A. Security Valuation Security transactions are recorded as of trade date. The net asset value of the Fund is computed once daily, on each day the New York Stock Exchange (NYSE) is open, as of the close of regular trading on the NYSE. In computing the net asset value, securities are valued at the last sale price on the principal exchange where 32 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- they are traded. Securities that have not traded on the date of valuation, or securities for which sale prices are not generally reported, are valued at the mean between the last bid and asked prices. Securities for which market quotations are not readily available are valued at their fair values as determined by, or under the direction of, the Board of Trustees. Trading in foreign securities is substantially completed each day at various times prior to the close of the NYSE. The values of such securities used in computing the net asset value of the Fund's shares are determined as of such times. The Fund also may use the fair value of a security including a non U.S. security when the closing market price on the principal exchange where the security is traded no longer reflects the value of the security. At September 30, 2005 there were no securities fair valued. Temporary cash investments are valued at amortized cost. Dividend income is recorded on the ex-dividend date, except that certain dividends from foreign securities where the ex-dividend date may have passed are recorded as soon as the Fund becomes aware of the ex-dividend data in the exercise of reasonable diligence. Interest income is recorded on the accrual basis. Dividend and interest income are reported net of unrecoverable foreign taxes withheld at the applicable country rates. Gains and losses on sales of investments are calculated on the identified cost method for both financial reporting and federal income tax purposes. B. Foreign Currency Translation The books and records of the Fund are maintained in U.S. dollars. Amounts denominated in foreign currencies are translated into U.S. dollars using current exchange rates. Net realized gains and losses on foreign currency transactions represent, among other things, the net realized gains and losses on foreign currency contracts, disposition of foreign currencies and the difference between the amount of income accrued and the U.S. dollars actually received. Further, the effects of changes in foreign currency exchange rates on investments are not segregated in the statement of operations from the effects of changes in market price of those securities but are included with the net realized and unrealized gain or loss on investments. 33 Pioneer Value Fund - -------------------------------------------------------------------------------- NOTES TO FINANCIAL STATEMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- C. Federal Income Taxes It is the Fund's policy to comply with the requirements of the Internal Revenue Code applicable to regulated investment companies and to distribute all of its taxable income and net realized capital gains, if any, to its shareowners. Therefore, no federal income tax provision is required. The amounts and characterizations of distributions to shareowners for financial reporting purposes are determined in accordance with federal income tax rules. Therefore, the sources of the Fund's distributions may be shown in the accompanying financial statements as either from or in excess of net investment income or net realized gain on investment transactions, or from paid-in capital, depending on the type of book/tax differences that may exist. The tax character of distributions paid during the year ended September 30, 2005 and 2004 was as follows: - -------------------------------------------------------------------------------- 2005 2004 ---------------- -------------- Distributions paid from: Ordinary income $ 72,054,389 $ 28,499,269 Long-term capital gain 682,451,592 8,517,249 ------------- ------------ Return of capital - - ------------- ------------ Total $ 754,505,981 $ 37,016,518 ============= ============ - -------------------------------------------------------------------------------- The following shows the components of distributable earnings on a federal income tax basis at September 30, 2005. - -------------------------------------------------------------------------------- 2005 -------------- Undistributed ordinary income $ 22,048,959 Undistributed long-term gain 11,156,268 Unrealized appreciation 792,747,984 ------------ Total $825,953,211 ============ - -------------------------------------------------------------------------------- The difference between book-basis and tax-basis unrealized appre ciation is attributable to the tax deferral of losses on wash sales. At September 30, 2005, The Fund reclassified $220,678 to increase undistributed net investment income and $220,678 to decrease accumulated net realized gain on investments and 34 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- foreign currency transactions to reflect permanent book/tax differences. This reclassification has no impact on the net asset value of the fund and is designed to present the Fund's capital accounts on a tax basis. D. Forward Foreign Currency Contracts The Fund enters into forward foreign currency contracts (contracts) for the purchase or sale of a specific foreign currency at a fixed price on a future date as a hedge or cross-hedge against either specific investment transactions (settlement hedges) or portfolio positions (portfolio hedges). All contracts are marked to market daily at the applicable exchange rates, and any resulting unrealized gains or losses are recorded in the Fund's financial statements. The Fund records realized gains and losses at the time a portfolio hedge is offset by entry into a closing transaction or extinguished by delivery of the currency. Risks may arise upon entering into these contracts from the potential inability of counterparties to meet the terms of the contract and from unanticipated movements in the value of foreign currencies relative to the U.S. dollar. As of September 30, 2005, the Fund had no outstanding settlement or portfolio hedges. E. Fund Shares The Fund records sales and repurchases of its shares as of trade date. Pioneer Funds Distributor, Inc. (PFD), the principal underwriter for the Fund and a wholly owned indirect subsidiary of UniCredito Italiano S.p.A. (UniCredito Italiano), earned $368,791 in underwriting commissions on the sale of Class A shares during the year ended September 30, 2005. F. Class Allocations Distribution fees are calculated based on the average daily net asset value attributable to Class A, Class B, Class C and Class R shares of the Fund, respectively (see Note 4). Investor Class and Class Y shares are not subject to a distribution plan. Shareowners of each class share all expenses and fees paid to the transfer agent, Pioneer Investment Management Shareholder Services, Inc. (PIMSS), for its services, which are allocated based on the number of accounts in each class and the ratable allocation of related out-of-pocket expenses (see Note 3). Income, common expenses and 35 Pioneer Value Fund - -------------------------------------------------------------------------------- NOTES TO FINANCIAL STATEMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- realized and unrealized gains and losses are calculated at the Fund level and allocated daily to each class of shares based on the respective percentage of adjusted net assets at the beginning of the day. Distributions to shareowners are recorded as of the ex-dividend date. Distributions paid by the Fund with respect to each class of shares are calculated in the same manner, at the same time, and in the same amount, except that Class A, Class B, Class C, Investor Class, Class R and Class Y shares can bear different transfer agent and distribution fees. G. Repurchase Agreements With respect to repurchase agreements entered into by the Fund, the value of the underlying securities (collateral), including accrued interest received from counterparties, is required to be at least equal to or in excess of the value of the repurchase agreement at the time of purchase. The collateral for all repurchase agreements is held in safekeeping in the customer-only account of the Fund's custodian, or subcustodians. The Fund's investment adviser, Pioneer Investment Management, Inc. (PIM), is responsible for determining that the value of the collateral remains at least equal to the repurchase price. H. Security Lending The Fund lends securities in its portfolio to certain broker-dealers or other institutional investors, with the Fund's custodian acting as the lending agent. When entering into a loan, the Fund receives collateral, which is maintained by the custodian and earns income in the form of negotiated lenders' fees. The Fund also continues to receive interest or payments in lieu of dividends on the securities loaned. Gain or loss in the fair value of the loaned securities that may occur during the term of the loan will be for the account of the Fund. The loans are secured by collateral of at least 102%, at all times, of the fair value of the securities loaned. The amount of the collateral will be adjusted daily to reflect any price fluctuation in the value of the loaned securities. The Fund has the right under the lending agreements to recover the securities from the borrower on demand. The Fund invests cash collateral in interest bearing bank deposits. 36 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- 2. Management Agreement PIM, a wholly owned indirect subsidiary of UniCredito Italiano, manages the Fund's portfolio. PIM receives a basic fee that is calculated at the annual rate of 0.60% of the Fund's average daily net assets up to $5 billion, 0.575% on the next $5 billion and 0.55% on the excess over $10 billion. The basic fee is subject to a performance adjustment (limited to a maximum of -0.10% applied to average assets during the measurement period) based on the Fund's investment performance as compared with the Russell 1000[RegTM] Value Index over a rolling 36-month period. In addition, the fee is further limited to a maximum annualized rate adjustment of -0.10% (a "ceiling" and a "floor") applied to average assets during the current month. Effective August 1, 2004, PIM commenced a voluntary waiver of the minimum fee provision (the "floor"), but may reimpose it in the future. Pursuant to a shareowner vote on April 17, 2003 the benchmark was changed from the Lipper Growth & Income Funds Index effective May 1, 2003; however, the Lipper Growth & Income Index will be used for monthly periods prior to May 1, 2003 until it is eventually phased out. For the year ended September 30, 2005, the aggregate performance adjustment resulted in a decrease to the basic fee of $2,848,006. For the year ended September 30, 2005, the net management fee was equivalent to 0.53% of average daily net assets. Through December 10, 2006, PIM has agreed not to impose all or a portion of its management fees and to assume other operating expenses (excluding taxes, commissions, interest and extraordinary expenses) of the Fund to the extent necessary to limit Investor Class expenses to 1.10% of the average daily net assets attributable to Investor Class shares. In addition, under the management and administration agreements, certain other services and costs, including accounting, regulatory reporting and insurance premiums, are paid by the Fund. At September 30, 2005, $101,935 was payable to PIM related to management fees, administration costs and certain other services and is included in due to affiliates. 37 Pioneer Value Fund - -------------------------------------------------------------------------------- NOTES TO FINANCIAL STATEMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- 3. Transfer Agent PIMSS, a wholly owned indirect subsidiary of UniCredito Italiano, provides substantially all transfer agent and shareowner services to the Fund at negotiated rates. Included in due to affiliates is $861,164 in transfer agent fees payable to PIMSS at September 30, 2005. 4. Distribution and Service Plans The Fund adopted a Plan of Distribution with respect to Class A, Class B, Class C and Class R shares in accordance with Rule 12b-1 under the Investment Company Act of 1940. Pursuant to the Class A Plan, the Fund pays PFD a service fee of up to 0.25% of the average daily net assets attributable to Class A shares in reimbursement of its actual expenditures to finance activities primarily intended to result in the sale of Class A shares. Pursuant to the Class B Plan and the Class C Plan, the Fund pays PFD 1.00% of the average daily net assets attributable to each class of shares. The fee consists of a 0.25% service fee and a 0.75% distribution fee paid as compensation for personal services and/or account maintenance services or distribution services with regard to Class B and Class C shares. Pursuant to the Class R Plan, the Fund pays PFD 0.50% of the average daily net assets attributable to Class R shares as compensation for distribution services. Included in due to affiliates is $27,792 in distribution fees payable to PFD at September 30, 2005. The Fund also has adopted a separate service plan for Class R shares (Service Plan). The Service Plan authorizes the Fund to pay as compensation to securities dealers, plan administrators or other service organizations that agree to provide certain services to retirement plans or plan participants holding shares of the Fund a service fee of up to 0.25% of the Fund's average daily net assets attributable to Class R shares held by such plans. In addition, redemptions of each class of shares (except Class Y and Investor Class shares) may be subject to a contingent deferred sales charge (CDSC). Effective February 1, 2004, a CDSC of 1.00% may be imposed on redemptions of certain net asset value purchases of Class A shares within 18 months of purchase (12 months for shares purchased prior to February 1, 2004). Effective December 1, 2004 Class B shares that are redeemed within five years of purchase are subject to a CDSC at declining rates beginning at 4.00%, based on the lower of cost or market value of shares being redeemed. Shares 38 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- purchased prior to December 1, 2004, remain subject to the CDSC in effect at the time those shares were purchased. Redemptions of Class C shares within one year of purchase are subject to a CDSC of 1.00%. Redemptions of Class R shares within 18 months of purchase were subject to a CDSC of 1.00%. Effective July 1, 2004, the CDSC on Class R shares was eliminated. Proceeds from the CDSCs are paid to PFD. For the year ended September 30, 2005, CDSCs in the amount of $47,913 were paid to PFD. 5. Commission Recapture and Expense Offset Arrangements Effective July 15, 2005, the Fund has entered into commission recapture arrangements with brokers with whom PIM places trades on behalf of the Fund where they provide services to the Fund in addition to trade execution. These services included payments of certain expenses on behalf of the Fund. For the year ended September 30, 2005, expenses were reduced by $4,286 under this agreement. In addition, the Fund has entered into certain expense offset arrangements with PIMSS resulting in a reduction in the Fund's total expenses due to interest earned on cash held by PIMSS. For the year ended September 30, 2005, the Fund's expenses were reduced by $90,160 under such arrangements. 6. Line of Credit The Fund, along with certain others in the Pioneer Family of Funds (the Funds), collectively participate in a $50 million committed, unsecured revolving line of credit facility. Borrowings are used solely for temporary or emergency purposes. The Fund may borrow up to the lesser of $50 million or the limits set by its prospectus for borrowings. Interest on collective borrowings is payable at the Federal Funds Rate plus 1/2%, on an annualized basis. The Funds pay an annual commitment fee for this facility. The commitment fee is allocated among such Funds based on their respective borrowing limits. For the year ended September 30, 2005, the Fund had no borrowings under this agreement. 7. Merger Information On December 8, 2004, beneficial owners of Safeco Large-Cap Value Fund (one of the series that comprised Safeco Common Stock Trust) approved a proposed Agreement and Plan of Reorganization that provided for the merger listed below. This tax-free reorganization was 39 Pioneer Value Fund - -------------------------------------------------------------------------------- NOTES TO FINANCIAL STATEMENTS 9/30/05 (continued) - -------------------------------------------------------------------------------- accomplished on December 10, 2004, by exchanging all of the Safeco Fund's net assets for Investor Class shares, based on the Fund's Class A shares' ending net asset value. The following charts show the details of the reorganization as of that closing date ("Closing Date"): - -------------------------------------------------------------------------------------- Pioneer Safeco Large-Cap Pioneer Value Fund Value Fund Value Fund (Pre-Reorganization) (Pre-Reorganization) (Post-Reorganization) ---------------------- ---------------------- ---------------------- Net Assets $3,928,863,026 $137,973,598 $4,079,685,285 Shares Out- standing 227,295,131 7,250,390 235,410,358 Investor Class Shares Issued - - 7,975,352 - -------------------------------------------------------------------------------------- - -------------------------------------------------------------------------------------- Unrealized Appreciation Accumulated on Closing Realized Gain Date (on Closing Date) -------------- ------------------ Safeco Large-Cap Value Fund $ 32,305,797 $ 14,519,243 - -------------------------------------------------------------------------------------- In addition, on September 22, 2005, beneficial owners of AmSouth Value Fund approved a proposed Agreement and Plan of Reorganization that provided for the merger listed below. This tax-free reorganization was accomplished on September 23, 2005, by exchanging all of AmSouth Value Fund's net assets for Value Fund's shares, based on Value Fund's Class A, Class B, Class C, Investor Class, Class R and Class Y shares' ending net asset value, respectively. The following charts show the details of the reorganizations as of that closing date ("Closing Date"): 40 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------------------- Pioneer Value Fund AmSouth Value Fund Pioneer Value Fund (Pre-Reorganization) (Pre-Reorganization) (Post-Reorganization) - -------------------------------------------------------------------------------------------- Net Assets Class A $3,846,864,590 $110,131,470 $3,956,996,060 Class B $ 26,743,819 $ 24,011,838 $ 50,755,657 Class C $ 8,808,028 $ - $ 8,808,028 Class R $ 33,730 $ - $ 33,730 Class Y $ 14,016,138 $ - $ 308,920,188 Investor Class $ 124,517,490 $ - $ 124,517,490 Class I $ - $294,904,050 $ - Total Net Assets $4,020,983,794 $429,047,359 $4,450,031,153 Shares Outstanding Class A 221,821,985 6,958,193 228,173,281 Class B 1,650,090 1,553,237 3,131,388 Class C 543,908 - 543,908 Class R 1,994 - 1,994 Class Y 808,519 - 20,776,532 Investor Class 7,173,404 - 7,173,404 Class I - 18,668,696 - Shares Issued in Reorganization Class A 6,351,296 Class B 1,481,298 Class Y 16,968,012 - -------------------------------------------------------------------------------------------- - -------------------------------------------------------------------------------------------- Unrealized Accumulated Depreciation on Gain on Closing Date Closing Date - -------------------------------------------------------------------------------------------- AmSouth Value Fund $73,055,075 $(28,434,297) - -------------------------------------------------------------------------------------------- 41 Pioneer Value Fund - -------------------------------------------------------------------------------- REPORT OF INDEPENDENT REGISTERED PUBLIC ACCOUNTING FIRM - -------------------------------------------------------------------------------- To the Board of Trustees and Shareowners of Pioneer Value Fund: We have audited the statement of assets and liabilities, including the schedule of investments, of Pioneer Value Fund (the "Fund") as of September 30, 2005, and the related statement of operations for the year then ended, the statements of changes in net assets for each of the two years in the period then ended, and the financial highlights for each of the four years in the period then ended. These financial statements and financial highlights are the responsibility of the Fund's management. Our responsibility is to express an opinion on these financial statements and financial highlights based on our audits. The financial highlights for the year ended September 30, 2001 were audited by other auditors who have ceased operations and whose report, dated November 5, 2001, expressed an unqualified opinion on those financial highlights. We conducted our audits in accordance with the standards of the Public Company Accounting Oversight Board (United States). Those standards require that we plan and perform the audit to obtain reasonable assurance about whether the financial statements and financial highlights are free of material misstatement. We were not engaged to perform an audit of the Fund's internal control over financial reporting. Our audits included consideration of internal control over financial reporting as a basis for designing audit procedures that are appropriate in the circumstances, but not for the purpose of expressing an opinion on the effectiveness of the Fund's internal control over financial reporting. Accordingly, we express no such opinion. An audit also includes examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements and financial highlights, assessing the accounting principles used and significant estimates made by management, and evaluating the overall financial statement presentation. Our procedures included confirmation of securities owned as of September 30, 2005, by correspondence with the custodian and brokers, or by other appropriate auditing procedures where replies form brokers were not received. We believe that our audits provide a reasonable basis for our opinion. In our opinion, the financial statements and financial highlights referred to above present fairly, in all material respects, the financial position of Pioneer Value Fund at September 30, 2005, the results of its operations for the year then ended, the changes in its net assets for each of the two years in the period then ended, and the financial highlights for each of the four years in the period then ended, in conformity with U.S. generally accepted accounting principles. /s/ Ernst & Young LLP Boston, Massachusetts November 14, 2005 42 Pioneer Value Fund - -------------------------------------------------------------------------------- TRUSTEES, OFFICERS AND SERVICE PROVIDERS - -------------------------------------------------------------------------------- Investment Adviser Pioneer Investment Management, Inc. Custodian Brown Brothers Harriman & Co. Independent Registered Public Accounting Firm Ernst & Young LLP Principal Underwriter Pioneer Funds Distributor, Inc. Legal Counsel Wilmer Cutler Pickering Hale and Dorr LLP Shareowner Services and Sub-Transfer Agent Pioneer Investment Management Shareholder Services, Inc. Trustees and Officers The Fund's Board of Trustees provides broad supervision over the Fund's affairs. The officers of the Fund are responsible for the Fund's operations. The Fund's Trustees and officers are listed below, together with their principal occupations during the past five years. Trustees who are interested persons of the Fund within the meaning of the Investment Company Act of 1940 are referred to as Interested Trustees. Trustees who are not interested persons of the Fund are referred to as Independent Trustees. Each of the Trustees may serve as a trustee of each of the 88 U.S. registered investment portfolios for which Pioneer Investment Management, Inc. ("Pioneer") serves as investment adviser (the "Pioneer Funds"). The address for all Interested Trustees and all officers of the Fund is 60 State Street, Boston, Massachusetts 02109. The Fund's statement of additional information provides more detailed information regarding the Fund's Trustees and is available upon request, without charge, by calling 1-800-225-6292. Proxy Voting Policies and Procedures of the Fund are available without charge, upon request, by calling our toll free number (1-800-225-6292). Information regarding how the Fund voted proxies relating to portfolio securities during the most recent 12-month period ended June 30 is publicly available to shareowners at www.pioneerfunds.com and on the SEC's web site at http://www.sec.gov. 43 Pioneer Value Fund - -------------------------------------------------------------------------------- INTERESTED TRUSTEES - -------------------------------------------------------------------------------- Positions Held Length of Service Name and Age With the Fund and Term of Office John F. Cogan, Jr. (79)* Chairman of the Trustee since 1982. Board, Serves until Trustee and President successor trustee is elected or earlier retirement or removal * Mr. Cogan is an Interested Trustee because he is an officer or director of Pioneer and certain of its affiliates. - ----------------------------------------------------------------------------------------------------------------- Pioneer Value Fund - ----------------------------------------------------------------------------------------------------------------- INTERESTED TRUSTEES - ----------------------------------------------------------------------------------------------------------------- Other Directorships Held Name and Age Principal Occupation During Past Five Years by this Trustee John F. Cogan, Jr. (79)* Deputy Chairman and a Director of Pioneer Global Asset Chairman and Director of Management S.p.A. ("PGAM"); Non-Executive Chairman ICI Mutual Insurance and a Director of Pioneer Investment Management USA Company; Director Inc. ("PIM-USA"); Chairman and a Director of Pioneer; of Harbor Global Director of Pioneer Alternative Investment Management Company, Ltd. Limited (Dublin); President and a Director of Pioneer Alternative Investment Management (Bermuda) Limited and affiliated funds; President and Director of Pioneer Funds Distributor, Inc. ("PFD"); President of all of the Pioneer Funds; and Of Counsel (since 2000, partner prior to 2000), Wilmer Cutler Pickering Hale and Dorr LLP (counsel to PIM-USA and the Pioneer Funds) * Mr. Cogan is an Interested Trustee because he is an officer or director of Pioneer and certain of its affiliates. - ----------------------------------------------------------------------------------------------------------------- 44 Pioneer Value Fund - -------------------------------------------------------------------------------- INTERESTED TRUSTEES - -------------------------------------------------------------------------------- Positions Held Length of Service Name, Age and Address With the Fund and Term of Office David R. Bock**(61) Trustee Trustee since 2005. 3050 K. Street NW, Serves until Washington, DC 20007 successor trustee is elected or earlier retirement or removal ** Mr. Bock became a Trustee of the Fund on January 1, 2005. - ------------------------------------------------------------------------------------------------------------------------ Mary K. Bush (57) Trustee Trustee since 1997. 3509 Woodbine Street, Serves until Chevy Chase, MD 20815 successor trustee is elected or earlier retirement or removal - ------------------------------------------------------------------------------------------------------------------------ Margaret B.W. Graham (58) Trustee Trustee since 1990. 1001 Sherbrooke Street West, Serves until Montreal, Quebec, Canada successor trustee H3A 1G5 is elected or earlier retirement or removal - ------------------------------------------------------------------------------------------------------------------------ Pioneer Value Fund - ------------------------------------------------------------------------------------------------------------------------ INTERESTED TRUSTEES - ------------------------------------------------------------------------------------------------------------------------ Other Directorships Held Name, Age and Address Principal Occupation During Past Five Years by this Trustee David R. Bock**(61) Senior Vice President and Chief Financial Officer, I-trax, Director of The Enterprise 3050 K. Street NW, Inc. (publicly traded health care services company) Social Investment Washington, DC 20007 (2001 - present); Managing Partner, Federal City Capital Company (privately-held Advisors (boutique merchant bank) (1995 - 2000; 2002 affordable housing to 2004); Executive Vice President and Chief Financial finance company); Officer, Pedestal Inc. (internet-based mortgage trading Director of New York company) (2000 - 2002) Mortgage Trust (publicly traded mortgage REIT) ** Mr. Bock became a Trustee of the Fund on January 1, 2005. - ------------------------------------------------------------------------------------------------------------------------ Mary K. Bush (57) President, Bush International (international financial Director of Brady 3509 Woodbine Street, advisory firm) Corporation (industrial Chevy Chase, MD 20815 identification and specialty coated material products manufacturer), Millennium Chemicals, Inc. (commodity chemicals), Mortgage Guaranty Insurance Corporation, and R.J. Reynolds Tobacco Holdings, Inc. (tobacco) - ------------------------------------------------------------------------------------------------------------------------ Margaret B.W. Graham (58) Founding Director, The Winthrop Group, Inc. (consulting None 1001 Sherbrooke Street West, firm); Professor of Management, Faculty of Management, Montreal, Quebec, Canada McGill University H3A 1G5 - ------------------------------------------------------------------------------------------------------------------------ 45 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Positions Held Length of Service Name, Age and Address With the Fund and Term of Office Marguerite A. Piret (57) Trustee Trustee since 1982. One Boston Place, 28th Floor, Serves until Boston, MA 02108 successor trustee is elected or earlier retirement or removal - ------------------------------------------------------------------------------------------------------------------- John Winthrop (69) Trustee Trustee since 1985. One North Adgers Wharf, Serves until Charleston, SC 29401 successor trustee is elected or earlier retirement or removal - ------------------------------------------------------------------------------------------------------------------- Pioneer Value Fund - ------------------------------------------------------------------------------------------------------------------- - ------------------------------------------------------------------------------------------------------------------- Other Directorships Held Name, Age and Address Principal Occupation During Past Five Years by this Trustee Marguerite A. Piret (57) President and Chief Executive Officer, Newbury, Piret & Director of New America One Boston Place, 28th Floor, Company, Inc. (investment banking firm) High Income Fund, Inc. Boston, MA 02108 (closed-end investment company) - ------------------------------------------------------------------------------------------------------------------- John Winthrop (69) President, John Winthrop & Co., Inc. None One North Adgers Wharf, (private investment firm) Charleston, SC 29401 - ------------------------------------------------------------------------------------------------------------------- 46 Pioneer Value Fund - -------------------------------------------------------------------------------- FUND OFFICERS - -------------------------------------------------------------------------------- Positions Held Length of Service Name and Age With the Fund and Term of Office Osbert M. Hood (53) Executive Vice Since June 2003. President Serves at the discretion of the Board - ------------------------------------------------------------------------------------------------------------------- Dorothy E. Bourassa (57) Secretary Since September, 2003. Serves at the discretion of the Board - ------------------------------------------------------------------------------------------------------------------- Christopher J. Kelley (40) Assistant Secretary Since September, 2003. Serves at the discretion of the Board - ------------------------------------------------------------------------------------------------------------------- David C. Phelan (48) Assistant Secretary Since September, 2003. Serves at the discretion of the Board - ------------------------------------------------------------------------------------------------------------------- Pioneer Value Fund - -------------------------------------------------------------------------------- FUND OFFICERS - -------------------------------------------------------------------------------- Other Directorships Held Name and Age Principal Occupation During Past Five Years by this Officer Osbert M. Hood (53) President and Chief Executive Officer, PIM-USA since Trustee of certain May 2003 (Director since January 2001); President Pioneer Funds and Director of Pioneer since May 2003; Chairman and Director of Pioneer Investment Management Shareholder Services, Inc. ("PIMSS") since May 2003; Executive Vice President of all of the Pioneer Funds since June 2003; Executive Vice President and Chief Operating Officer of PIM-USA, November 2000 to May 2003 - ------------------------------------------------------------------------------------------------------------------- Dorothy E. Bourassa (57) Secretary of PIM-USA; Senior Vice President - Legal None of Pioneer; and Secretary/Clerk of most of PIM-USA's subsidiaries; Secretary of all of the Pioneer Funds since September 2003 (Assistant Secretary from November 2000 to September 2003) - ------------------------------------------------------------------------------------------------------------------- Christopher J. Kelley (40) Assistant Vice President and Senior Counsel of None Pioneer since July 2002; Vice President and Senior Counsel of BISYS Fund Services, Inc. (April 2001 to June 2002); Senior Vice President and Deputy General Counsel of Funds Distributor, Inc. (July 2000 to April 2001); Assistant Secretary of all Pioneer Funds since September 2003 - ------------------------------------------------------------------------------------------------------------------- David C. Phelan (48) Partner, Wilmer Cutler Pickering Hale and Dorr LLP; None Assistant Secretary of all Pioneer Funds since September 2003 - ------------------------------------------------------------------------------------------------------------------- 47 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Positions Held Length of Service Name and Age With the Fund and Term of Office Vincent Nave (60) Treasurer Since November, 2000. Serves at the discretion of the Board - -------------------------------------------------------------------------------------------------------- Mark E. Bradley (45) Assistant Treasurer Since November, 2004. Serves at the discretion of the Board - -------------------------------------------------------------------------------------------------------- Luis I. Presutti (40) Assistant Treasurer Since November, 2000. Serves at the discretion of the Board - -------------------------------------------------------------------------------------------------------- Gary Sullivan (47) Assistant Treasurer Since May, 2002. Serves at the discretion of the Board - -------------------------------------------------------------------------------------------------------- Pioneer Value Fund Other Directorships Held Name and Age Principal Occupation During Past Five Years by this Officer Vincent Nave (60) Vice President - Fund Accounting, Administration None and Custody Services of Pioneer; and Treasurer of all of the Pioneer Funds - -------------------------------------------------------------------------------------------------------- Mark E. Bradley (45) Deputy Treasurer of Pioneer since 2004; Treasurer None and Senior Vice President, CDC IXIS Asset Management Services from 2002 to 2003; Assistant Treasurer and Vice President, MFS Investment Management from 1997 to 2002; and Assistant Treasurer of all of the Pioneer Funds since November 2004 - -------------------------------------------------------------------------------------------------------- Luis I. Presutti (40) Assistant Vice President - Fund Accounting, None Administration and Custody Services of Pioneer; and Assistant Treasurer of all of the Pioneer Funds - -------------------------------------------------------------------------------------------------------- Gary Sullivan (47) Fund Accounting Manager - Fund Accounting, None Administration and Custody Services of Pioneer; and Assistant Treasurer of all of the Pioneer Funds since May 2002 - -------------------------------------------------------------------------------------------------------- 48 Pioneer Value Fund - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- Positions Held Length of Service Name and Age With the Fund and Term of Office Katherine Kim Sullivan (31) Assistant Treasurer Since September, 2003. Serves at the discretion of the Board - ---------------------------------------------------------------------------------------------------------------------- Martin J. Wolin (38) Chief Compliance Since October, 2004. Officer Serves at the discretion of the Board - ---------------------------------------------------------------------------------------------------------------------- Other Directorships Held Name and Age Principal Occupation During Past Five Years by this Officer Katherine Kim Sullivan (31) Fund Administration Manager - Fund Accounting, None Administration and Custody Services since June 2003; Assistant Vice President - Mutual Fund Operations of State Street Corporation from June 2002 to June 2003 (formerly Deutsche Bank Asset Management); Pioneer Fund Accounting, Administration and Custody Services (Fund Accounting Manager from August 1999 to May 2002, Assistant Treasurer of all Pioneer Funds since September 2003 - ---------------------------------------------------------------------------------------------------------------------- Martin J. Wolin (38) Chief Compliance Officer of Pioneer (Director of None Compliance and Senior Counsel from November 2000 to September 2004); and Chief Compliance Officer of all of the Pioneer Funds since 2004 - ---------------------------------------------------------------------------------------------------------------------- The outstanding capital stock of PFD, PIM and PIMSS is indirectly wholly owned by UniCredito Italiano S.p.A. ("UniCredito Italiano"), one of the largest banking groups in Italy. PIM, the Fund's investment adviser, provides investment management and financial services to mutual funds, institutional and other clients. 49 - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- This page for your notes. 50 - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- This page for your notes. 51 - -------------------------------------------------------------------------------- - -------------------------------------------------------------------------------- This page for your notes. 52 - -------------------------------------------------------------------------------- HOW TO CONTACT PIONEER - -------------------------------------------------------------------------------- We are pleased to offer a variety of convenient ways for you to contact us for assistance or information. Call us for: Account Information, including existing accounts, new accounts, prospectuses, applications and service forms 1-800-225-6292 FactFone(SM) for automated fund yields, prices, account information and transactions 1-800-225-4321 Retirement plans information 1-800-622-0176 Telecommunications Device for the Deaf (TDD) 1-800-225-1997 Write to us: PIMSS, Inc. P.O. Box 55014 Boston, Massachusetts 02205-5014 Our toll-free fax 1-800-225-4240 Our internet e-mail address ask.pioneer@pioneerinvest.com (for general questions about Pioneer only) Visit our web site: www.pioneerfunds.com Before investing consider the Fund's investment objectives, risks, charges and expenses. Contact your advisor or Pioneer Investments for a prospectus containing this information. Please read it carefully. The Fund files a complete statement of investments with the Securities and Exchange Commission for the first and third quarters for each fiscal year on Form N-Q. Shareholders may view the filed Form N-Q by visiting the Commission's web site at http://www.sec.gov. The filed form may also be viewed and copied at the Commission's Public Reference Room in Washington, DC. Information regarding the operations of the Public Reference Room may be obtained by calling 1-800-SEC-0330. ITEM 2. CODE OF ETHICS. (a) Disclose whether, as of the end of the period covered by the report, the registrant has adopted a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party. If the registrant has not adopted such a code of ethics, explain why it has not done so. The registrant has adopted, as of the end of the period covered by this report, a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer and controller. (b) For purposes of this Item, the term "code of ethics" means written standards that are reasonably designed to deter wrongdoing and to promote: (1) Honest and ethical conduct, including the ethical handling of actual or apparent conflicts of interest between personal and professional relationships; (2) Full, fair, accurate, timely, and understandable disclosure in reports and documents that a registrant files with, or submits to, the Commission and in other public communications made by the registrant; (3) Compliance with applicable governmental laws, rules, and regulations; (4) The prompt internal reporting of violations of the code to an appropriate person or persons identified in the code; and (5) Accountability for adherence to the code. (c) The registrant must briefly describe the nature of any amendment, during the period covered by the report, to a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item. The registrant must file a copy of any such amendment as an exhibit pursuant to Item 10(a), unless the registrant has elected to satisfy paragraph (f) of this Item by posting its code of ethics on its website pursuant to paragraph (f)(2) of this Item, or by undertaking to provide its code of ethics to any person without charge, upon request, pursuant to paragraph (f)(3) of this Item. The registrant has made no amendments to the code of ethics during the period covered by this report. (d) If the registrant has, during the period covered by the report, granted a waiver, including an implicit waiver, from a provision of the code of ethics to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, that relates to one or more of the items set forth in paragraph (b) of this Item, the registrant must briefly describe the nature of the waiver, the name of the person to whom the waiver was granted, and the date of the waiver. Not applicable. (e) If the registrant intends to satisfy the disclosure requirement under paragraph (c) or (d) of this Item regarding an amendment to, or a waiver from, a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item by posting such information on its Internet website, disclose the registrant's Internet address and such intention. Not applicable. (f) The registrant must: (1) File with the Commission, pursuant to Item 10(a), a copy of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, as an exhibit to its annual report on this Form N-CSR; (2) Post the text of such code of ethics on its Internet website and disclose, in its most recent report on this Form N-CSR, its Internet address and the fact that it has posted such code of ethics on its Internet website; or (3) Undertake in its most recent report on this Form N-CSR to provide to any person without charge, upon request, a copy of such code of ethics and explain the manner in which such request may be made. 	See Item 10(2) ITEM 3. AUDIT COMMITTEE FINANCIAL EXPERT. (a) (1) Disclose that the registrant's board of trustees has determined that the registrant either: (i) Has at least one audit committee financial expert serving on its audit committee; or (ii) Does not have an audit committee financial expert serving on its audit committee. The registrant's Board of Trustees has determined that the registrant has at least one audit committee financial expert. (2) If the registrant provides the disclosure required by paragraph (a)(1)(i) of this Item, it must disclose the name of the audit committee financial expert and whether that person is "independent." In order to be considered "independent" for purposes of this Item, a member of an audit committee may not, other than in his or her capacity as a member of the audit committee, the board of trustees, or any other board committee: (i) Accept directly or indirectly any consulting, advisory, or other compensatory fee from the issuer; or (ii) Be an "interested person" of the investment company as defined in Section 2(a)(19) of the Act (15 U.S.C. 80a-2(a)(19)). Ms. Marguerite A. Piret, an independent trustee, is such an audit committee financial expert. (3) If the registrant provides the disclosure required by paragraph (a)(1) (ii) of this Item, it must explain why it does not have an audit committee financial expert. Not applicable. ITEM 4. PRINCIPAL ACCOUNTANT FEES AND SERVICES. (a) Disclose, under the caption AUDIT FEES, the aggregate fees billed for each of the last two fiscal years for professional services rendered by the principal accountant for the audit of the registrant's annual financial statements or services that are normally provided by the accountant in connection with statutory and regulatory filings or engagements for those fiscal years. Audit Fees Fees for audit services provided to the Fund, including fees associated with the routine and non-routine filings of its Form N-1A, totaled approximately $45,770 in 2005 and approximately $44,800 in 2004. (b) Disclose, under the caption AUDIT-RELATED FEES, the aggregate fees billed in each of the last two fiscal years for assurance and related services by the principal accountant that are reasonably related to the performance of the audit of the registrant's financial statements and are not reported under paragraph (a) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Audit-Related and Other Fees There were no audit-related and other services provided to the Fund during the fiscal years ended September 30, 2005 and 2004. (c) Disclose, under the caption TAX FEES, the aggregate fees billed in each of the last two fiscal years for professional services rendered by the principal accountant for tax compliance, tax advice, and tax planning. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Tax Fees Fees for tax compliance services, primarily for tax returns, totaled $6,800 in 2005 and $6,000 in 2004. (d) Disclose, under the caption ALL OTHER FEES, the aggregate fees billed in each of the last two fiscal years for products and services provided by the principal accountant, other than the services reported in paragraphs (a) through (c) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. N/A (e) (1) Disclose the audit committee's pre-approval policies and procedures described in paragraph (c)(7) of Rule 2-01 of Regulation S-X. PIONEER FUNDS APPROVAL OF AUDIT, AUDIT-RELATED, TAX AND OTHER SERVICES PROVIDED BY THE INDEPENDENT AUDITOR SECTION I - POLICY PURPOSE AND APPLICABILITY The Pioneer Funds recognize the importance of maintaining the independence of their outside auditors. Maintaining independence is a shared responsibility involving Pioneer Investment Management, Inc ("PIM"), the audit committee and the independent auditors. The Funds recognize that a Fund's independent auditors: 1) possess knowledge of the Funds, 2) are able to incorporate certain services into the scope of the audit, thereby avoiding redundant work, cost and disruption of Fund personnel and processes, and 3) have expertise that has value to the Funds. As a result, there are situations where it is desirable to use the Fund's independent auditors for services in addition to the annual audit and where the potential for conflicts of interests are minimal. Consequently, this policy, which is intended to comply with Rule 210.2-01(C)(7), sets forth guidelines and procedures to be followed by the Funds when retaining the independent audit firm to perform audit, audit-related tax and other services under those circumstances, while also maintaining independence. Approval of a service in accordance with this policy for a Fund shall also constitute approval for any other Fund whose pre-approval is required pursuant to Rule 210.2-01(c)(7)(ii). In addition to the procedures set forth in this policy, any non-audit services that may be provided consistently with Rule 210.2-01 may be approved by the Audit Committee itself and any pre-approval that may be waived in accordance with Rule 210.2-01(c)(7)(i)(C) is hereby waived. Selection of a Fund's independent auditors and their compensation shall be determined by the Audit Committee and shall not be subject to this policy. SECTION II - POLICY - ---------------- -------------------------------- ------------------------------------------------- SERVICE SERVICE CATEGORY DESCRIPTION SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES CATEGORY - ---------------- -------------------------------- ------------------------------------------------- I. AUDIT Services that are directly o Accounting research assistance SERVICES related to performing the o SEC consultation, registration independent audit of the Funds statements, and reporting o Tax accrual related matters o Implementation of new accounting standards o Compliance letters (e.g. rating agency letters) o Regulatory reviews and assistance regarding financial matters o Semi-annual reviews (if requested) o Comfort letters for closed end offerings - ---------------- -------------------------------- ------------------------------------------------- II. Services which are not o AICPA attest and agreed-upon procedures AUDIT-RELATED prohibited under Rule o Technology control assessments SERVICES 210.2-01(C)(4) (the "Rule") o Financial reporting control assessments and are related extensions of o Enterprise security architecture the audit services support the assessment audit, or use the knowledge/expertise gained from the audit procedures as a foundation to complete the project. In most cases, if the Audit-Related Services are not performed by the Audit firm, the scope of the Audit Services would likely increase. The Services are typically well-defined and governed by accounting professional standards (AICPA, SEC, etc.) - ---------------- -------------------------------- ------------------------------------------------- ------------------------------------- ------------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the audit period for all services and related fees pre-approved specific service reported at each regularly subcategories. Approval of the scheduled Audit Committee independent auditors as meeting. auditors for a Fund shall constitute pre approval for these services. ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the fund fiscal year within services and related fees a specified dollar limit (including comparison to for all pre-approved specified dollar limits) specific service subcategories reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limit for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for Audit-Related Services not denoted as "pre-approved", or to add a specific service subcategory as "pre-approved" ------------------------------------- ------------------------------------ SECTION III - POLICY DETAIL, CONTINUED - ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- --------------------------- ----------------------------------------------- III. TAX SERVICES Services which are not o Tax planning and support prohibited by the Rule, o Tax controversy assistance if an officer of the Fund o Tax compliance, tax returns, excise determines that using the tax returns and support Fund's auditor to provide o Tax opinions these services creates significant synergy in the form of efficiency, minimized disruption, or the ability to maintain a desired level of confidentiality. - ----------------------- --------------------------- ----------------------------------------------- - ------------------------------------- ------------------------- AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------- ------------------------- - ------------------------------------- ------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year all such services and within a specified dollar limit related fees 				 (including comparison 			 to specified dollar 			 limits) reported 			 quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for tax services not denoted as pre-approved, or to add a specific service subcategory as "pre-approved" - ------------------------------------- ------------------------- SECTION III - POLICY DETAIL, CONTINUED - ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- --------------------------- ----------------------------------------------- IV. OTHER SERVICES Services which are not o Business Risk Management support prohibited by the Rule, o Other control and regulatory A. SYNERGISTIC, if an officer of the Fund compliance projects UNIQUE QUALIFICATIONS determines that using the Fund's auditor to provide these services creates significant synergy in the form of efficiency, minimized disruption, the ability to maintain a desired level of confidentiality, or where the Fund's auditors posses unique or superior qualifications to provide these services, resulting in superior value and results for the Fund. - ----------------------- --------------------------- ----------------------------------------------- - --------------------------------------- ------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------- -------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year within all such services and a specified dollar limit related fees 			 (including comparison 			 to specified dollar 				 limits) reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for "Synergistic" or "Unique Qualifications" Other Services not denoted as pre-approved to the left, or to add a specific service subcategory as "pre-approved" - ------------------------------------- -------------------------- SECTION III - POLICY DETAIL, CONTINUED - ----------------------- ------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PROHIBITED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- ------------------------- ----------------------------------------------- PROHIBITED SERVICES Services which result 1. Bookkeeping or other services in the auditors losing related to the accounting records or independence status financial statements of the audit under the Rule. client* 2. Financial information systems design and implementation* 3. Appraisal or valuation services, fairness* opinions, or contribution-in-kind reports 4. Actuarial services (i.e., setting actuarial reserves versus actuarial audit work)* 5. Internal audit outsourcing services* 6. Management functions or human resources 7. Broker or dealer, investment advisor, or investment banking services 8. Legal services and expert services unrelated to the audit 9. Any other service that the Public Company Accounting Oversight Board determines, by regulation, is impermissible - ----------------------- ------------------------- ----------------------------------------------- - ------------------------------------------- ------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------------- ------------------------------ o These services are not to be o A summary of all performed with the exception of the(*) services and related services that may be permitted fees reported at each if they would not be subject to audit regularly scheduled procedures at the audit client (as Audit Committee meeting defined in rule 2-01(f)(4)) level will serve as continual the firm providing the service. confirmation that has 				 not provided any restricted services. - ------------------------------------------- ------------------------------ - -------------------------------------------------------------------------------- GENERAL AUDIT COMMITTEE APPROVAL POLICY: o For all projects, the officers of the Funds and the Fund's auditors will each make an assessment to determine that any proposed projects will not impair independence. o Potential services will be classified into the four non-restricted service categories and the "Approval of Audit, Audit-Related, Tax and Other Services" Policy above will be applied. Any services outside the specific pre-approved service subcategories set forth above must be specifically approved by the Audit Committee. o At least quarterly, the Audit Committee shall review a report summarizing the services by service category, including fees, provided by the Audit firm as set forth in the above policy. - -------------------------------------------------------------------------------- (2) Disclose the percentage of services described in each of paragraphs (b) through (d) of this Item that were approved by the audit committee pursuant to paragraph (c)(7)(i)(C) of Rule 2-01 of Regulation S-X. Non-Audit Services Beginning with non-audit service contracts entered into on or after May 6, 2003, the effective date of the new SEC pre-approval rules, the Funds audit committeeis required to pre-approve services to affiliates defined by SEC rules to the extent that the services are determined to have a direct impact on the operations or financial reporting of the Fund. For the fiscal year ended September 30, 2005, there we no services provided to an affiliate that required the Funds audit committee pre-approval. For the fiscal year ended September 30, 2004, $68,880 was billed to an Affiliate in Dublin for organizational assistance. (f) If greater than 50 percent, disclose the percentage of hours expended on the principal accountant's engagement to audit the registrant's financial statements for the most recent fiscal year that were attributed to work performed by persons other than the principal accountant's full-time, permanent employees. N/A (g) Disclose the aggregate non-audit fees billed by the registrant's accountant for services rendered to the registrant, and rendered to the registrant's investment adviser (not including any sub-adviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the adviser that provides ongoing services to the registrant for each of the last two fiscal years of the registrant. Aggregate Non-Audit Fees The aggregate non-audit fees for the Fund and affiliates, as previously defined, totaled approximately $50,514 in 2005 and $166,800 in 2004. These fees include services provided prior to May 6, 2003, the effective date of the pre-approval process (h) Disclose whether the registrant's audit committee of the board of trustees has considered whether the provision of non-audit services that were rendered to the registrant's investment adviser (not including any subadviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the investment adviser that provides ongoing services to the registrant that were not pre-approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. The Fund's independent auditor, Ernst & Young LLP ("E&Y"), has advised the Audit Committee of the Fund's Board of Trustees that E&Ys Spanish affiliate (E&Y Spain) performed certain non-audit work for Pioneer Global Investments Limited ("PGIL"), an affiliate of the Funds investment adviser. The services involved the receipt and disbursement of monies transferred to E&Y Spain by PGIL in payment of individual payroll and related income tax withholdings due on returns prepared by E&Y Spain for certain PGIL employees located in Spain from February 2001 to October 2005. E&Y became auditors of the Fund in May 2002. These payroll and tax services were discontinued in November 2005. The annual fee received by E&Y Spain for all such services totaled approximately 9,000 Euro per year. E&Y has informed the Audit Committee that based on its internal reviews and the de minimus nature of the services provided and fees received, E&Y does not believe its independence with respect to the Fund has been impaired or that it is disqualified from acting as independent auditors to the Fund. The Fund's audit committee of the Board of Trustees has considered whether the provision of non-audit services that were rendered to the Affiliates (as defined) that were not pre-approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. ITEMS 5-6. [RESERVED] ITEM 7. DISCLOSURE OF PROXY VOTING POLICIES AND PROCEDURES FOR CLOSED-END MANAGEMENT INVESTMENT COMPANIES. A closed-end management investment company that is filing an annual report on this Form N-CSR must, unless it invests exclusively in non-voting securities, describe the policies and procedures that it uses to determine how to vote proxies relating to portfolio securities, including the procedures that the company uses when a vote presents a conflict between the interests of its shareholders, on the one hand, and those of the company's investment adviser; principal underwriter; or any affiliated person (as defined in Section 2(a)(3) of the Investment Company Act of 1940 (15 U.S.C. 80a-2(a)(3)) and the rules thereunder) of the company, its investment adviser, or its principal underwriter, on the other. Include any policies and procedures of the company's investment adviser, or any other third party, that the company uses, or that are used on the company's behalf, to determine how to vote proxies relating to portfolio securities. Not applicable to open-end management investment companies. ITEM 8. [RESERVED] ITEM 9. CONTROLS AND PROCEDURES. (a) Disclose the conclusions of the registrant's principal executive officer or officers and principal financial officer or officers, or persons performing similar functions, about the effectiveness of the registrant's disclosure controls and procedures (as defined in Rule 30a-2(c) under the Act (17 CFR 270.30a-2(c))) based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of the report that includes the disclosure required by this paragraph. The registrant's principal executive officer and principal financial officer have concluded, that the registrant's disclosure controls and procedures are effective based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of this report. (b) Disclose whether or not there were significant changes in the registrant's internal controls or in other factors that could significantly affect these controls subsequent to the date of their evaluation, including any corrective actions with regard to significant deficiencies and material weaknesses. There were no significant changes in the registrant's internal controls or in other factors that could significantly affect these controls subsequent to the date of their evaluation, including any corrective actions with regard to significant deficiencies and material weaknesses. ITEM 10. EXHIBITS. File the exhibits listed below as part of this Form. Letter or number the exhibits in the sequence indicated. (a) Any code of ethics, or amendment thereto, that is the subject of the disclosure required by Item 2, to the extent that the registrant intends to satisfy the Item 2 requirements through filing of an exhibit. (b) A separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2 under the Act (17 CFR 270.30a-2). Filed herewith. SIGNATURES [See General Instruction F] Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized. (Registrant) Pioneer Value Fund By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr, President Date November 29, 2005 Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated. By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr., President Date November 29, 2005 By (Signature and Title)* /s/ Vincent Nave Vincent Nave, Treasurer Date November 29, 2005 * Print the name and title of each signing officer under his or her signature.