Exhibit 23 Independent Auditors' Consent To the Program Administrators of the Savings and Investment Program for Employees of Union Carbide Corporation and Participating Subsidiary Companies: We consent to incorporation by reference in the Registration Statement on Form S-8 (No. 33-58931) of Union Carbide Corporation of our report, dated May 16, 1996 relating to the statements of financial condition of the Savings and Investment Program for Employees of Union Carbide Corporation and Participating Subsidiary Companies as of December 31, 1995 and 1994 and the statements of income and changes in program equity for each of the years in the three-year period ended December 31, 1995 included in this annual report on Form 11-K. KPMG PEAT MARWICK LLP June 26, 1996 Stamford, Connecticut - 18 -