OMB APPROVAL OMB Number: 3235-0570 Expires: August 31, 2010 Estimated average burden hours per response.....18.9 UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM N-CSR CERTIFIED SHAREHOLDER REPORT OF REGISTERED MANAGEMENT INVESTMENT COMPANIES 		Investment Company Act file number 811-01835 	 Pioneer Value Fund (Exact name of registrant as specified in charter) 60 State Street, Boston, MA 02109 (Address of principal executive offices) (ZIP code) Dorothy E. Bourassa, Pioneer Investment Management, Inc., 60 State Street, Boston, MA 02109 (Name and address of agent for service) Registrant's telephone number, including area code: (617) 742-7825 Date of fiscal year end: September 30 Date of reporting period: October 1, 2007 through September 30, 2008 Form N-CSR is to be used by management investment companies to file reports with the Commission not later than 10 days after the transmission to stockholders of any report that is required to be transmitted to stockholders under Rule 30e-1 under the Investment Company Act of 1940 (17 CFR 270.30e-1). The Commission may use the information provided on Form N-CSR in its regulatory, disclosure review, inspection, and policymaking roles. A registrant is required to disclose the information specified by Form N-CSR, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-CSR unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. ss. 3507. ITEM 1. REPORTS TO SHAREOWNERS. Pioneer Value Fund Annual Report | September 30, 2008 Ticker Symbols: Class A PIOTX Class B PBOTX Class C PCOTX Class Y PVFYX [LOGO]PIONEER Investments(R) visit us: pioneerinvestments.com Table of Contents Letter to Shareowners 2 Portfolio Management Discussion 4 Portfolio Summary 8 Prices and Distributions 9 Performance Update 10 Comparing Ongoing Fund Expenses 14 Schedule of Investments 16 Financial Statements 25 Notes to Financial Statements 33 Report of Independent Registered Public Accounting Firm 41 Approval of Investment Advisory Agreement 44 Trustees, Officers and Service Providers 48 Pioneer Value Fund | Annual Report | 9/30/08 1 President's Letter Dear Shareowner, Stock and bond markets around the globe this year have experienced one of their most tumultuous periods in history. Investors have witnessed volatility of a magnitude that many have never before seen. Distance often provides the best vantage point for perspective. Still, we believe that the benefits of basic investment principles that have stood the test of time -- even in the midst of market turmoil -- cannot be underestimated. First, invest for the long term. The founder of Pioneer Investments, Philip L. Carret, began his investment career during the 1920's. One lesson he learned is that while great prosperity affords an advantageous time for selling stocks, extreme economic slumps can create opportunities for purchase. Indeed, many of our portfolio managers, who follow the value-conscious investing approach of our founder, are looking at recent market conditions as an opportunity to buy companies whose shares we believe have been unjustifiably beaten down by indiscriminate selling, but we have identified as having strong prospects over time. While investors may be facing a sustained market downturn, we continue to believe that patience, along with staying invested in the market, are important considerations for long-term investors. A second principle is to stay diversified across different types of investments. The global scope of the current market weakness poses challenges for this basic investment axiom. But the turbulence makes now a good time to reassess your portfolio and make sure that your investments continue to meet your needs. We believe you should work closely with your financial advisor to find the mix of stocks, bonds and money market assets that is best aligned to your particular risk tolerance and investment objective. As the investment markets sort through the continuing crisis in the financial industry, we are staying focused on the fundamentals and risk management. With more than 80 years of experience behind us, we have learned how to navigate turbulent markets. At Pioneer Investments, risk management has always been a critical part of our culture -- not just during periods of extraordinary volatility. Our investment process is based on fundamental research, quantitative analysis and active portfolio management. This three-pillared process, which we apply to each of our portfolios, is supported by an integrated team approach and is designed to carefully balance risk and reward. While we 2 Pioneer Value Fund | Annual Report | 9/30/08 see potential chances for making money in many corners of the market, it takes research and experience to separate solid investment opportunities from speculation. We invite you to learn more about Pioneer and our time-tested approach to investing by consulting with your financial advisor or visiting us online at www.pioneerinvestments.com. Thank you for investing with Pioneer. Respectfully, /s/ Daniel K. Kingsbury Daniel K. Kingsbury President and CEO Pioneer Investment Management USA, Inc. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of the opinion of Fund management as of the date of this report. These statements should not be relied upon for any other purposes. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Pioneer Value Fund | Annual Report | 9/30/08 3 Portfolio Management Discussion | 9/30/08 In the following discussion, Rod Wright, lead portfolio manager of Pioneer Value Fund, reviews recent market events and describes the factors that affected Pioneer Value Fund's performance during the annual reporting period ended September 30, 2008. Mr. Wright assumed the management duties of the Fund on April 30, 2008. Q How did the U.S. stock market and Pioneer Value Fund perform during the 12 months ended September 30, 2008? A U.S. equities finished the 12-month period ended September 30 deeply in the red, reflecting the unprecedented nature of the financial turmoil that characterized the latter half of the period. When the Fund's fiscal year began on October 1, 2007, the housing and subprime mortgage crisis was already several months old. Still, the consensus view at the time was that the difficulties would largely stay confined to the financial sector rather than spreading to the broader economy. The result was that while stock prices were generally volatile throughout the first half of the reporting period, by the middle of May 2008, the major U.S. indices stood only modestly off their highs of 2007. As the summer of 2008 progressed, however, a stream of negative news events began to weigh heavily on market performance. Investors had to contend with the government bailouts of Fannie Mae and Freddie Mac, the failures of Lehman Brothers and Washington Mutual, the rescue of Merrill Lynch by Bank of America, and the $85 billion emergency loan to AIG by the U.S. government. This chain of events had two important effects. First, it led investors to begin anticipating a recession and a concurrent downturn in corporate profits. Second, it sparked a wave of forced selling by hedge funds and other highly leveraged investors. With these bearish factors as the backdrop, stocks plunged in early summer, paused for approximately two months, and then collapsed in September as the 12-month reporting period was drawing to a close. On the second-to-last day of the period, the Dow Jones Industrial Average registered a 778-point drop -- one of the worst one-day declines in the 112-year history of the index. In this environment, the Russell 1000 Value Index (the Russell Index), the Fund's benchmark, returned -23.56% during the 12-month period ended September 30, 2008, while Class A shares of Pioneer Value Fund underperformed the Russell Index by a wide margin, returning -30.75% at net asset value over the same period. The Fund's return also trailed the -23.80% average return of the 569 funds in its Lipper peer group, Large-Cap Value Funds, over the same 12-month period. 4 Pioneer Value Fund | Annual Report | 9/30/08 Q What are your comments regarding the Fund's underperformance over the 12-month period ended September 30, 2008? A Pioneer is extremely disappointed with the Fund's return during the past year. Still, we believe it is important to note that since we took over the management duties of the Fund on April 30 of this year, its return has been in line with the Russell Index, as the changes we made to the portfolio helped arrest the heavy underperformance the Fund experienced in the first seven months of the period. We discuss the changes we have made to the portfolio in greater detail in the pages that follow. Looking at the Fund's results in the first half of the 12-month period, prior to the portfolio management change, the primary reason why the Fund lagged the Russell Index was its underperformance in the health care sector. Positions in the large-cap pharmaceutical stocks Schering-Plough, Merck, and Bristol-Myers Squibb all plunged during the first half of the reporting period, costing the Fund over three percentage points of performance against the Russell Index. That drop represented more than 40% of the overall 7.19% shortfall versus the benchmark for the entire annual reporting period. The Fund continues to hold reduced positions in all three stocks in its portfolio, based on our belief that the companies represent attractive values at their lower levels. The financial sector also proved to be an area of difficulty for the Fund in the first half of the reporting period and prior to April 30th. Most notably, holdings in Washington Mutual (WaMu) and First Marblehead both plummeted amid concerns about the viability of the two companies. We sold both positions upon taking over management of the Fund, which enabled it to avoid the negative impact of WaMu's eventual bankruptcy. Q What changes have you made to the Fund since taking over its management on April 30, 2008? A Our primary objective has been to halt the underperformance of the Fund by taking three steps: first, by cutting its exposure to many of its underperforming positions (such as WaMu); second, by adding higher-quality holdings to improve the overall strength of the portfolio; and third, by increasing diversification to reduce risk. Our efforts to diversify the Fund's portfolio are based on our belief that the highly concentrated nature of the Fund's investments was a key factor in its underperformance during the first half of the reporting period. During the first half of the reporting period, the Fund held fewer than 40 individual positions on average. This meant that one or two stock "blow-ups" could hurt the entire portfolio. We therefore altered the Fund's portfolio to make it more broad based, bringing its total number of holdings to 84 by the end of September 2008. At the same time, we took steps to reduce the Fund's Pioneer Value Fund | Annual Report | 9/30/08 5 risk relative to the Russell Index. While the Fund continues to emphasize and de-emphasize certain sectors, we are also making an effort to avoid putting too much of the Fund's assets into any one area of the market. Our new purchases for the Fund, meanwhile, have been stocks of companies with strong balance sheets, stable earnings power, high profit margins, and attractive valuations. Included in this group are Cardinal Health, Waste Management, Microsoft, Apache, and Applied Materials. Not all of the Fund's holdings have been winners, of course: we also invested the Fund in some stocks that have underperformed, such as the refining company Valero Energy. However, the fact that the Fund has performed in line with the Russell Index since April 30, 2008, indicates that we were largely successful in our objective of stabilizing its performance. Q Do you have any closing thoughts for investors? A We continue to hold a cautious outlook on U.S. equities due to the unprecedented nature of the financial crisis. Nevertheless, our core belief is that a focus on identifying the most reasonably valued, fundamentally sound stocks in the market should lead to outperformance in both up and down markets. We therefore believe that our conservative approach for the Fund will prove well suited not only to the difficult environment of the present, but also to the inevitable recovery. Please refer to the Schedule of Investments on pages 16-24 for a full listing of Fund securities. Investing in foreign and/or emerging markets securities involves risks relating to interest rates, currency exchange rates, economic, and political conditions. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making it more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of the opinion of Fund management as of the date of this report. These statements should not be relied upon for any other purposes. 6 Pioneer Value Fund | Annual Report | 9/30/08 Note to Shareowners: Aaron Clark, the former lead portfolio manager of Pioneer Value Fund, resigned from Pioneer Investments effective May 1, 2008. Mr. Clark had been portfolio manager of the Pioneer Value Fund since May 2006. Rod Wright, strategy director of Pioneer's large-and mid-value equity team, assumed portfolio management responsibilities. Mr. Wright had been assisting Mr. Clark. Brad Galko supports Mr. Wright as a portfolio manager of Pioneer Value Fund. The investment objective for the Fund remains the same, and Mr. Wright, Mr. Galko and the U.S. value team continue to be supported by Pioneer's global equity research team. Pioneer Value Fund | Annual Report | 9/30/08 7 Portfolio Summary | 9/30/08 Portfolio Diversification - -------------------------------------------------------------------------------- (As a percentage of total investment portfolio) [THE FOLLOWING DATA WAS REPRESENTED AS A PIE CHART IN THE PRINTED MATERIAL.] U.S. Common Stocks 89.3% Temporary Cash Investments 9.7% Depositary Receipts for International Stocks 1.0% Sector Distribution - -------------------------------------------------------------------------------- (As a percentage of equity holdings) [THE FOLLOWING DATA WAS REPRESENTED AS A PIE CHART IN THE PRINTED MATERIAL.] Financials 22.5% Energy 16.1% Health Care 11.8% Industrials 10.7% Consumer Staples 10.0% Information Technology 7.4% Consumer Discretionary 7.2% Telecommunication Services 5.4% Utilities 5.0% Materials 3.9% 10 Largest Holdings - -------------------------------------------------------------------------------- (As a percentage of equity holdings)* 1. Unum Group 4.94% 2. Chevron Corp. 4.84 3. J.P. Morgan Chase & Co. 4.03 4. General Electric Co. 3.55 5. Verizon Communications, Inc. 3.42 6. Johnson & Johnson 2.41 7. Apache Corp. 2.37 8. Bank of America Corp. 2.27 9. Exxon Mobil Corp. 2.25 10. AT&T Corp. 2.00 * This list excludes temporary cash and derivative instruments. The portfolio is actively managed, and current holdings may be different. The holdings listed should not be considered recommendations to buy or sell any security listed. 8 Pioneer Value Fund | Annual Report | 9/30/08 Prices and Distributions | 9/30/08 Net Asset Value per Share - -------------------------------------------------------------------------------- Class 9/30/08 9/30/07 A $ 11.44 $ 18.28 - -------------------------------------------------------------------------------- B $ 10.47 $ 16.87 - -------------------------------------------------------------------------------- C $ 10.43 $ 16.84 - -------------------------------------------------------------------------------- Y $ 11.54 $ 18.42 - -------------------------------------------------------------------------------- Distributions per Share: 10/1/07-9/30/08 - -------------------------------------------------------------------------------- Net Investment Short-Term Long-Term Class Income Capital Gains Capital Gains A $ 0.2548 $ 0.3474 $ 1.0272 - -------------------------------------------------------------------------------- B $ 0.0955 $ 0.3474 $ 1.0272 - -------------------------------------------------------------------------------- C $ 0.1289 $ 0.3474 $ 1.0272 - -------------------------------------------------------------------------------- Y $ 0.3038 $ 0.3474 $ 1.0272 - -------------------------------------------------------------------------------- Index Definitions - -------------------------------------------------------------------------------- The Russell 1000 Value Index measures the performance of large-cap U.S. value stocks. Index returns assume reinvestment of dividends and, unlike Fund returns, do not reflect any fees, expenses or sales charges. You cannot invest directly in an index. The index defined here pertains to the "Value of $10,000 Investment" charts on pages 10-13. Pioneer Value Fund | Annual Report | 9/30/08 9 Performance Update | 9/30/08 Class A Shares Investment Returns - -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Pioneer Value Fund at public offering price, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2008) - -------------------------------------------------------------------------------- Net Asset Public Offering Period Value (NAV) Price (POP) - -------------------------------------------------------------------------------- 10 Years 3.56% 2.94% 5 Years 3.18 1.96 1 Year -30.75 -34.75 - -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated February 1, 2008) - -------------------------------------------------------------------------------- Gross Net - -------------------------------------------------------------------------------- 0.92% 0.92% - -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL.] Value of $10,000 Investment Russell Pioneer 1000 Value Value Fund Index 9/98 9,425 10,000 10,542 11,872 9/00 12,260 12,930 11,172 11,778 9/02 9,297 9,782 11,430 12,165 9/04 13,377 14,661 15,224 17,108 9/06 16,426 19,609 19,300 22,442 9/08 13,365 17,156 Call 1-800-225-6292 or visit www.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. NAV results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. POP returns reflect deduction of maximum 5.75% sales charge. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 10 Pioneer Value Fund | Annual Report | 9/30/08 Performance Update | 9/30/08 Class B Shares Investment Returns - -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2008) - -------------------------------------------------------------------------------- If If Period Held Redeemed - -------------------------------------------------------------------------------- 10 Years 2.39% 2.39% 5 Years 2.09 2.09 1 Year -31.54 -34.02 - -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated February 1, 2008) - -------------------------------------------------------------------------------- Gross Net - -------------------------------------------------------------------------------- 2.05% 2.05% - -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL.] Value of $10,000 Investment Russell Pioneer 1000 Value Value Fund Index 9/98 10,000 10,000 11,063 11,872 9/00 12,701 12,930 11,451 11,778 9/02 9,427 9,782 11,417 12,165 9/04 13,239 14,661 14,914 17,108 9/06 15,919 19,609 18,494 22,442 9/08 12,661 17,156 Call 1-800-225-6292 or visit www.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. "If Redeemed" returns reflect the deduction of applicable contingent deferred sales charge (CDSC). Effective December 1, 2004, the period during which a CDSC is applied to withdrawals was shortened to 5 years. The maximum CDSC for Class B shares continues to be 4%. For more complete information, please see the prospectus for details. Note: Shares purchased prior to December 1, 2004 remain subject to the CDSC in effect at the time you purchased those shares. For performance information for shares purchased prior to December 1, 2004, please visit www.pioneerinvestments.com. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. Pioneer Value Fund | Annual Report | 9/30/08 11 Performance Update | 9/30/08 Class C Shares Investment Returns - -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2008) - -------------------------------------------------------------------------------- If If Period Held Redeemed - -------------------------------------------------------------------------------- 10 Years 2.39% 2.39% 5 Years 2.06 2.06 1 Year -31.49 -31.49 - -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated February 1, 2008) - -------------------------------------------------------------------------------- Gross Net - -------------------------------------------------------------------------------- 1.98% 1.98% - -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL.] Value of $10,000 Investment Russell Pioneer 1000 Value Value Fund Index 9/98 10,000 10,000 11,066 11,872 9/00 12,708 12,930 11,440 11,778 9/02 9,405 9,782 11,437 12,165 9/04 13,227 14,661 14,895 17,108 9/06 15,890 19,609 18,481 22,442 9/08 12,661 17,156 Call 1-800-225-6292 or visit www.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Class C shares held for less than one year are also subject to a 1% contingent deferred sales charge (CDSC). The performance of Class C shares does not reflect the 1% front-end sales charge in effect prior to February 1, 2004. If you paid a 1% sales charge, your returns would be lower than those shown above. "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 12 Pioneer Value Fund | Annual Report | 9/30/08 Performance Update | 9/30/08 Class Y Shares Investment Returns - -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Pioneer Value Fund, compared to that of the Russell 1000 Value Index. Average Annual Total Returns (As of September 30, 2008) - -------------------------------------------------------------------------------- If If Period Held Redeemed - -------------------------------------------------------------------------------- 10 Years 3.73% 3.73% 5 Years 3.53 3.53 1 Year -30.50 -30.50 - -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated February 1, 2008) - -------------------------------------------------------------------------------- Gross Net - -------------------------------------------------------------------------------- 0.54% 0.54% - -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL.] Value of $10,000 Investment Russell Pioneer 1000 Value Value Fund Index 9/98 10,000 10,000 11,187 11,872 9/00 13,009 12,930 11,855 11,778 9/02 9,865 9,782 12,129 12,165 9/04 14,203 14,661 16,248 17,108 9/06 17,599 19,609 20,753 22,442 9/08 14,423 17,156 Call 1-800-225-6292 or visit www.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Performance shown for periods prior to the inception of Class Y shares reflects the NAV performance of the Fund's Class A shares. The performance does not reflect differences in expenses, including the Rule 12b-1 fees, applicable to Class A shares. Since fees for Class A shares are generally higher than those of Class Y shares, the performance for Class Y shares prior to their inception (8/11/04) would have been higher. Class Y shares are not subject to sales charges and are available to limited groups of eligible investors, including institutional investors. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. Pioneer Value Fund | Annual Report | 9/30/08 13 Comparing Ongoing Fund Expenses As a shareowner in the Fund, you incur two types of costs: (1) ongoing costs, including management fees, distribution and/or service (12b-1) fees, and other Fund expenses; and (2) transaction costs, including sales charges (loads) on purchase payments. This example is intended to help you understand your ongoing expenses (in dollars) of investing in the Fund and to compare these costs with the ongoing costs of investing in other mutual funds. The example is based on an investment of $1,000 at the beginning of the Fund's latest six-month period and held throughout the six months. Using the Tables - -------------------------------------------------------------------------------- Actual Expenses The first table below provides information about actual account values and actual expenses. You may use the information in this table, together with the amount you invested, to estimate the expenses that you paid over the period as follows: 1. Divide your account value by $1,000 Example: an $8,600 account value [divided by] $1,000 = 8.6 2. Multiply the result in (1) above by the corresponding share class's number in the third row under the heading entitled "Expenses Paid During Period" to estimate the expenses you paid on your account during this period. Expenses Paid on a $1,000 Investment in Pioneer Value Fund Based on actual returns from April 1, 2008 through September 30, 2008. Share Class A B C Y Beginning Account $ 1,000.00 $ 1,000.00 $ 1,000.00 $ 1,000.00 Value on 4/1/08 - ------------------------------------------------------------------------------------- Ending Account $ 882.73 $ 876.91 $ 877.21 $ 883.55 Value on 9/30/08 - ------------------------------------------------------------------------------------- Expenses Paid $ 4.42 $ 9.57 $ 8.96 $ 2.50 During Period* - ------------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized expense ratio of 0.94%, 2.04%, 1.91% and 0.53% for Class A, Class B, Class C, and Class Y shares, respectively, multiplied by the average account value over the period, multiplied by 183/366 (to reflect the one-half year period). 14 Pioneer Value Fund | Annual Report | 9/30/08 Hypothetical Example for Comparison Purposes The table below provides information about hypothetical account values and hypothetical expenses based on the Fund's actual expense ratio and an assumed rate of return of 5% per year before expenses, which is not the Fund's actual return. The hypothetical account values and expenses may not be used to estimate the actual ending account balance or expenses you paid for the period. You may use this information to compare the ongoing costs of investing in the Fund and other funds. To do so, compare this 5% hypothetical example with the 5% hypothetical examples that appear in the shareholder reports of the other funds. Please note that the expenses shown in the tables are meant to highlight your ongoing costs only and do not reflect any transaction costs, such as sales charges (loads) that are charged at the time of the transaction. Therefore, the table below is useful in comparing ongoing costs only and will not help you determine the relative total costs of owning different funds. In addition, if these transaction costs were included, your costs would have been higher. Expenses Paid on a $1,000 Investment in Pioneer Value Fund Based on a hypothetical 5% return per year before expenses, reflecting the period from April 1, 2008 through September 30, 2008. Share Class A B C Y Beginning Account $ 1,000.00 $ 1,000.00 $ 1,000.00 $ 1,000.00 Value on 4/1/08 - ------------------------------------------------------------------------------------- Ending Account $ 1,020.30 $ 1,014.80 $ 1,015.45 $ 1,022.35 Value on 9/30/08 - ------------------------------------------------------------------------------------- Expenses Paid $ 4.75 $ 10.28 $ 9.62 $ 2.68 During Period* - ------------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized expense ratio of 0.94%, 2.04%, 1.91%, and 0.53%, for Class A, Class B, Class C, and Class Y shares, respectively, multiplied by the average account value over the period, multiplied by 183/366 (to reflect the one-half year period). Pioneer Value Fund | Annual Report | 9/30/08 15 Schedule of Investments | 9/30/08 Shares Value COMMON STOCKS -- 97.4% ENERGY -- 15.7% Integrated Oil & Gas -- 8.8% 1,266,125 Chevron Corp. $ 104,429,990 352,200 ConocoPhillips 25,798,650 626,300 Exxon Mobil Corp. 48,638,458 416,900 USX-Marathon Group, Inc. 16,621,803 --------------- $ 195,488,901 - -------------------------------------------------------------------------------------- Oil & Gas Equipment & Services -- 1.0% 883,400 Weatherford International, Inc.*(b) $ 22,208,676 - -------------------------------------------------------------------------------------- Oil & Gas Exploration & Production -- 4.2% 491,100 Apache Corp. $ 51,211,908 352,100 Devon Energy Corp. 32,111,520 200,058 XTO Energy, Inc. 9,306,698 --------------- $ 92,630,126 - -------------------------------------------------------------------------------------- Oil & Gas Refining & Marketing -- 0.4% 300,000 Valero Energy Corp. $ 9,090,000 - -------------------------------------------------------------------------------------- Oil & Gas Storage & Transportation -- 1.3% 2,229,500 El Paso Corp. (b) $ 28,448,420 --------------- Total Energy $ 347,866,123 - -------------------------------------------------------------------------------------- MATERIALS -- 3.8% Aluminum -- 0.3% 300,000 Alcoa, Inc. (b) $ 6,774,000 - -------------------------------------------------------------------------------------- Diversified Chemical -- 1.5% 1,000,000 Dow Chemical Co. $ 31,780,000 - -------------------------------------------------------------------------------------- Diversified Metals & Mining -- 0.9% 166,700 Freeport-McMoRan Copper & Gold, Inc. (Class B) (b) $ 9,476,895 370,000 Teck Cominco, Ltd. (Class B) (b) 10,774,400 --------------- $ 20,251,295 - -------------------------------------------------------------------------------------- Gold -- 1.1% 304,400 Agnico Eagle Mines, Ltd. $ 16,763,308 192,466 Newmont Mining Corp. (b) 7,459,982 --------------- $ 24,223,290 --------------- Total Materials $ 83,028,585 - -------------------------------------------------------------------------------------- CAPITAL GOODS -- 8.5% Aerospace & Defense -- 2.9% 550,000 Northrop Grumman Corp.* $ 33,297,000 497,800 United Technologies Corp. 29,897,868 --------------- $ 63,194,868 - -------------------------------------------------------------------------------------- Electrical Component & Equipment -- 0.3% 175,000 Rockwell International Corp. $ 6,534,500 - -------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 16 Pioneer Value Fund | Annual Report | 9/30/08 Shares Value Industrial Conglomerates -- 5.3% 600,000 3M Co. $ 40,986,000 3,000,000 General Electric Co. 76,500,000 --------------- $ 117,486,000 --------------- Total Capital Goods $ 187,215,368 - ------------------------------------------------------------------------ COMMERCIAL SERVICES & SUPPLIES -- 1.1% Environmental & Facilities Services -- 1.1% 791,100 Waste Management, Inc.*(b) $ 24,911,739 --------------- Total Commercial Services & Supplies $ 24,911,739 - ------------------------------------------------------------------------ TRANSPORTATION -- 0.8% Railroads -- 0.8% 264,803 Norfolk Southern Corp. $ 17,532,607 --------------- Total Transportation $ 17,532,607 - ------------------------------------------------------------------------ AUTOMOBILES & COMPONENTS -- 0.8% Auto Parts & Equipment -- 0.8% 594,300 Johnson Controls, Inc. $ 18,025,119 --------------- Total Automobiles & Components $ 18,025,119 - ------------------------------------------------------------------------ MEDIA -- 3.7% Broadcasting -- 0.8% 1,255,000 CBS Corp. (Class B) (b) $ 18,297,900 - ------------------------------------------------------------------------ Movies & Entertainment -- 2.9% 1,200,000 The Walt Disney Co. (b) $ 36,828,000 1,069,100 Viacom, Inc. (Class B)* 26,556,444 --------------- $ 63,384,444 --------------- Total Media $ 81,682,344 - ------------------------------------------------------------------------ RETAILING -- 2.5% Apparel Retail -- 1.3% 165,500 Abercrombie & Fitch Co. (b) $ 6,528,975 1,200,000 Gap, Inc. (b) 21,336,000 --------------- $ 27,864,975 - ------------------------------------------------------------------------ Department Stores -- 0.5% 349,700 J.C. Penney Co., Inc. $ 11,658,998 - ------------------------------------------------------------------------ Home Improvement Retail -- 0.7% 600,000 Home Depot, Inc. $ 15,534,000 --------------- Total Retailing $ 55,057,973 - ------------------------------------------------------------------------ FOOD & DRUG RETAILING -- 3.0% Drug Retail -- 0.6% 401,000 CVS Corp. $ 13,497,660 - ------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 17 Schedule of Investments | 9/30/08 (continued) Shares Value Food Retail -- 1.1% 680,770 Kroger Co. $ 18,707,560 224,400 Safeway, Inc. 5,322,768 --------------- $ 24,030,328 - -------------------------------------------------------------------------- Hypermarkets & Supercenters -- 1.3% 466,600 Wal-Mart Stores, Inc. (b) $ 27,944,674 --------------- Total Food & Drug Retailing $ 65,472,662 - -------------------------------------------------------------------------- FOOD, BEVERAGE & TOBACCO -- 6.8% Packaged Foods & Meats -- 2.0% 376,838 General Mills, Inc. $ 25,896,307 536,400 Kraft Foods, Inc. 17,567,100 --------------- $ 43,463,407 - -------------------------------------------------------------------------- Soft Drinks -- 1.1% 475,000 Coca-Cola Co. $ 25,118,000 - -------------------------------------------------------------------------- Tobacco -- 3.7% 1,458,336 Altria Group, Inc. $ 28,933,386 343,800 Lorillard, Inc. 24,461,370 600,000 Phillip Morris International, Inc. 28,860,000 --------------- $ 82,254,756 --------------- Total Food, Beverage & Tobacco $ 150,836,163 - -------------------------------------------------------------------------- HEALTH CARE EQUIPMENT & SERVICES -- 4.4% Health Care Distributors -- 0.3% 110,400 Cardinal Health, Inc. $ 5,440,512 - -------------------------------------------------------------------------- Health Care Equipment -- 2.0% 600,700 Medtronic, Inc. $ 30,095,070 234,600 Zimmer Holdings, Inc.* 15,145,776 --------------- $ 45,240,846 - -------------------------------------------------------------------------- Managed Health Care -- 2.1% 457,600 Aetna, Inc. $ 16,523,936 477,800 CIGNA Corp.* 16,235,644 301,100 Wellpoint, Inc.* 14,082,447 --------------- $ 46,842,027 --------------- Total Health Care Equipment & Services $ 97,523,385 - -------------------------------------------------------------------------- PHARMACEUTICALS & BIOTECHNOLOGY -- 7.1% Biotechnology -- 1.2% 445,800 Amgen, Inc.* $ 26,422,566 - -------------------------------------------------------------------------- Life Sciences Tools & Services -- 0.8% 330,800 Thermo Fisher Scientific, Inc.* $ 18,194,000 - -------------------------------------------------------------------------- Pharmaceuticals -- 5.1% 1,000,000 Bristol-Myers Squibb Co. $ 20,850,000 749,576 Johnson & Johnson 51,930,625 The accompanying notes are an integral part of these financial statements. 18 Pioneer Value Fund | Annual Report | 9/30/08 Shares Value Pharmaceuticals -- (continued) 750,000 Merck & Co., Inc. $ 23,670,000 863,300 Schering-Plough Corp. 15,945,151 --------------- $ 112,395,776 --------------- Total Pharmaceuticals & Biotechnology $ 157,012,342 - ------------------------------------------------------------------------- BANKS -- 4.0% Diversified Banks -- 0.7% 400,000 Wells Fargo & Co. (b) $ 15,012,000 - ------------------------------------------------------------------------- Regional Banks -- 2.7% 423,000 PNC Bank Corp. (b) $ 31,598,100 323,900 SunTrust Banks, Inc. (b) 14,572,261 350,000 Zions Bancorporation (b) 13,545,000 --------------- $ 59,715,361 - ------------------------------------------------------------------------- Thrifts & Mortgage Finance -- 0.6% 861,000 New York Community Bancorp, Inc. (b) $ 14,438,970 --------------- Total Banks $ 89,166,331 - ------------------------------------------------------------------------- DIVERSIFIED FINANCIALS -- 11.1% Asset Management & Custody Banks -- 3.9% 330,700 Franklin Resources, Inc. $ 29,144,591 1,448,966 Invesco, Ltd. 30,399,307 500,000 Legg Mason, Inc. (b) 19,030,000 250,000 The Bank of New York Mellon Corp. 8,145,000 --------------- $ 86,718,898 - ------------------------------------------------------------------------- Diversified Financial Services -- 6.1% 1,400,000 Bank of America Corp. (b) $ 49,000,000 1,859,364 J.P. Morgan Chase & Co. 86,832,299 --------------- $ 135,832,299 - ------------------------------------------------------------------------- Specialized Finance -- 1.1% 65,800 CME Group, Inc. (b) $ 24,445,358 --------------- Total Diversified Financials $ 246,996,555 - ------------------------------------------------------------------------- INSURANCE -- 6.7% Life & Health Insurance -- 5.3% 270,100 Lincoln National Corp. $ 11,562,981 4,250,000 Unum Group (b) 106,675,000 --------------- $ 118,237,981 - ------------------------------------------------------------------------- Property & Casualty Insurance -- 1.4% 559,800 Chubb Corp. $ 30,733,020 --------------- Total Insurance $ 148,971,001 - ------------------------------------------------------------------------- SOFTWARE & SERVICES -- 1.2% Systems Software -- 1.2% 982,700 Microsoft Corp. $ 26,228,263 --------------- Total Software & Services $ 26,228,263 - ------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 19 Schedule of Investments | 9/30/08 (continued) Shares Value TECHNOLOGY HARDWARE & EQUIPMENT -- 4.2% Communications Equipment -- 1.5% 727,200 Corning, Inc. $ 11,373,408 1,245,000 Nokia Corp. (A.D.R.) (b) 23,219,250 --------------- $ 34,592,658 - ------------------------------------------------------------------------- Computer Hardware -- 2.7% 1,000,000 Dell, Inc.* $ 16,480,000 531,915 Hewlett-Packard Co. 24,595,750 155,200 IBM Corp.* 18,152,192 --------------- $ 59,227,942 --------------- Total Technology Hardware & Equipment $ 93,820,600 - ------------------------------------------------------------------------- SEMICONDUCTORS -- 1.8% Semiconductor Equipment -- 1.0% 1,515,000 Applied Materials, Inc. $ 22,921,950 - ------------------------------------------------------------------------- Semiconductors -- 0.8% 926,800 Intel Corp. $ 17,358,964 --------------- Total Semiconductors $ 40,280,914 - ------------------------------------------------------------------------- TELECOMMUNICATION SERVICES -- 5.3% Integrated Telecommunication Services -- 5.3% 1,542,900 AT&T Corp. $ 43,077,767 2,300,000 Verizon Communications, Inc. 73,807,000 --------------- $ 116,884,767 --------------- Total Telecommunication Services $ 116,884,767 - ------------------------------------------------------------------------- UTILITIES -- 4.9% Electric Utilities -- 1.7% 486,900 Edison International LLC $ 19,427,310 272,700 Firstenergy Corp. 18,268,173 --------------- $ 37,695,483 - ------------------------------------------------------------------------- Gas Utilities -- 0.6% 308,200 Questar Corp. $ 12,611,544 - ------------------------------------------------------------------------- Independent Power Producer & Energy Traders -- 0.5% 451,000 NRG Energy, Inc.*(b) $ 11,162,250 - ------------------------------------------------------------------------- Multi-Utilities -- 2.1% 543,300 Public Service Enterprise Group, Inc. $ 17,814,807 584,200 Sempra Energy (b) 29,484,574 --------------- $ 47,299,381 --------------- Total Utilities $ 108,768,658 - ------------------------------------------------------------------------- TOTAL COMMON STOCKS (Cost $2,280,735,852) $ 2,157,281,499 - ------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 20 Pioneer Value Fund | Annual Report | 9/30/08 Principal Amount Value TEMPORARY CASH INVESTMENTS -- 10.5% Repurchase Agreement -- 1.3% $ 5,975,000 Bank of America, 0.5%, dated 9/30/08, repurchase price of $5,975,000 plus accrued interest on 10/1/08 collateralized by the following: $2,816,894 U.S. Treasury Bill, 0.0%, 1/15/09 $3,123,619 U.S. Treasury Note, 3.875%, 5/15/10 $ 5,975,000 5,975,000 Bank of America, 1.80%, dated 9/30/08, repurchase price of $5,975,000 plus accrued interest on 10/1/08 collateralized by $6,608,569 Freddie Mac Giant, 5.5%, 1/1/38 5,975,000 5,980,000 Barclays Plc, 2.25%, dated 9/30/08, repurchase price of $5,980,000 plus accrued interest on 10/1/08 collateralized by the following: $7,317,646 Federal National Mortgage Association, 5.0%, 3/1/21 - 2/1/36 $888,612 Freddie Mac Giant, 5.0%, 8/1/36 5,980,000 5,980,000 Deutsche Bank, 2.25%, dated 9/30/08, repurchase price of $5,980,000 plus accrued interest on 10/1/08 collateralized by the following: $2,655,966 Freddie Mac Giant, 5.0 - 7.5%, 10/1/18 - 9/1/38 $104,310 Federal Home Loan Mortgage Corp., 6.591%, 2/1/37 $320,705 Federal National Mortgage Association (ARM), 4.574 - 5.502%, 10/1/15 - 5/1/36 $5,645,856 Federal National Mortgage Association, 5.0 - 7.0%, 5/1/20 - 9/1/47 5,980,000 5,975,000 JP Morgan Chase & Co., 1.70%, dated 9/30/08, repurchase price of $5,975,000 plus accrued interest on 10/1/08 collateralized by $6,787,563 Federal National Mortgage Association, 4.5 - 6.5%, 6/1/23 - 9/1/38 5,975,000 --------------- $ 29,885,000 - ------------------------------------------------------------------------------------------------ Shares Securities Lending Collateral -- 9.2% (c) Certificates of Deposit: 3,524,508 Citibank, 2.73%, 10/30/08 $ 3,524,508 3,524,508 Abbey National Plc, 3.15%, 8/13/09 3,524,508 3,526,177 Banco Santander NY, 3.09%, 12/22/08 3,526,177 3,523,673 Bank of Nova Scotia, 3.18%, 5/5/09 3,523,673 1,268,440 Bank of Scotland NY, 2.89%, 11/4/08 1,268,440 5,628,404 Bank of Scotland NY, 3.03%, 6/5/09 5,628,404 6,344,114 Barclays Bank, 3.18%, 5/27/09 6,344,114 7,049,015 BNP Paribas NY, 2.72% 11/3/08 7,049,015 703,952 Calyon NY, 2.69%, 1/16/09 703,952 415,266 Calyon NY, 2.69%, 1/16/09 415,266 6,344,114 DNB NOR Bank ASA NY, 2.9%, 6/8/09 6,344,114 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 21 Schedule of Investments | 9/30/08 (continued) Shares Value Certificates of Deposit -- (continued): 6,456,898 Intesa SanPaolo S.p.A., 2.72%, 5/22/09 $ 6,456,898 407,767 NORDEA NY, 2.72%, 4/9/09 407,767 338,122 NORDEA NY, 2.73%, 12/1/08 338,122 5,286,762 Royal Bank of Canada NY, 3.0%, 8/7/09 5,286,762 3,524,508 Bank of Scotland NY, 3.06%, 3/5/09 3,524,508 2,115,097 Bank of Scotland NY, 2.96%, 11/3/08 2,115,095 703,877 Skandinavian Enskilda Bank NY, 3.06%, 2/13/09 703,877 6,344,114 Svenska Bank NY, 2.7%, 7/8/09 6,344,114 2,114,705 Toronto Dominion Bank NY, 2.75%, 11/5/08 2,114,705 3,524,508 Wachovia Corp., 2.79%, 10/30/08 3,524,508 ------------- $ 72,668,527 ------------------------------------------------------------------------------- Commercial Paper: 6,922,133 American Honda Finance Corp., 2.92%, 7/14/09 $ 6,922,133 7,030,991 ANZ Bank, 2.64%, 11/5/08 7,030,991 7,049,015 Commonwealth Bank Australia, 3.02%, 7/16/09 7,049,015 702,701 Dexdel, 2.7%, 11/10/08 702,701 7,015,215 JP Morgan Chase & Co., 1.42%, 12/3/08 7,015,215 703,073 Met Life, Inc., 2.7%, 11/3/08 703,073 2,114,535 John Deere Capital Corp., 2.82%, 12/12/08 2,114,535 7,049,015 HSBC USA, Inc., 3.2%, 8/14/09 7,049,015 7,049,015 Monumental Global Funding, Ltd., 3.2%, 8/17/09 7,049,015 6,344,114 New York Life Global, 2.98%, 9/4/09 6,344,114 671,128 Bank Bovespa NY, 2.79%, 3/12/09 671,128 3,171,688 General Electric Capital Corp., 4.24%, 1/5/09 3,171,688 3,523,671 General Electric Capital Corp., 2.82%, 3/16/09 3,523,671 3,524,508 CME Group, Inc., 3.0%, 8/6/09 3,524,508 1,303,661 IBM, 3.18%, 2/13/09 1,303,661 3,524,508 IBM, 3.18%, 6/26/09 3,524,508 6,344,114 Met Life Global Funding, 3.19%, 6/12/09 6,344,114 3,522,760 Macquarie Bank, Ltd., 2.55%, 10/8/08 3,522,760 3,522,760 Macquarie Bank, Ltd., 2.55%, 10/8/08 3,522,760 7,049,015 Societe Generale, 3.28%, 9/4/09 7,049,015 7,049,015 U.S. Bank, 2.912%, 8/24/09 7,049,015 704,553 Wachovia Corp., 2.85%, 10/28/08 704,553 5,991,663 Westpac Banking Corp., 3.74%, 6/1/09 5,991,663 ------------- $ 101,882,851 ------------------------------------------------------------------------------- Tri-party Repurchase Agreements: 14,098,031 ABN Amro, 1.85%, 10/1/08 $ 14,098,031 7,891,373 Barclays Capital Markets, 2.11%, 10/1/08 7,891,373 5,870,138 Deutsche Bank, 2.0%, 10/1/08 5,870,138 ------------- $ 27,859,542 ------------------------------------------------------------------------------- Other: 781,224 ABS CFAT 2008-A A1, 3.005%, 4/27/09 $ 781,224 ------------- Total Securities Lending Collateral $ 203,192,144 ------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 22 Pioneer Value Fund | Annual Report | 9/30/08 Shares Value TOTAL TEMPORARY CASH INVESTMENTS (Cost $233,077,144) $ 233,077,144 - ---------------------------------------------------------------------- TOTAL INVESTMENT IN SECURITIES -- 107.9% (Cost $2,513,812,996) (a) $2,390,358,643 - ---------------------------------------------------------------------- OTHER ASSETS AND LIABILITIES -- (7.9%) $ (174,384,404) - ---------------------------------------------------------------------- TOTAL NET ASSETS -- 100.0% $2,215,974,239 - ---------------------------------------------------------------------- * Non-income producing security. (A.D.R.) American Depositary Receipt. (a) At September 30, 2008, the net unrealized loss on investments based on cost for federal income tax purposes of $2,517,407,272 was as follows: Aggregate gross unrealized gain for all investments in which there is an excess of value over tax cost $ 116,589,704 Aggregate gross unrealized loss for all investments in which there is an excess of tax cost over value (243,638,333) ------------- Net unrealized loss $(127,048,629) ------------- (b) At September 30, 2008, the following securities were out on loan: Shares Description Value 51,700 Abercrombie & Fitch Co. $2,039,565 23,000 Alcoa, Inc. 519,340 784,400 Bank of America Corp. 27,454,000 1,172,000 CBS Corp. (Class B) 17,087,760 28,000 CME Group, Inc. 10,402,280 234,000 El Paso Corp. 2,985,840 270,000 Freeport-McMoRan Copper & Gold, Inc. (Class B)** 15,349,500 15,700 Gap, Inc. 279,146 10,000 Legg Mason, Inc. 380,600 140,000 New York Community Bancorp, Inc. 2,347,800 175,000 Newmont Mining Corp. 6,783,000 130,000 Nokia Corp. (A.D.R.) 2,424,500 321,675 NRG Energy, Inc.* 7,961,456 1,100 PNC Bank Corp. 82,170 417,000 Sempra Energy 21,045,990 320,000 SunTrust Banks, Inc. 14,396,800 75,000 Teck Cominco (Class B) 2,184,000 29,300 Unum Group 735,430 44,200 Wal-Mart Stores, Inc. 2,647,138 738,000 The Walt Disney Co. 22,649,220 715,000 Waste Management, Inc.* 22,515,350 The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 23 Schedule of Investments | 9/30/08 (continued) Shares Description Value 456,300 Weatherford International, Inc.* $ 11,471,382 50,000 Wells Fargo & Co. 1,876,500 381,900 Zions Bancorporation** 14,779,530 - ---------------------------------------------------------------- Total $210,398,297 - ---------------------------------------------------------------- ** Pending sale at 9/30/08. (c) Security lending collateral is managed by Credit Suisse. Purchases and sales of securities (excluding temporary cash investments) for the year ended September 30, 2008 aggregated $2,740,285,326 and $3,270,840,962, respectively. The accompanying notes are an integral part of these financial statements. 24 Pioneer Value Fund | Annual Report | 9/30/08 Statement of Assets and Liabilities | 9/30/08 ASSETS: Investment in securities, at value (including securities loaned of $210,398,297) (cost $2,513,812,996) $2,390,358,643 Cash 3,832,457 Receivables -- Investment securities sold 28,461,507 Fund shares sold 129,309 Dividends, interest and foreign taxes withheld 4,310,178 Other 1,192,125 - --------------------------------------------------------------------------------------- Total assets $2,428,284,219 - --------------------------------------------------------------------------------------- LIABILITIES: Payables -- Investment securities purchased $ 5,220,386 Fund shares repurchased 3,217,000 Upon return of securities loaned 203,192,144 Due to affiliates 387,282 Accrued expenses 293,168 - --------------------------------------------------------------------------------------- Total liabilities $ 212,309,980 - --------------------------------------------------------------------------------------- NET ASSETS: Paid-in capital $2,653,620,196 Undistributed net investment income 19,126,106 Accumulated net realized loss on investments and foreign currency transactions (333,317,710) Net unrealized loss on investments (123,454,353) - --------------------------------------------------------------------------------------- Total net assets $2,215,974,239 - --------------------------------------------------------------------------------------- NET ASSET VALUE PER SHARE: (No par value, unlimited number of shares authorized) Class A (based on $2,082,426,599/182,109,497 shares) $ 11.44 Class B (based on $13,518,127/1,291,120 shares) $ 10.47 Class C (based on $7,458,323/715,054 shares) $ 10.43 Class Y (based on $112,571,190/9,752,882 shares) $ 11.54 MAXIMUM OFFERING PRICE: Class A ($11.44 [divided by] 94.25%) $ 12.14 - --------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 25 Statement of Operations For the Year Ended 9/30/08 INVESTMENT INCOME: Dividends (net of foreign taxes withheld of $144,502) $ 72,888,325 Interest 4,868,603 Income from securities loaned, net 821,725 - -------------------------------------------------------------------------------------------------- Total investment income $ 78,578,653 - -------------------------------------------------------------------------------------------------- EXPENSES: Management fees Basic Fee $ 17,655,287 Performance Adjustment (3,776,033) Transfer agent fees and expenses Class A 4,553,211 Class B 110,593 Class C 38,375 Class Y 2,678 Distribution fees Class A 6,771,036 Class B 211,119 Class C 97,902 Administrative fees 662,633 Custodian fees 99,374 Registration fees 71,573 Professional fees 258,948 Printing expense 21,989 Fees and expenses of nonaffiliated trustees 86,641 Miscellaneous 448,487 - -------------------------------------------------------------------------------------------------- Total expenses $ 27,313,813 Less fees paid indirectly (94,412) - -------------------------------------------------------------------------------------------------- Net expenses $ 27,219,401 - -------------------------------------------------------------------------------------------------- Net investment income $ 51,359,252 - -------------------------------------------------------------------------------------------------- REALIZED AND UNREALIZED GAIN (LOSS) ON INVESTMENTS, OPTIONS AND FOREIGN CURRENCY TRANSACTIONS: Net realized gain (loss) on: Investments $(318,668,552) Written options closed/expired 798,845 Forward foreign currency contracts and other assets and liabilities denominated in foreign currencies 23,850 $ (317,845,857) - -------------------------------------------------------------------------------------------------- Change in net unrealized gain (loss) on: Investments $(822,333,275) Forward foreign currency contracts and other assets and liabilities denominated in foreign currencies (14,994) $ (822,348,269) - -------------------------------------------------------------------------------------------------- Net loss on investments, options and foreign currency transactions $(1,140,194,126) - -------------------------------------------------------------------------------------------------- Net decrease in net assets resulting from operations $(1,088,834,874) - -------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 26 Pioneer Value Fund | Annual Report | 9/30/08 Statements of Changes in Net Assets For the Years Ended 9/30/08 and 9/30/07, respectively Year Ended Year Ended 9/30/08 9/30/07 FROM OPERATIONS: Net investment income $ 51,359,252 $ 71,375,830 Net realized gain (loss) on investments, redemptions in kind, options and foreign currency transactions (317,845,857) 459,589,158 Change in net unrealized gain (loss) on investments and foreign currency transactions (822,348,269) 169,437,699 - ------------------------------------------------------------------------------------------------------- Net increase (decrease) in net assets resulting from operations $ (1,088,834,874) $ 700,402,687 - ------------------------------------------------------------------------------------------------------- DISTRIBUTIONS TO SHAREOWNERS: Net investment income: Class A ($0.25 and $0.30 per share, respectively) $ (50,294,291) $ (65,887,777) Class B ($0.10 and $0.12 per share, respectively) (160,860) (255,486) Class C ($0.13 and $0.13 per share, respectively) (97,670) (77,440) Class Y ($0.30 and $0.37 per share, respectively) (3,580,443) (6,699,766) Net realized gain: Class A ($1.37 and $2.86 per share, respectively) (261,794,286) (575,019,963) Class B ($1.37 and $2.86 per share, respectively) (2,352,305) (5,835,262) Class C ($1.37 and $2.86 per share, respectively) (999,619) (1,444,227) Investor Class ($0.00 and $2.86 per share, respectively) -- (18,158,124) Class R ($0.00 and $2.86 per share, respectively) -- (17,330) Class Y ($1.37 and $2.86 per share, respectively) (16,900,631) (50,100,370) - ------------------------------------------------------------------------------------------------------- Total distributions to shareowners $ (336,180,105) $ (723,495,745) - ------------------------------------------------------------------------------------------------------- FROM FUND SHARE TRANSACTIONS: Net proceeds from sale of shares $ 107,788,885 $ 215,579,676 Reinvestment of distributions 307,535,467 652,094,865 Cost of shares repurchased (624,773,394) (1,009,087,609) Redemption in kind -- (337,791,016) - ------------------------------------------------------------------------------------------------------- Net decrease in net assets resulting from fund share transactions $ (209,449,042) $ (479,204,084) - ------------------------------------------------------------------------------------------------------- Net decrease in net assets $ (1,634,464,021) $ (502,297,142) NET ASSETS: Beginning of year 3,850,438,260 4,352,735,402 - ------------------------------------------------------------------------------------------------------- End of year $ 2,215,974,239 $ 3,850,438,260 - ------------------------------------------------------------------------------------------------------- Undistributed net investment income $ 19,126,106 $ 21,888,750 - ------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 27 Statements of Changes in Net Assets (continued) '08 Shares '08 Amount '07 Shares '07 Amount Class A Shares sold 4,706,766 $ 67,233,587 8,108,936 $ 141,919,949 Reinvestment of distributions 18,863,164 293,192,504 35,934,857 600,068,674 Conversion of Investors Class Shares to Class A Shares -- -- 7,261,950 122,145,998 Less shares repurchased (36,761,033) (518,107,787) (45,254,581) (805,326,623) Redemptions in Kind -- -- (18,498,960) (337,791,016) - --------------------------------------------------------------------------------------------------------------- Net decrease (13,191,103) $(157,681,696) (12,447,798) $(278,983,018) - --------------------------------------------------------------------------------------------------------------- Class B Shares sold 119,790 $ 1,563,555 174,034 $ 2,871,887 Reinvestment of distributions 159,868 2,297,706 361,010 5,547,350 Less shares repurchased (789,625) (10,137,455) (872,578) (14,236,202) - --------------------------------------------------------------------------------------------------------------- Net decrease (509,967) $ (6,276,194) (337,534) $ (5,816,965) - --------------------------------------------------------------------------------------------------------------- Class C Shares sold 204,198 $ 2,638,167 348,047 $ 5,613,238 Reinvestment of distributions 50,044 715,039 88,811 1,362,885 Less shares repurchased (287,970) (3,701,993) (191,383) (3,124,518) - --------------------------------------------------------------------------------------------------------------- Net increase (decrease) (33,728) $ (348,787) 245,475 $ 3,851,605 - --------------------------------------------------------------------------------------------------------------- Investor Class (a) Shares sold -- -- 23 $ 384 Reinvestment of distributions -- -- 1,000,967 16,646,079 Conversion of Investors Class Shares to Class A Shares -- -- (7,254,000) (122,145,998) Less shares repurchased -- -- (217,458) (3,941,403) - --------------------------------------------------------------------------------------------------------------- Net decrease -- -- (6,470,468) $(109,440,938) - --------------------------------------------------------------------------------------------------------------- Class R (b) Shares sold -- -- 661 $ 11,290 Reinvestment of distributions -- -- 1,093 17,328 Less shares repurchased -- -- (7,588) (123,431) - --------------------------------------------------------------------------------------------------------------- Net decrease -- -- (5,834) $ (94,813) - --------------------------------------------------------------------------------------------------------------- Class Y Shares sold 2,572,286 $ 36,353,576 3,748,773 $ 65,162,928 Reinvestment of distributions 719,630 11,330,218 1,692,101 28,452,549 Less shares repurchased (6,480,001) (92,826,159) (10,387,401) (182,335,432) - --------------------------------------------------------------------------------------------------------------- Net decrease (3,188,085) $ (45,142,365) (4,946,527) $ (88,719,955) - --------------------------------------------------------------------------------------------------------------- (a) Investor Class shares converted to Class A shares on December 10, 2006. (b) Class R shares ceased operations on January 31, 2007. The accompanying notes are an integral part of these financial statements. 28 Pioneer Value Fund | Annual Report | 9/30/08 Financial Highlights Year Year Ended Ended 9/30/08 9/30/07 Class A Net asset value, beginning of period $ 18.28 $ 18.55 - ----------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.25 $ 0.29 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions (5.47) 2.60 - ----------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ (5.22) $ 2.89 Distributions to shareowners: Net investment income (0.25) (0.30) Net realized gain (1.37) (2.86) - ----------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (6.84) $ (0.27) - ----------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 11.44 $ 18.28 - ----------------------------------------------------------------------------------------------------------------- Total return* (30.75)% 17.49% Ratio of net expenses to average net assets+ 0.94% 0.92% Ratio of net investment income to average net assets+ 1.73% 1.65% Portfolio turnover rate 95% 34% Net assets, end of period (in thousands) $2,082,427 $3,569,146 Ratios with reduction for fees paid indirectly: Net expenses 0.94% 0.92% Net investment income 1.73% 1.65% - ----------------------------------------------------------------------------------------------------------------- Year Year Year Ended Ended Ended 9/30/06 9/30/05 9/30/04 Class A Net asset value, beginning of period $ 17.55 $ 18.83 $ 16.25 - ------------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.28 $ 0.14 $ 0.14 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions 1.09 2.26 2.62 - ------------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.37 $ 2.40 $ 2.76 Distributions to shareowners: Net investment income (0.25) (0.12) (0.14) Net realized gain (0.12) (3.56) (0.04) - ------------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 1.00 $ (1.28) $ 2.58 - ------------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 18.55 $ 17.55 $ 18.83 - ------------------------------------------------------------------------------------------------------------------------------- Total return* 7.89% 13.81% 17.04% Ratio of net expenses to average net assets+ 0.94% 0.98% 1.02% Ratio of net investment income to average net assets+ 1.44% 0.85% 0.72% Portfolio turnover rate 86% 53% 40% Net assets, end of period (in thousands) $3,852,832 $3,997,849 $3,745,950 Ratios with reduction for fees paid indirectly: Net expenses 0.94% 0.97% 1.02% Net investment income 1.44% 0.86% 0.72% - ------------------------------------------------------------------------------------------------------------------------------- * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 29 Financial Highlights (continued) Year Year Ended Ended 9/30/08 9/30/07 Class B Net asset value, beginning of period $ 16.87 $ 17.36 - ------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income (loss) $ 0.11 $ 0.10 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions (5.04) 2.39 - ------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ (4.93) $ 2.49 Distributions to shareowners: Net investment income (0.10) (0.12) Net realized gain (1.37) (2.86) - ------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (6.40) $ (0.49) - ------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 10.47 $ 16.87 - ------------------------------------------------------------------------------------------------------------- Total return* (31.54)% 16.18% Ratio of net expenses to average net assets+ 2.06% 2.05% Ratio of net investment income (loss) to average net assets+ 0.60% 0.53% Portfolio turnover rate 95% 34% Net assets, end of period (in thousands) $ 13,518 $ 30,378 Ratios with reduction for fees paid indirectly: Net expenses 2.04% 2.02% Net investment income (loss) 0.62% 0.56% - ------------------------------------------------------------------------------------------------------------- Year Year Year Ended Ended Ended 9/30/06 9/30/05 9/30/04 Class B Net asset value, beginning of period $ 16.40 $ 17.87 $ 15.45 - ------------------------------------------------------------------------------------------------------------------------ Increase (decrease) from investment operations: Net investment income (loss) $ 0.10 $ (0.04) $ (0.04) Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions 1.00 2.13 2.50 - ------------------------------------------------------------------------------------------------------------------------ Net increase (decrease) from investment operations $ 1.10 $ 2.09 $ 2.46 Distributions to shareowners: Net investment income (0.02) -- -- Net realized gain (0.12) (3.56) (0.04) - ------------------------------------------------------------------------------------------------------------------------ Net increase (decrease) in net asset value $ 0.96 $ (1.47) $ 2.42 - ------------------------------------------------------------------------------------------------------------------------ Net asset value, end of period $ 17.36 $ 16.40 $ 17.87 - ------------------------------------------------------------------------------------------------------------------------ Total return* 6.74% 12.66% 15.95% Ratio of net expenses to average net assets+ 2.03% 2.03% 1.89% Ratio of net investment income (loss) to average net assets+ 0.32% (0.21)% (0.15)% Portfolio turnover rate 86% 53% 40% Net assets, end of period (in thousands) $37,116 $51,164 $32,440 Ratios with reduction for fees paid indirectly: Net expenses 2.03% 2.02% 1.89% Net investment income (loss) 0.32% (0.20)% (0.15)% - ------------------------------------------------------------------------------------------------------------------------ * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 30 Pioneer Value Fund | Annual Report | 9/30/08 Year Year Ended Ended 9/30/08 9/30/07 Class C Net asset value, beginning of period $ 16.84 $ 17.33 - ------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income (loss) $ 0.10 $ 0.07 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions (5.01) 2.43 - ------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ (4.91) $ 2.50 Distributions to shareowners: Net investment income (0.13) (0.13) Net realized gain (1.37) (2.86) - ------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (6.41) $ (0.49) - ------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 10.43 $ 16.84 - ------------------------------------------------------------------------------------------------------------- Total return* (31.49)% 16.31% Ratio of net expenses to average net assets+ 1.92% 1.98% Ratio of net investment income (loss) to average net assets+ 0.76% 0.58% Portfolio turnover rate 95% 34% Net assets, end of period (in thousands) $ 7,458 $ 12,606 Ratios with reduction for fees paid indirectly: Net expenses 1.91% 1.96% Net investment income (loss) 0.77% 0.60% - ------------------------------------------------------------------------------------------------------------- Year Year Year Ended Ended Ended 9/30/06 9/30/05 9/30/04 Class C Net asset value, beginning of period $ 16.39 $ 17.87 $ 15.49 - ----------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income (loss) $ 0.07 $ (0.04) $ (0.09) Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions 1.02 2.12 2.51 - ----------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.09 $ 2.08 $ 2.42 Distributions to shareowners: Net investment income (0.03) -- -- Net realized gain (0.12) (3.56) (0.04) - ----------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 0.94 $ (1.48) $ 2.38 - ----------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 17.33 $ 16.39 $ 17.87 - ----------------------------------------------------------------------------------------------------------------------- Total return* 6.68% 12.60% 15.66% Ratio of net expenses to average net assets+ 2.03% 2.08% 2.21% Ratio of net investment income (loss) to average net assets+ 0.34% (0.25)% (0.47)% Portfolio turnover rate 86% 53% 40% Net assets, end of period (in thousands) $ 8,723 $ 8,926 $ 9,168 Ratios with reduction for fees paid indirectly: Net expenses 2.03% 2.07% 2.20% Net investment income (loss) 0.34% (0.24)% (0.46)% - ----------------------------------------------------------------------------------------------------------------------- * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period, and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer Value Fund | Annual Report | 9/30/08 31 Financial Highlights (continued) Year Year Ended Ended 9/30/08 9/30/07 Class Y Net asset value, beginning of period $ 18.42 $ 18.67 - -------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.33 $ 0.39 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions (5.54) 2.59 - -------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ (5.21) $ 2.98 Distributions to shareowners: Net investment income (0.30) (0.37) Net realized gain (1.37) (2.86) - -------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (6.88) $ (0.25) - -------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 11.54 $ 18.42 - -------------------------------------------------------------------------------------------------------------- Total return* (30.50)% 17.92% Ratio of net expenses to average net assets+ 0.53% 0.54% Ratio of net investment income to average net assets+ 2.12% 2.04% Portfolio turnover rate 95% 34% Net assets, end of period (in thousands) $112,571 $238,308 Ratios with reduction for fees paid indirectly: Net expenses 0.53% 0.54% Net investment income 2.12% 2.04% - -------------------------------------------------------------------------------------------------------------- Year Year Ended Ended 8/11/04 (a) 9/30/06 9/30/05 to 9/30/04 Class Y Net asset value, beginning of period $ 17.59 $ 18.84 $ 18.16 - --------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.33 $ 0.12 $ 0.02 Net realized and unrealized gain (loss) on investments, written options and foreign currency transactions 1.11 2.37 0.66 - --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.44 $ 2.49 $ 0.68 Distributions to shareowners: Net investment income (0.24) (0.18) -- Net realized gain (0.12) (3.56) -- - --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 1.08 $ (1.25) $ 0.68 - --------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 18.67 $ 17.59 $ 18.84 - --------------------------------------------------------------------------------------------------------------------------- Total return* 8.31% 14.40% 3.74%(b Ratio of net expenses to average net assets+ 0.55% 0.59% 0.61%** Ratio of net investment income to average net assets+ 1.84% 1.50% 1.37%** Portfolio turnover rate 86% 53% 40%(b) Net assets, end of period (in thousands) $333,884 $311,272 $ 1,872 Ratios with reduction for fees paid indirectly: Net expenses 0.55% 0.59% 0.61%** Net investment income 1.84% 1.51% 1.37%** - --------------------------------------------------------------------------------------------------------------------------- (a) Class Y Shares were first publicly offered on August 11, 2004. * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period. (b) Not annualized. ** Annualized. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 32 Pioneer Value Fund | Annual Report | 9/30/08 Notes to Financial Statements | 9/30/08 1. Organization and Significant Accounting Policies Pioneer Value Fund (the Fund), is a Delaware statutory trust registered under the Investment Company Act of 1940 as a diversified, open-end management investment company. The investment objective of the Fund is reasonable income and capital growth. The Fund currently offers four classes of shares designated as Class A, Class B, Class C, and Class Y shares. As planned, Investor Class shares converted to Class A shares on December 10, 2006. Class R shares were first publicly offered on April 1, 2003 and ceased operations on January 31, 2007. Class Y shares were first publicly offered on August 11, 2004. Each class of shares represents an interest in the same portfolio of investments of the Fund and has equal rights to voting, redemptions, dividends and liquidation, except that each class of shares can bear different transfer agent and distribution fees and have exclusive voting rights with respect to the distribution plans that have been adopted by Class A, Class B, and Class C shareowners, respectively. There is no distribution plan for Class Y shares. The Fund's financial statements have been prepared in conformity with U.S. generally accepted accounting principles that require the management of the Fund to, among other things, make estimates and assumptions that affect the reported amounts of assets and liabilities, the disclosure of contingent assets and liabilities at the date of the financial statements, and the reported amounts of income, expenses and gains and losses on investments during the reporting period. Actual results could differ from those estimates. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making it more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. The Fund's prospectuses (unaudited) contain information regarding the Fund's principal risks. Please refer to those documents when considering the Fund's principal risks. The following is a summary of significant accounting policies followed by the Fund in the preparation of its financial statements, which are consistent with those policies generally accepted in the investment company industry: Pioneer Value Fund | Annual Report | 9/30/08 33 A. Security Valuation Security transactions are recorded as of trade date. The net asset value of the Fund is computed once daily, on each day the New York Stock Exchange (NYSE) is open, as of the close of regular trading on the NYSE. In computing the net asset value, securities are valued at the last sale price on the principal exchange where they are traded. Securities that have not traded on the date of valuation, or securities for which sale prices are not generally reported, are valued at the mean between the last bid and asked prices. Securities for which market quotations are not readily available are valued at their fair values as determined by, or under the direction of, the Board of Trustees. Trading in foreign securities is substantially completed each day at various times prior to the close of the NYSE. The values of such securities used in computing the net asset value of the Fund's shares are determined as of such times. The Fund may also use the fair value of a security including a non-U.S. security when the closing market price on the principal exchange where the security is traded no longer reflects the value of the security. At September 30, 2008, there were no securities fair valued. Temporary cash investments are valued at cost which approximates market value. Dividend income is recorded on the ex-dividend date, except that certain dividends from foreign securities where the ex-dividend date may have passed are recorded as soon as the Fund becomes aware of the ex-dividend data in the exercise of reasonable diligence. Interest income is recorded on the accrual basis. Dividend and interest income are reported net of unrecoverable foreign taxes withheld at the applicable country rates. Gains and losses on sales of investments are calculated on the identified cost method for both financial reporting and federal income tax purposes. B. Foreign Currency Translation The books and records of the Fund are maintained in U.S. dollars. Amounts denominated in foreign currencies are translated into U.S. dollars using current exchange rates. Net realized gains and losses on foreign currency transactions, if any, represent, among other things, the net realized gains and losses on foreign currency contracts, disposition of foreign currencies and the difference between the amount of income accrued and the U.S. dollars actually received. Further, the effects of changes in foreign currency exchange rates on investments are not segregated in the Statement of Operations from the effects of changes in market price of those securities but are included with the net realized and unrealized gain or loss on investments. 34 Pioneer Value Fund | Annual Report | 9/30/08 C. Federal Income Taxes It is the Fund's policy to comply with the requirements of the Internal Revenue Code applicable to regulated investment companies and to distribute all of its taxable income and net realized capital gains, if any, to its shareowners. Therefore, no federal income tax provision is required. Tax years prior to 2004 are closed (not subject to examination by tax authorities) due to the expiration of statute of limitations; all other tax years are open. The amounts and characterizations of distributions to shareowners for financial reporting purposes are determined in accordance with federal income tax rules. Therefore, the sources of the Fund's distributions may be shown in the accompanying financial statements as from or in excess of net investment income or as from net realized gain on investment transactions, or as from paid-in capital, depending on the type of book/tax differences that may exist. The Fund has elected to defer approximately $329,723,434 of capital losses recognized between November 1, 2007 and September 30, 2008 to its fiscal year ending September 30, 2009. At September 30, 2008, the Fund has reclassified $11,368 to increase undistributed net investment income and $11,368 to increase accumulated net realized loss on investments and foreign currency transactions, to reflect permanent book/tax differences. The reclassification has no impact on the net assets of the Fund and presents the Fund's capital accounts on a tax basis. The tax character of distributions paid during the years ended September 30, 2008 and September 30, 2007 was as follows: 2008 2007 Distributions paid from: Ordinary income $125,423,328 $109,853,484 Long-term capital gain 210,756,777 613,642,261 --------------------------------------------------------------------------- Total $336,180,105 $723,495,745 --------------------------------------------------------------------------- The following shows the components of distributable earnings on a federal income tax basis at September 30, 2008: 2008 Distributable earnings: Undistributed ordinary income $ 19,126,106 Current year post October loss deferred (329,723,434) Unrealized depreciation (127,048,629) --------------------------------------------------------------------------- Total $(437,645,957) --------------------------------------------------------------------------- Pioneer Value Fund | Annual Report | 9/30/08 35 The difference between book-basis and tax-basis unrealized depreciation is attributable to the tax deferral of losses on wash sales. D. Forward Foreign Currency Contracts The Fund enters into forward foreign currency contracts (contracts) for the purchase or sale of a specific foreign currency at a fixed price on a future date as a hedge or cross-hedge against either specific investment transactions (settlement hedges) or portfolio positions (portfolio hedges). All contracts are marked to market daily at the applicable exchange rates, and any resulting unrealized gains or losses are recorded in the Fund's financial statements. The Fund records realized gains and losses at the time a portfolio hedge is offset by entry into a closing transaction or extinguished by delivery of the currency. Risks may arise upon entering into these contracts from the potential inability of counterparties to meet the terms of the contract and from unanticipated movements in the value of foreign currencies relative to the U.S. dollar. As of September 30, 2008, the Fund had no outstanding settlement or portfolio hedges. E. Fund Shares The Fund records sales and repurchases of its shares as of trade date. Pioneer Funds Distributor, Inc. (PFD), the principal underwriter for the Fund and a wholly owned indirect subsidiary of UniCredit S.p.A. (UniCredit), earned $178,154 in underwriting commissions on the sale of Class A shares during the year ended September 30, 2008. F. Class Allocations Income, common expenses and realized and unrealized gains and losses are calculated at the Fund level and allocated daily to each class of shares based on the respective percentage of adjusted net assets at the beginning of the day. Distribution fees are calculated based on the average daily net asset value attributable to Class A, Class B, and Class C shares of the Fund, respectively (see Note 4). Class Y shares are not subject to a distribution plan. Shareowners of each class participate in all expenses and fees paid to the transfer agent, Pioneer Investment Management Shareholder Services, Inc. (PIMSS), for its services, which are allocated based on the number of accounts in each class and the ratable allocation of related out-of-pocket expenses (see Note 3). Distributions to shareowners are recorded as of the ex-dividend date. Distributions paid by the Fund with respect to each class of shares are calculated in the same manner, at the same time, and in the same amount, except that Class A, Class B, Class C and Class Y shares can bear different transfer agent and distribution expense rates. 36 Pioneer Value Fund | Annual Report | 9/30/08 G. Repurchase Agreements With respect to repurchase agreements entered into by the Fund, the value of the underlying securities (collateral), including accrued interest received from counterparties, is required to be at least equal to or in excess of the value of the repurchase agreement at the time of purchase. The collateral for all repurchase agreements is held in safekeeping in the customer-only account of the Fund's custodian or subcustodians. The Fund's investment adviser, Pioneer Investment Management, Inc. (PIM), is responsible for determining that the value of the collateral remains at least equal to the repurchase price. H. Securities Lending The Fund lends securities in its portfolio to certain broker-dealers or other institutional investors. When entering into a loan, the Fund receives collateral and earns income in the form of negotiated lenders' fees. The Fund also continues to receive interest or payments in lieu of dividends on the securities loaned. Gain or loss on the fair value of the loaned securities that may occur during the term of the loan will be for the account of the Fund. The loans are secured by collateral which is required to be at least 102%, at all times, of the fair value of the securities loaned. The amount of collateral is required to be adjusted daily to reflect any price fluctuation in the value of the loaned securities. The Fund has the right under the lending agreement to recover the securities from the borrower on demand. The Fund invests cash collateral in cash equivalent investments. Securities lending collateral is managed by Credit Suisse. I. Option Writing When the Fund writes an option, an amount equal to the premium received by the Fund is recorded as a liability and is subsequently adjusted to the current fair value of the option written. Premiums received from writing options that expire unexercised are treated by the Fund on the expiration date as realized gains from investments. The difference between the premium and the amount paid on effecting a closing purchase transaction, including brokerage commissions, is also treated as a realized gain, or, if the premium is less than the amount paid for the closing purchase transaction, as a realized loss. If a call option is exercised, the premium is added to the proceeds from the sale of the underlying security in determining whether the Fund has realized a gain or loss. The Fund as writer of an option bears the market risk of an unfavorable change in the price of the security underlying the written option. Pioneer Value Fund | Annual Report | 9/30/08 37 Transactions in written call options for the year ended September 30, 2008 are summarized as follows: Number of Premiums Contracts Received Options outstanding at beginning of period -- $ -- Options opened 14,550 4,045,818 Options exercised (1,500) (980,779) Options closed (8,150) (2,117,056) Options expired (4,900) (947,983) --------------------------------------------------------------------------- Options outstanding at end of period -- $ -- --------------------------------------------------------------------------- 2. Management Agreement PIM, a wholly owned indirect subsidiary of UniCredit, manages the Fund's portfolio. PIM receives a basic fee that is calculated at the annual rate of 0.60% of the Fund's average daily net assets up to $5 billion, 0.575% on the next $5 billion and 0.55% on the excess over $10 billion. The basic fee is subject to a performance adjustment (limited to a maximum of -0.10% applied to average assets during the measurement period) based on the Fund's investment performance as compared with the Russell 1000[RegTM] Value Index over a rolling 36-month period. In addition, the fee is further limited to a maximum annualized rate adjustment of up to 0.10% (a "ceiling") applied to average assets during the current month. For the year ended September 30, 2008, the aggregate performance adjustment resulted in a decrease to the basic fee of $3,776,033. For the year ended September 30, 2008, the effective management fee was equivalent to 0.47% of the Fund's average daily net assets. In addition, under the management and administration agreements, certain other services and costs, including accounting, regulatory reporting and insurance premiums, are paid by the Fund. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $19,675 in management fees, administrative costs and certain other services payable to PIM at September 30, 2008. 3. Transfer Agent PIMSS, a wholly owned indirect subsidiary of UniCredit, provides substantially all transfer agent and shareowner services to the Fund at negotiated rates. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $353,502 in transfer agent fees payable to PIMSS at September 30, 2008. 4. Distribution Plan The Fund adopted a Plan of Distribution with respect to Class A, Class B and Class C shares (Class A Plan, Class B Plan, Class C Plan) in accordance with Rule 12b-1 of the Investment Company Act of 1940. Effective February 1, 2008, under the Class A Plan, the Fund pays PFD a service fee equal to 0.25% of the 38 Pioneer Value Fund | Annual Report | 9/30/08 average daily net assets attributable to Class A shares to finance activities primarily intended to result in the sale of Class A shares. Prior to February 1, 2008, PFD was reimbursed for service fees in an amount up to 0.25% of the average daily net assets attributable to Class A shares. Pursuant to the Class B Plan and Class C Plan the Fund pays PFD 1.00% of the average daily net assets attributable to each class of shares. The fee consists of a 0.25% service fee and a 0.75% distribution fee paid as compensation for personal services and/or account maintenance services or distribution services with regard to Class B and Class C shares. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $14,105 in distribution fees payable to PFD at September 30, 2008. In addition, redemptions of each class of shares (except Class Y shares) may be subject to a contingent deferred sales charge (CDSC). A CDSC of 1.00% may be imposed on redemptions of certain net asset value purchases of Class A shares within 18 months of purchase. Class B shares that are redeemed within five years of purchase are subject to a CDSC at declining rates beginning at 4.00%, based on the lower of cost or market value of shares being redeemed. Redemptions of Class C shares within one year of purchase are subject to a CDSC of 1.00%. Proceeds from the CDSCs are paid to PFD. For the year ended September 30, 2008, CDSCs in the amount of $52,662 were paid to PFD. 5. Expense Offset Arrangements Effective July 15, 2005, the Fund has entered into commission recapture arrangements with brokers with whom PIM places trades on behalf of the Fund where they provide services to the Fund in addition to trade execution. These services included payments of certain expenses on behalf of the Fund. For the year ended September 30, 2008, expenses were not reduced under this agreement. In addition, the Fund has entered into certain expense offset arrangements with PIMSS resulting in a reduction in the Fund's total expenses due to interest earned on cash held by PIMSS. For the year ended September 30, 2008, the Fund's expenses were reduced by $94,412 under such arrangements. 6. Line of Credit The Fund, along with certain others in the Pioneer Family of Funds (the Funds), collectively participate in a $200 million committed, unsecured revolving line of credit facility. Borrowings are used solely for temporary or emergency purposes. The Fund may borrow up to the lesser of $200 million or the limits set by its prospectus for borrowings. Interest on collective borrowings is payable at the Federal Funds Rate plus 1/2%, on an annualized basis. The Funds pay an annual commitment fee for this facility. The commitment fee is allocated among such Funds based on their respective borrowing limits. For the year ended September 30, 2008, the Fund had no borrowings under this agreement. Pioneer Value Fund | Annual Report | 9/30/08 39 7. New Pronouncements In September 2006, Statement of Financial Accounting Standards No. 157, Fair Value Measurements (SFAS 157), was issued and is effective for fiscal years beginning after November 15, 2007. SFAS 157 defines fair value, establishes a framework for measuring fair value and expands disclosures about fair value measurements. Management is currently evaluating the impact the adoption of SFAS 157 will have on the Fund's financial statement disclosures. In March 2008, Statement of Financial Accounting Standards No. 161, Disclosures about Derivative Instruments and Hedging Activities (SFAS 161), was issued and is effective for fiscal years beginning after November 15, 2008. SFAS 161 requires enhanced disclosures about an entity's derivative and hedging activities. Management is currently evaluating the impact the adoption of SFAS 161 will have on the Fund's financial statement disclosures. 40 Pioneer Value Fund | Annual Report | 9/30/08 Report of Independent Registered Public Accounting Firm To the Board of Trustees and Shareowners of Pioneer Value Fund: - -------------------------------------------------------------------------------- We have audited the accompanying statement of assets and liabilities of Pioneer Value Fund ("the Fund"), including the schedule of investments, as of September 30, 2008, and the related statement of operations for the year then ended, the statements of changes in net assets for each of the two years in the period then ended, and the financial highlights for each of the periods indicated therein. These financial statements and financial highlights are the responsibility of the Fund's management. Our responsibility is to express an opinion on these financial statements and financial highlights based on our audits. We conducted our audits in accordance with the standards of the Public Company Accounting Oversight Board (United States). Those standards require that we plan and perform the audit to obtain reasonable assurance about whether the financial statements and financial highlights are free of material misstatement. We were not engaged to perform an audit of the Fund's internal control over financial reporting. Our audits included consideration of internal control over financial reporting as a basis for designing audit procedures that are appropriate in the circumstances, but not for the purpose of expressing an opinion on the effectiveness of the Fund's internal control over financial reporting. Accordingly, we express no such opinion. An audit also includes examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements and financial highlights, assessing the accounting principles used and significant estimates made by management, and evaluating the overall financial statement presentation. Our procedures included confirmation of securities owned as of September 30, 2008, by correspondence with the custodian and brokers or by other appropriate auditing procedures where replies from brokers were not received. We believe that our audits provide a reasonable basis for our opinion. In our opinion, the financial statements and financial highlights referred to above present fairly, in all material respects, the financial position of Pioneer Value Fund at September 30, 2008, the results of its operations for the year then ended, the changes in its net assets for each of the two years in the period then ended, and the financial highlights for each of the periods indicated therein, in conformity with U.S. generally accepted accounting principles. /s/ Ernst & Young LLP Boston, Massachusetts November 17, 2008 Pioneer Value Fund | Annual Report | 9/30/08 41 ADDITIONAL INFORMATION (unaudited) For the year ended September 30, 2008, certain dividends paid by the Fund may be subject to a maximum tax rate of 15%, as provided for by the Jobs and Growth Tax Relief Reconciliation Act (the Act) of 2003. The Fund intends to designate up to the maximum amount of such dividends allowable under the Act, as taxed at a maximum rate of 15%. Complete information will be computed and reported in conjunction with your 2008 form 1099-DIV. The qualifying percentage of the Fund's ordinary income dividends for the purpose of the corporate dividends received deduction was 54.00%. The percentage of the Fund's ordinary income distributions that are exempt from nonresident alien (NRA) tax withholding resulting from qualified short term gains was 58.11%. Results of Shareholder Meeting (unaudited) At a special meeting held on May 13, 2008, and adjourned to July 17, 2008 with respect to proposal 3I, shareholders of the Fund were asked to consider the proposals described below. A report of the total votes cast by the Fund's shareholders follows: Broker For Against Abstain Non-Votes Proposal 1 -- To elect Trustees John F. Cogan, Jr. 163,598,931.527 4,974,647.060 401,063.007 0.000 Daniel K. Kingsbury 164,396,629.268 4,197,113.524 380,898.801 0.000 David R. Bock 164,270,974.008 4,303,828.298 399,839.287 0.000 Mary K. Bush 163,715,490.961 4,878,251.831 380,898.801 0.000 Benjamin M. Friedman 164,243,829.991 4,330,972.315 399,839.287 0.000 Margaret B.W. Graham 164,314,343.303 4,278,175.769 382,122.521 0.000 Thomas J. Perna 164,112,951.398 4,448,352.986 413,337.209 0.000 Marguerite A. Piret 164,144,163.221 4,437,305.369 393,173.003 0.000 John Winthrop 163,599,511.327 4,938,491.156 436,639.110 0.000 Broker For Against Abstain Non-Votes Proposal 2 -- To approve an amendment to the Declaration of Trust 110,835,729.023 7,192,072.638 3,960,673.932 46,986,166.000 42 Pioneer Value Fund | Annual Report | 9/30/08 Broker For Against Abstain Non-Votes Proposal 3A -- To approve changes to the Fund's fundamental investment policy relating to borrowing money 110,749,185.825 7,062,200.805 4,177,088.963 46,986,166.000 Proposal 3B -- To approve changes to the Fund's fundamental investment policy relating to underwriting 110,910,914.749 6,401,048.402 4,676,512.442 46,986,166.000 Proposal 3C -- To approve changes to the Fund's fundamental investment policy relating to lending 110,605,653.182 7,225,341.927 4,157,480.484 46,986,166.000 Proposal 3D -- To approve changes to the Fund's fundamental investment policy relating to issuing senior securities 111,603,362.549 6,247,614.426 4,137,498.618 46,986,166.000 Proposal 3E -- To approve changes to the Fund's fundamental investment policy relating to real estate 111,557,194.592 6,258,289.457 4,172,991.545 46,986,166.000 Proposal 3F -- To approve changes to the Fund's fundamental investment policy relating to commodities 111,193,467.625 6,803,646.577 3,991,361.392 46,986,166.000 Proposal 3G -- To approve changes to the Fund's fundamental investment policy relating to concentration 111,712,180.674 5,918,916.056 4,357,378.862 46,986,166.000 Proposal 3H -- To approve changes to the Fund's fundamental investment policy relating to diversification. 112,121,571.961 5,783,788.825 4,083,114.807 46,986,166.000 Proposal 3I -- To approve the conversion of the Fund's investment objective from fundamental to non- fundamental 107,027,991.724 18,272,026.810 6,087,807.809 41,472,848.000 Broker For Against Abstain Non-Votes Proposal 4 -- To approve an Amended and Restated Management Agreement with PIM 113,176,482.835 4,797,663.556 4,014,329.202 46,986,166.000 Pioneer Value Fund | Annual Report | 9/30/08 43 Approval of Investment Advisory Agreement (unaudited) Pioneer Investment Management, Inc. (PIM) serves as the Fund's investment adviser pursuant to an investment advisory agreement between PIM and the Fund. The Trustees of the Fund, as required by law, determine annually whether to continue the investment advisory agreement for the Fund. In connection with their most recent consideration of the investment advisory agreement for the Fund, the Trustees received and reviewed a substantial amount of information provided by PIM in response to requests of the independent Trustees and their independent legal counsel. The independent Trustees met on a number of occasions with PIM and also separately with their independent legal counsel to evaluate and discuss the information provided to them by PIM. At a meeting held on November 13, 2007, based on their evaluation of the information provided by PIM, the Trustees, including the independent Trustees voting separately, unanimously approved the continuation of the investment advisory agreement for another year. At a meeting held on January 8, 2008, the Trustees considered whether an amended and restated investment advisory agreement for the Fund should be approved for an initial period ending December 31, 2009. The management fee to be paid by the Fund to PIM under the amended and restated investment advisory agreement is the same as the management fee provided in the previously approved investment advisory agreement. Based on their evaluation of the information provided by PIM, including the information provided by PIM in connection with the Trustees' most recent approval of the continuation of the previous investment advisory agreement, the Trustees, including the independent Trustees voting separately, unanimously approved the amended and restated investment advisory agreement. Shareholders of the Fund approved the amended and restated investment advisory agreement at a meeting held on May 13, 2008. In considering the amended and restated investment advisory agreement, the Trustees considered various factors that they determined were relevant, including the factors described below. The Trustees did not identify any single factor as the controlling factor in determining to approve the amended and restated investment advisory agreement. Nature, Extent and Quality of Services The Trustees considered the nature, extent and quality of the services that were provided by PIM to the Fund under the previous investment advisory agreement, and that would continue to be provided by PIM to the Fund under the amended and restated investment advisory agreement, taking into account the investment objective and strategy of the Fund and the information related to 44 Pioneer Value Fund | Annual Report | 9/30/08 the Fund provided to the Trustees at each quarterly meeting. The Trustees reviewed the terms of the amended and restated investment advisory agreement. The Trustees also reviewed PIM's investment approach for the Fund and its research process. The Trustees considered the resources of PIM and the personnel of PIM who provide investment management services to the Fund. They also considered PIM's compliance and legal resources and personnel. In addition, the Trustees considered the other services that PIM provided under the previous investment advisory agreement and that PIM would continue to provide to the Fund under the amended and restated investment advisory agreement and that, as administrator, PIM is responsible for the administration of the Fund's business and other affairs. It was noted that PIM supervises and monitors the performance of the Fund's service providers and provides the Fund with personnel (including officers) as are necessary for the Fund's operations. The Trustees considered the fees paid to PIM for the provision of such services. Based on these considerations, the Trustees concluded that the nature, extent and quality of services that PIM would continue to provide to the Fund under the amended and restated investment advisory agreement, were satisfactory and consistent with the terms of the amended and restated investment advisory agreement. Performance of the Fund The Trustees considered the performance results of the Fund over various time periods. They reviewed information comparing the Fund's performance with the average performance of its peer group of funds as classified by Morningstar, Inc. (Morningstar), an independent provider of investment company data, and with the performance of the Fund's benchmark index. The Trustees considered that the Fund's annualized total return was in the fourth quintile of its Morningstar category for the one, three and five year periods ended June 30, 2007. (In all quintile rankings referred to throughout this disclosure, first quintile is most favorable to the Fund's shareowners. Thus, highest relative performance would be first quintile and lowest relative expenses would also be first quintile.) The Trustees considered the recent changes in the Fund's portfolio management team and that performance appeared to be improving and concluded that the investment performance of the Fund was satisfactory. Management Fee and Expenses The Trustees considered that the management fee to be paid by the Fund to PIM under the amended and restated investment advisory agreement would be the same as the management fee to be paid by the Fund under the previously approved investment advisory agreement. The Trustees considered information on the fees and expenses of the Fund in comparison to the management fees of its peer group of funds as classified by Morningstar and the expense Pioneer Value Fund | Annual Report | 9/30/08 45 ratios of a peer group of funds selected on the basis of criteria determined by the independent Trustees for this purpose using data provided by Strategic Insight Mutual Fund Research and Consulting, LLC (Strategic Insight), an independent third party. The Trustees considered that the Fund's management fee for the twelve months ended June 30, 2007 was in the first quintile relative to the management fees paid by other funds in its peer group Morningstar category for the comparable period. The Trustees also considered that the Fund's expense ratio for the twelve months ended June 30, 2007 was in the first quintile relative to its Strategic Insight peer group. The Trustees also reviewed management fees charged by PIM to its other clients with a similar investment strategy as the Fund. The Trustees noted that in some instances the fee rates for those clients were lower than the management fees for the Fund and considered that, under the amended and restated investment advisory agreement with the Fund, PIM performs additional services for the Fund that it does not provide to those other clients, including oversight of the Fund's other service providers, regulatory compliance and other services. The Trustees concluded that the management fee payable by the Fund to PIM was reasonable in relation to the nature and quality of services provided, taking into account the fees charged by other advisers for managing comparable mutual funds with similar strategies. The Trustees also concluded that the Fund's expense ratio was reasonable, taking into account the size of the Fund, the quality of services provided by PIM and the investment performance of the Fund. Profitability The Trustees considered information provided by PIM regarding the profitability of PIM with respect to the advisory services provided by PIM to the Fund, including the methodology used by PIM in allocating certain of its costs to the management of the Fund. The Trustees also considered PIM's profit margin in connection with the overall operation of the Fund. They further reviewed the financial results realized by PIM and its affiliates from non-fund businesses. The Trustees considered PIM's profit margins with respect to the Fund in comparison to the limited industry data available and noted that the profitability of any adviser was affected by numerous factors, including its organizational structure and method for allocating expenses. The Trustees recognized that PIM should be entitled to earn a reasonable level of profit for the services provided to the Fund. The Trustees concluded that PIM's profitability with respect to the management of the Fund was not unreasonable. 46 Pioneer Value Fund | Annual Report | 9/30/08 Economies of Scale The Trustees considered the economies of scale with respect to the management of the Fund, whether the Fund had appropriately benefited from any economies of scale, and whether there was potential for realization of any further economies of scale. The Trustees concluded that, because of the breakpoints in the management fee schedule and the reduced fee rates above certain asset levels, any perceived or potential economies of scale would be shared between PIM and the Fund. Other Benefits The Trustees considered the other benefits to PIM from its relationship with the Fund. The Trustees considered that affiliates of PIM serve as the Fund's transfer agent and distributor. The Trustees considered the receipt by PIM and its affiliates of sales loads and payments under Rule 12b-1 plans in respect of the Fund and the other Pioneer funds and the benefits to PIM and its affiliates from the use of "soft" commission dollars generated by the Fund to pay for research and brokerage services. The Trustees further considered the intangible benefits to PIM by virtue of its relationship with the Fund and the other Pioneer funds. The Trustees concluded that the receipt of these benefits was reasonable in the context of the overall relationship between PIM and the Fund. Conclusion After consideration of the factors described above as well as other factors, the Trustees, including all of the independent Trustees, concluded that the terms of the amended and restated investment advisory agreement between PIM and the Fund, including the fees payable thereunder, were fair and reasonable and voted to approve the amended and restated investment advisory agreement for the Fund. Pioneer Value Fund | Annual Report | 9/30/08 47 Trustees, Officers and Service Providers Investment Adviser Pioneer Investment Management, Inc. Custodian Brown Brothers Harriman & Co. Independent Registered Public Accounting Firm Ernst & Young LLP Principal Underwriter Pioneer Funds Distributor, Inc. Legal Counsel Bingham McCutchen LLP Shareowner Services and Transfer Agent Pioneer Investment Management Shareholder Services, Inc. Trustees and Officers The Board of Trustees provides broad supervision over the Fund's affairs. The officers of the Fund are responsible for the Fund's operations. The Trustees and officers are listed below, together with their principal occupations during the past five years. Trustees who are interested persons of the Fund within the meaning of the 1940 Act are referred to as Interested Trustees. Trustees who are not interested persons of the Fund are referred to as Independent Trustees. Each of the Trustees (except Mr. West, Mr. Bock and Dr. Friedman) serves as a Trustee of each of the 77 U.S. registered investment portfolios for which Pioneer serves as investment adviser (the "Pioneer Funds"). Mr. West serves as Trustee of 33 of the 77 Pioneer Funds, Mr. Bock serves as Trustee of 76 of the 77 Pioneer Funds, and Dr. Friedman serves as Trustee of 76 of the 77 Pioneer Funds. The address for all Trustees and all officers of the Fund is 60 State Street, Boston, Massachusetts 02109. 48 Pioneer Value Fund | Annual Report | 9/30/08 Interested Trustees Position Held Length of Service Name and Age with the Fund and Term of Office John F. Cogan, Jr. (82)* Chairman of the Board, Trustee since 1982. Trustee and President Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Daniel K. Kingsbury (50)* Trustee and Executive Trustee since 2008. Vice President Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- * Mr. Cogan and Mr. Kingsbury are Interested Trustees because they are officers or directors of the Fund's investment adviser and certain of its affiliates. Interested Trustees Other Directorships Name and Age Principal Occupation During Past Five Years Held by this Trustee John F. Cogan, Jr. (82)* Deputy Chairman and a Director of Pioneer Global Asset Man- None agement S.p.A. ("PGAM"); Non-Executive Chairman and a Direc- tor of Pioneer Investment Management USA Inc. ("PIM-USA"); Chairman and a Director of Pioneer; Chairman and Director of Pioneer Institutional Asset Management, Inc. (since 2006); Director of Pioneer Alternative Investment Management Limited (Dublin); President and a Director of Pioneer Alternative Invest- ment Management (Bermuda) Limited and affiliated funds; Director of PIOGLOBAL Real Estate Investment Fund (Russia) (until June 2006); Director of Nano-C, Inc. (since 2003); Director of Cole Management Inc. (since 2004); Director of Fiduciary Counseling, Inc.; President and Director of Pioneer Funds Dis- tributor, Inc. ("PFD") (until May 2006); President of all of the Pioneer Funds; and Of Counsel, Wilmer Cutler Pickering Hale and Dorr LLP - --------------------------------------------------------------------------------------------------------------------- Daniel K. Kingsbury (50)* Director, CEO and President of Pioneer Investment Management None USA Inc. (since February 2007); Director and President of Pioneer Investment Management, Inc. and Pioneer Institutional Asset Management, Inc. (since February 2007); Executive Vice President of all of the Pioneer Funds (since March 2007); Director of Pioneer Global Asset Management S.p.A. (since April 2007); Head of New Markets Division, Pioneer Global Asset Management S.p.A. (2000 - 2007) - --------------------------------------------------------------------------------------------------------------------- * Mr. Cogan and Mr. Kingsbury are Interested Trustees because they are officers or directors of the Fund's investment adviser and certain of its affiliates. Pioneer Value Fund | Annual Report | 9/30/08 49 Independent Trustees Position Held Length of Service Name and Age with the Fund and Term of Office David R. Bock (64) Trustee Trustee since 2005. Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Mary K. Bush (60) Trustee Trustee since 1997. Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Independent Trustees Other Directorships Name and Age Principal Occupation During Past Five Years Held by this Trustee David R. Bock (64) Executive Vice President and Chief Financial Officer, I-trax, Inc. Director of Enterprise Com- (publicly traded health care services company) (2004 - 2007); munity Investment, Inc. Partner, Federal City Capital Advisors (boutique merchant bank) (privately-held affordable (1997 to 2004 and 2008 - present); and Executive Vice Presi- housing finance company); dent and Chief Financial Officer, Pedestal Inc. (internet-based and Director of New York mortgage trading company) (2000 - 2002) Mortgage Trust (publicly traded mortgage REIT) - ------------------------------------------------------------------------------------------------------------------------ Mary K. Bush (60) President, Bush International, LLC (international financial advi- Director of Marriott sory firm) International, Inc., Director of Discover Financial Services (credit card issuer and electronic payment services); Director of Briggs & Stratton Co. (engine manufacturer); Director of UAL Corporation (airline holding company) Director of Mantech International Corporation (national secu- rity, defense, and intelli- gence technology firm); and Member, Board of Governors, Investment Company Institute - ------------------------------------------------------------------------------------------------------------------------ 50 Pioneer Value Fund | Annual Report | 9/30/08 Position Held Length of Service Name and Age with the Fund and Term of Office Benjamin M. Friedman (64) Trustee Trustee since May, 2008. Serves until a successor trustee is elected or earlier retire- ment or removal. - -------------------------------------------------------------------------------- Margaret B.W. Graham (61) Trustee Trustee since 1990. Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Thomas J. Perna (57) Trustee Trustee since 2006. Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Marguerite A. Piret (60) Trustee Trustee since 1982. Serves until a successor trustee is elected or earlier retirement or removal. - -------------------------------------------------------------------------------- Other Directorships Name and Age Principal Occupation During Past Five Years Held by this Trustee Benjamin M. Friedman (64) Professor, Harvard University Trustee, Mellon Institutional Funds Investment Trust and Mellon Institutional Funds Master Portfolio (oversees 17 portfolios in fund complex) - ------------------------------------------------------------- -------------------------------------------------------------------- Margaret B.W. Graham (61) Founding Director, Vice-President and Corporate Secretary, The None Winthrop Group, Inc. (consulting firm); and Desautels Faculty of Management, McGill University - ------------------------------------------------------------- -------------------------------------------------------------------- Thomas J. Perna (57) Chief Executive Officer, Quadriserv, Inc. (technology products for None securities lending industry) (2008 - present); private investor (2004 - present); and Senior Executive Vice President, The Bank of New York (financial and securities services) (1986 - 2004) - ------------------------------------------------------------- -------------------------------------------------------------------- Marguerite A. Piret (60) President and Chief Executive Officer, Newbury, Piret & Company, Director of New America Inc. (investment banking firm) High Income Fund, Inc. (closed-end investment company) - ------------------------------------------------------------- -------------------------------------------------------------------- Pioneer Value Fund | Annual Report | 9/30/08 51 Fund Officers Position Held Length of Service Name and Age with the Fund and Term of Office Dorothy E. Bourassa (60) Secretary Since 2003. Serves at the discretion of the Board - -------------------------------------------------------------------------------- Christopher J. Kelley (43) Assistant Secretary Since 2003. Serves at the discretion of the Board - -------------------------------------------------------------------------------- Mark E. Bradley (48) Treasurer Since March 2008. Serves at the discretion of the Board - -------------------------------------------------------------------------------- Luis I. Presutti (43) Assistant Treasurer Since 2000. Serves at the discretion of the Board - -------------------------------------------------------------------------------- Gary Sullivan (50) Assistant Treasurer Since 2002. Serves at the discretion of the Board - -------------------------------------------------------------------------------- Fund Officers Other Directorships Name and Age Principal Occupation During Past Five Years Held by this Officer Dorothy E. Bourassa (60) Secretary of PIM-USA; Senior Vice President - Legal of Pioneer; None Secretary/Clerk of most of PIM-USA's subsidiaries; and Secretary of all of the Pioneer Funds since September 2003 (Assistant Secretary from November 2000 to September 2003) - ---------------------------------------------------------------------------------------------------------------------- Christopher J. Kelley (43) Associate General Counsel of Pioneer since January 2008 and None Assistant Secretary of all of the Pioneer Funds since September 2003; Vice President and Senior Counsel of Pioneer from July 2002 to December 2007 - ---------------------------------------------------------------------------------------------------------------------- Mark E. Bradley (48) Vice President - Fund Accounting, Administration and Controller- None ship Services of Pioneer; and Treasurer of all of the Pioneer Funds since March 2008; Deputy Treasurer of Pioneer from March 2004 to February 2008; Assistant Treasurer of all of the Pioneer Funds from March 2004 to February 2008; and Treasurer and Senior Vice President, CDC IXIS Asset Management Services from 2002 to 2003 - ---------------------------------------------------------------------------------------------------------------------- Luis I. Presutti (43) Assistant Vice President - Fund Accounting, Administration and None Controllership Services of Pioneer; and Assistant Treasurer of all of the Pioneer Funds - ---------------------------------------------------------------------------------------------------------------------- Gary Sullivan (50) Fund Accounting Manager - Fund Accounting, Administration and None Controllership Services of Pioneer; and Assistant Treasurer of all of the Pioneer Funds - ---------------------------------------------------------------------------------------------------------------------- 52 Pioneer Value Fund | Annual Report | 9/30/08 Position Held Length of Service Name and Age with the Fund and Term of Office Katherine Kim Sullivan (34) Assistant Treasurer Since 2003. Serves at the discretion of the Board - ----------------------------------------------------------------------------------- Teri W. Anderholm (49) Chief Compliance Officer Since January 2007. Serves at the discretion of the Board - ----------------------------------------------------------------------------------- Other Directorships Name and Age Principal Occupation During Past Five Years Held by this Officer Katherine Kim Sullivan (34) Fund Administration Manager - Fund Accounting, Administration None and Controllership Services since June 2003 and Assistant Trea- surer of all of the Pioneer Funds since September 2003; Assis- tant Vice President - Mutual Fund Operations of State Street Corporation from June 2002 to June 2003 (formerly Deutsche Bank Asset Management) - --------------------------------------------------------------------------------------------------------------------- Teri W. Anderholm (49) Chief Compliance Officer of Pioneer since December 2006 and of None all the Pioneer Funds since January 2007; Vice President and Compliance Officer, MFS Investment Management (August 2005 to December 2006); Consultant, Fidelity Investments (February 2005 to July 2005); Independent Consultant (July 1997 to February 2005) - --------------------------------------------------------------------------------------------------------------------- Pioneer Value Fund | Annual Report | 9/30/08 53 This page for your notes. 54 Pioneer Value Fund | Annual Report | 9/30/08 This page for your notes. Pioneer Value Fund | Annual Report | 9/30/08 55 This page for your notes. 56 Pioneer Value Fund | Annual Report | 9/30/08 This page for your notes. Pioneer Value Fund | Annual Report | 9/30/08 57 This page for your notes. 58 Pioneer Value Fund | Annual Report | 9/30/08 This page for your notes. Pioneer Value Fund | Annual Report | 9/30/08 59 This page for your notes. 60 Pioneer Value Fund | Annual Report | 9/30/08 How to Contact Pioneer We are pleased to offer a variety of convenient ways for you to contact us for assistance or information. Call us for: - -------------------------------------------------------------------------------- Account Information, including existing accounts, new accounts, prospectuses, applications and service forms 1-800-225-6292 FactFone(SM) for automated fund yields, prices, account information and transactions 1-800-225-4321 Retirement plans information 1-800-622-0176 Telecommunications Device for the Deaf (TDD) 1-800-225-1997 Write to us: - -------------------------------------------------------------------------------- PIMSS, Inc. P.O. Box 55014 Boston, Massachusetts 02205-5014 Our toll-free fax 1-800-225-4240 Our internet e-mail address ask.pioneer@pioneerinvestments.com (for general questions about Pioneer only) Visit our web site: pioneerinvestments.com This report must be preceded or accompanied by a prospectus. The Fund files a complete schedule of investments with the Securities and Exchange Commission for the first and third quarters for each fiscal year on Form N-Q. Shareholders may view the filed Form N-Q by visiting the Commission's web site at http://www.sec.gov. The filed form may also be viewed and copied at the Commission's Public Reference Room in Washington, DC. Information regarding the operations of the Public Reference Room may be obtained by calling 1-800-SEC-0330. [LOGO]PIONEER Investments(R) Pioneer Investment Management, Inc. 60 State Street Boston, MA 02109 pioneerinvestments.com Securities offered through Pioneer Funds Distributor, Inc. 60 State Street, Boston, MA 02109 Underwriter of Pioneer Mutual Funds, Member SIPC (C) 2008 Pioneer Investments 19438-02-1108 ITEM 2. CODE OF ETHICS. (a) Disclose whether, as of the end of the period covered by the report, the registrant has adopted a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party. If the registrant has not adopted such a code of ethics, explain why it has not done so. The registrant has adopted, as of the end of the period covered by this report, a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer and controller. (b) For purposes of this Item, the term "code of ethics" means written standards that are reasonably designed to deter wrongdoing and to promote: (1) Honest and ethical conduct, including the ethical handling of actual or apparent conflicts of interest between personal and professional relationships; (2) Full, fair, accurate, timely, and understandable disclosure in reports and documents that a registrant files with, or submits to, the Commission and in other public communications made by the registrant; (3) Compliance with applicable governmental laws, rules, and regulations; (4) The prompt internal reporting of violations of the code to an appropriate person or persons identified in the code; and (5) Accountability for adherence to the code. (c) The registrant must briefly describe the nature of any amendment, during the period covered by the report, to a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item. The registrant must file a copy of any such amendment as an exhibit pursuant to Item 10(a), unless the registrant has elected to satisfy paragraph (f) of this Item by posting its code of ethics on its website pursuant to paragraph (f)(2) of this Item, or by undertaking to provide its code of ethics to any person without charge, upon request, pursuant to paragraph (f)(3) of this Item. The registrant has made no amendments to the code of ethics during the period covered by this report. (d) If the registrant has, during the period covered by the report, granted a waiver, including an implicit waiver, from a provision of the code of ethics to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, that relates to one or more of the items set forth in paragraph (b) of this Item, the registrant must briefly describe the nature of the waiver, the name of the person to whom the waiver was granted, and the date of the waiver. Not applicable. (e) If the registrant intends to satisfy the disclosure requirement under paragraph (c) or (d) of this Item regarding an amendment to, or a waiver from, a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item by posting such information on its Internet website, disclose the registrant's Internet address and such intention. Not applicable. (f) The registrant must: (1) File with the Commission, pursuant to Item 10(a), a copy of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, as an exhibit to its annual report on this Form N-CSR; (2) Post the text of such code of ethics on its Internet website and disclose, in its most recent report on this Form N-CSR, its Internet address and the fact that it has posted such code of ethics on its Internet website; or (3) Undertake in its most recent report on this Form N-CSR to provide to any person without charge, upon request, a copy of such code of ethics and explain the manner in which such request may be made. 	See Item 10(2) ITEM 3. AUDIT COMMITTEE FINANCIAL EXPERT. (a) (1) Disclose that the registrant's board of trustees has determined that the registrant either: (i) Has at least one audit committee financial expert serving on its audit committee; or (ii) Does not have an audit committee financial expert serving on its audit committee. The registrant's Board of Trustees has determined that the registrant has at least one audit committee financial expert. (2) If the registrant provides the disclosure required by paragraph (a)(1)(i) of this Item, it must disclose the name of the audit committee financial expert and whether that person is "independent." In order to be considered "independent" for purposes of this Item, a member of an audit committee may not, other than in his or her capacity as a member of the audit committee, the board of trustees, or any other board committee: (i) Accept directly or indirectly any consulting, advisory, or other compensatory fee from the issuer; or (ii) Be an "interested person" of the investment company as defined in Section 2(a)(19) of the Act (15 U.S.C. 80a-2(a)(19)). Ms. Marguerite A. Piret, an independent trustee, is such an audit committee financial expert. (3) If the registrant provides the disclosure required by paragraph (a)(1) (ii) of this Item, it must explain why it does not have an audit committee financial expert. Not applicable. ITEM 4. PRINCIPAL ACCOUNTANT FEES AND SERVICES. (a) Disclose, under the caption AUDIT FEES, the aggregate fees billed for each of the last two fiscal years for professional services rendered by the principal accountant for the audit of the registrant's annual financial statements or services that are normally provided by the accountant in connection with statutory and regulatory filings or engagements for those fiscal years. Audit Fees Fees for audit services provided to the Fund, including fees associated with the filings of its Form N-1A, totaled approximately $36,700 in 2008 and approximately $40,475 in 2007. (b) Disclose, under the caption AUDIT-RELATED FEES, the aggregate fees billed in each of the last two fiscal years for assurance and related services by the principal accountant that are reasonably related to the performance of the audit of the registrant's financial statements and are not reported under paragraph (a) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Audit-Related Fees There were no fees for audit-related services provided to the Fund during the fiscal years ended September 30, 2008 and 2007. (c) Disclose, under the caption TAX FEES, the aggregate fees billed in each of the last two fiscal years for professional services rendered by the principal accountant for tax compliance, tax advice, and tax planning. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Tax Fees Fees for tax compliance services, primarily for tax returns, totaled $8,290 in 2008 and $7,820 in 2007. (d) Disclose, under the caption ALL OTHER FEES, the aggregate fees billed in each of the last two fiscal years for products and services provided by the principal accountant, other than the services reported in paragraphs (a) through (c) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Other Fees There were no fees for other services provided to the Fund during the fiscal years ended September 30, 2008 and 2007. (e) (1) Disclose the audit committee's pre-approval policies and procedures described in paragraph (c)(7) of Rule 2-01 of Regulation S-X. PIONEER FUNDS APPROVAL OF AUDIT, AUDIT-RELATED, TAX AND OTHER SERVICES PROVIDED BY THE INDEPENDENT AUDITOR SECTION I - POLICY PURPOSE AND APPLICABILITY The Pioneer Funds recognize the importance of maintaining the independence of their outside auditors. Maintaining independence is a shared responsibility involving Pioneer Investment Management, Inc ("PIM"), the audit committee and the independent auditors. The Funds recognize that a Fund's independent auditors: 1) possess knowledge of the Funds, 2) are able to incorporate certain services into the scope of the audit, thereby avoiding redundant work, cost and disruption of Fund personnel and processes, and 3) have expertise that has value to the Funds. As a result, there are situations where it is desirable to use the Fund's independent auditors for services in addition to the annual audit and where the potential for conflicts of interests are minimal. Consequently, this policy, which is intended to comply with Rule 210.2-01(C)(7), sets forth guidelines and procedures to be followed by the Funds when retaining the independent audit firm to perform audit, audit-related tax and other services under those circumstances, while also maintaining independence. Approval of a service in accordance with this policy for a Fund shall also constitute approval for any other Fund whose pre-approval is required pursuant to Rule 210.2-01(c)(7)(ii). In addition to the procedures set forth in this policy, any non-audit services that may be provided consistently with Rule 210.2-01 may be approved by the Audit Committee itself and any pre-approval that may be waived in accordance with Rule 210.2-01(c)(7)(i)(C) is hereby waived. Selection of a Fund's independent auditors and their compensation shall be determined by the Audit Committee and shall not be subject to this policy. SECTION II - POLICY - ---------------- -------------------------------- ------------------------------------------------- SERVICE SERVICE CATEGORY DESCRIPTION SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES CATEGORY - ---------------- -------------------------------- ------------------------------------------------- I. AUDIT Services that are directly o Accounting research assistance SERVICES related to performing the o SEC consultation, registration independent audit of the Funds statements, and reporting o Tax accrual related matters o Implementation of new accounting standards o Compliance letters (e.g. rating agency letters) o Regulatory reviews and assistance regarding financial matters o Semi-annual reviews (if requested) o Comfort letters for closed end offerings - ---------------- -------------------------------- ------------------------------------------------- II. Services which are not o AICPA attest and agreed-upon procedures AUDIT-RELATED prohibited under Rule o Technology control assessments SERVICES 210.2-01(C)(4) (the "Rule") o Financial reporting control assessments and are related extensions of o Enterprise security architecture the audit services support the assessment audit, or use the knowledge/expertise gained from the audit procedures as a foundation to complete the project. In most cases, if the Audit-Related Services are not performed by the Audit firm, the scope of the Audit Services would likely increase. The Services are typically well-defined and governed by accounting professional standards (AICPA, SEC, etc.) - ---------------- -------------------------------- ------------------------------------------------- ------------------------------------- ------------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the audit period for all services and related fees pre-approved specific service reported at each regularly subcategories. Approval of the scheduled Audit Committee independent auditors as meeting. auditors for a Fund shall constitute pre approval for these services. ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the fund fiscal year within services and related fees a specified dollar limit (including comparison to for all pre-approved specified dollar limits) specific service subcategories reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limit for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for Audit-Related Services not denoted as "pre-approved", or to add a specific service subcategory as "pre-approved" ------------------------------------- ------------------------------------ SECTION III - POLICY DETAIL, CONTINUED - ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- --------------------------- ----------------------------------------------- III. TAX SERVICES Services which are not o Tax planning and support prohibited by the Rule, o Tax controversy assistance if an officer of the Fund o Tax compliance, tax returns, excise determines that using the tax returns and support Fund's auditor to provide o Tax opinions these services creates significant synergy in the form of efficiency, minimized disruption, or the ability to maintain a desired level of confidentiality. - ----------------------- --------------------------- ----------------------------------------------- - ------------------------------------- ------------------------- AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------- ------------------------- - ------------------------------------- ------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year all such services and within a specified dollar limit related fees 				 (including comparison 			 to specified dollar 			 limits) reported 			 quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for tax services not denoted as pre-approved, or to add a specific service subcategory as "pre-approved" - ------------------------------------- ------------------------- SECTION III - POLICY DETAIL, CONTINUED - ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- --------------------------- ----------------------------------------------- IV. OTHER SERVICES Services which are not o Business Risk Management support prohibited by the Rule, o Other control and regulatory A. SYNERGISTIC, if an officer of the Fund compliance projects UNIQUE QUALIFICATIONS determines that using the Fund's auditor to provide these services creates significant synergy in the form of efficiency, minimized disruption, the ability to maintain a desired level of confidentiality, or where the Fund's auditors posses unique or superior qualifications to provide these services, resulting in superior value and results for the Fund. - ----------------------- --------------------------- ----------------------------------------------- - --------------------------------------- ------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------- -------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year within all such services and a specified dollar limit related fees 			 (including comparison 			 to specified dollar 				 limits) reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for "Synergistic" or "Unique Qualifications" Other Services not denoted as pre-approved to the left, or to add a specific service subcategory as "pre-approved" - ------------------------------------- -------------------------- SECTION III - POLICY DETAIL, CONTINUED - ----------------------- ------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PROHIBITED SERVICE SUBCATEGORIES DESCRIPTION - ----------------------- ------------------------- ----------------------------------------------- PROHIBITED SERVICES Services which result 1. Bookkeeping or other services in the auditors losing related to the accounting records or independence status financial statements of the audit under the Rule. client* 2. Financial information systems design and implementation* 3. Appraisal or valuation services, fairness* opinions, or contribution-in-kind reports 4. Actuarial services (i.e., setting actuarial reserves versus actuarial audit work)* 5. Internal audit outsourcing services* 6. Management functions or human resources 7. Broker or dealer, investment advisor, or investment banking services 8. Legal services and expert services unrelated to the audit 9. Any other service that the Public Company Accounting Oversight Board determines, by regulation, is impermissible - ----------------------- ------------------------- ----------------------------------------------- - ------------------------------------------- ------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY - ------------------------------------------- ------------------------------ o These services are not to be o A summary of all performed with the exception of the(*) services and related services that may be permitted fees reported at each if they would not be subject to audit regularly scheduled procedures at the audit client (as Audit Committee meeting defined in rule 2-01(f)(4)) level will serve as continual the firm providing the service. confirmation that has 				 not provided any restricted services. - ------------------------------------------- ------------------------------ - -------------------------------------------------------------------------------- GENERAL AUDIT COMMITTEE APPROVAL POLICY: o For all projects, the officers of the Funds and the Fund's auditors will each make an assessment to determine that any proposed projects will not impair independence. o Potential services will be classified into the four non-restricted service categories and the "Approval of Audit, Audit-Related, Tax and Other Services" Policy above will be applied. Any services outside the specific pre-approved service subcategories set forth above must be specifically approved by the Audit Committee. o At least quarterly, the Audit Committee shall review a report summarizing the services by service category, including fees, provided by the Audit firm as set forth in the above policy. - -------------------------------------------------------------------------------- (2) Disclose the percentage of services described in each of paragraphs (b) through (d) of this Item that were approved by the audit committee pursuant to paragraph (c)(7)(i)(C) of Rule 2-01 of Regulation S-X. Beginning with non-audit service contracts entered into on or after May 6, 2003, the effective date of the new SEC pre-approval rules, the Fund's audit committee is required to pre-approve services to affiliates defined by SEC rules to the extent that the services are determined to have a direct impact on the operations or financial reporting of the Fund. For the years ended September 30, 2008 and 2007, there were no services provided to an affiliate that required the Fund's audit committee pre-approval. (f) If greater than 50 percent, disclose the percentage of hours expended on the principal accountant's engagement to audit the registrant's financial statements for the most recent fiscal year that were attributed to work performed by persons other than the principal accountant's full-time, permanent employees. N/A (g) Disclose the aggregate non-audit fees billed by the registrant's accountant for services rendered to the registrant, and rendered to the registrant's investment adviser (not including any sub-adviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the adviser that provides ongoing services to the registrant for each of the last two fiscal years of the registrant. The aggregate non-audit fees for the Fund and affiliates, as previously defined, totaled approximately $8,290 in 2008 and $7,820 in 2007. (h) Disclose whether the registrant's audit committee of the board of trustees has considered whether the provision of non-audit services that were rendered to the registrant's investment adviser (not including any subadviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the investment adviser that provides ongoing services to the registrant that were not pre-approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. The Fund's audit committee of the Board of Trustees has considered whether the provision of non-audit services that were rendered to the Affiliates (as defined) that were not pre- approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. Item 5. Audit Committee of Listed Registrants (a) If the registrant is a listed issuer as defined in Rule 10A-3 under the Exchange Act (17 CFR 240.10A-3), state whether or not the registrant has a separately-designated standing audit committee established in accordance with Section 3(a)(58)(A) of the Exchange Act (15 U.S.C. 78c(a)(58)(A)). If the registrant has such a committee, however designated, identify each committee member. If the entire board of directors is acting as the registrants audit committee as specified in Section 3(a)(58)(B) of the Exchange Act (15 U.S.C. 78c(a)(58)(B)), so state. N/A (b) If applicable, provide the disclosure required by Rule 10A-3(d) under the Exchange Act (17 CFR 240.10A-3(d)) regarding an exemption from the listing standards for audit committees. N/A Item 6. Schedule of Investments. File Schedule I Investments in securities of unaffiliated issuers as of the close of the reporting period as set forth in 210.12- 12 of Regulation S-X [17 CFR 210.12-12], unless the schedule is included as part of the report to shareholders filed under Item 1 of this Form. Included in Item 1 ITEM 7. DISCLOSURE OF PROXY VOTING POLICIES AND PROCEDURES FOR CLOSED-END MANAGEMENT INVESTMENT COMPANIES. A closed-end management investment company that is filing an annual report on this Form N-CSR must, unless it invests exclusively in non-voting securities, describe the policies and procedures that it uses to determine how to vote proxies relating to portfolio securities, including the procedures that the company uses when a vote presents a conflict between the interests of its shareholders, on the one hand, and those of the company's investment adviser; principal underwriter; or any affiliated person (as defined in Section 2(a)(3) of the Investment Company Act of 1940 (15 U.S.C. 80a-2(a)(3)) and the rules thereunder) of the company, its investment adviser, or its principal underwriter, on the other. Include any policies and procedures of the company's investment adviser, or any other third party, that the company uses, or that are used on the company's behalf, to determine how to vote proxies relating to portfolio securities. Not applicable to open-end management investment companies. Item 8. Portfolio Managers of Closed-End Management Investment Companies. (a) If the registrant is a closed-end management investment company that is filing an annual report on this Form N-CSR,provide the following information: (1) State the name, title, and length of service of the person or persons employed by or associated with the registrant or an investment adviser of the registrant who are primarily responsible for the day-to-day management of the registrants portfolio (Portfolio Manager). Also state each Portfolio Managers business experience during the past 5 years. Not applicable to open-end management investment companies. Item 9. Purchases of Equity Securities by Closed-End Management Investment Company and Affiliated Purchasers. (a) If the registrant is a closed-end management investment company, in the following tabular format, provide the information specified in paragraph (b) of this Item with respect to any purchase made by or on behalf of the registrant or any affiliated purchaser, as defined in Rule 10b-18(a)(3) under the Exchange Act (17 CFR 240.10b-18(a)(3)), of shares or other units of any class of the registrants equity securities that is registered by the registrant pursuant to Section 12 of the Exchange Act (15 U.S.C. 781). Instruction to paragraph (a). Disclose all purchases covered by this Item, including purchases that do not satisfy the conditions of the safe harbor of Rule 10b-18 under the Exchange Act (17 CFR 240.10b-18), made in the period covered by the report. Provide disclosures covering repurchases made on a monthly basis. For example, if the reporting period began on January 16 and ended on July 15, the chart would show repurchases for the months from January 16 through February 15, February 16 through March 15, March 16 through April 15, April 16 through May 15, May 16 through June 15, and June 16 through July 15. Not applicable to open-end management investment companies. Item 10. Submission of Matters to a Vote of Security Holders. Describe any material changes to the procedures by which shareholders may recommend nominees to the registrants board of directors, where those changes were implemented after the registrant last provided disclosure in response to the requirements of Item 7(d)(2)(ii)(G) of Schedule 14A (17 CFR 240.14a-101), or this Item. There have been no material changes to the procedures by which the shareholders may recommend nominees to the registrants board of directors since the registrant last provided disclosure in response to the requirements of Item 7(d)(2)(ii)(G) of Schedule 14(A) in its definitive proxy statement, or this Item. ITEM 11. CONTROLS AND PROCEDURES. (a) Disclose the conclusions of the registrant's principal executive officer or officers and principal financial officer or officers, or persons performing similar functions, about the effectiveness of the registrant's disclosure controls and procedures (as defined in Rule 30a-2(c) under the Act (17 CFR 270.30a-2(c))) based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of the report that includes the disclosure required by this paragraph. The registrant's principal executive officer and principal financial officer have concluded that the registrant's disclosure controls and procedures are effective based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of this report. (b) Disclose whether or not there were significant changes in the registrant's internal controls or in other factors that could significantly affect these controls subsequent to the date of their evaluation, including any corrective actions with regard to significant deficiencies and material weaknesses. There were no significant changes in the registrant's internal control over financial reporting that occurred during the second fiscal quarter of the period covered by this report that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting. The registrant's principal executive officer and principal financial officer, however, voluntarily are reporting the following information: In August of 2006 the registrant's investment adviser enhanced its internal procedures for reporting performance information required to be included in prospectuses. Those enhancements involved additional internal controls over the appropriateness of performance data generated for this purpose. Such enhancements were made following an internal review which identified prospectuses relating to certain classes of shares of a limited number of registrants where, inadvertently, performance information not reflecting the deduction of applicable sales charges was included. Those prospectuses were revised, and the revised prospectuses were distributed to shareholders. ITEM 12. EXHIBITS. File the exhibits listed below as part of this Form. Letter or number the exhibits in the sequence indicated. (a) Any code of ethics, or amendment thereto, that is the subject of the disclosure required by Item 2, to the extent that the registrant intends to satisfy the Item 2 requirements through filing of an exhibit. (b) A separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2 under the Act (17 CFR 270.30a-2). Filed herewith. SIGNATURES [See General Instruction F] Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized. (Registrant) Pioneer Value Fund By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr, President Date November 28, 2008 Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated. By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr., President Date November 28, 2008 By (Signature and Title)* /s/ Mark Bradley Mark Bradley, Treasurer Date November 28, 2008 * Print the name and title of each signing officer under his or her signature.