EXHIBIT 4.14 CERTIFICATE OF TRUST OF CALPINE CAPITAL TRUST V THIS Certificate of Trust of Calpine Capital Trust V (the "Trust"), dated as of January 10, 2002, is being duly executed and filed by the undersigned, as trustees, to form a business trust under the Delaware Business Trust Act (12 Del. C. Section 3801 et seq.) (the "Act"). 1. Name. The name of the business trust formed hereby is "Calpine Capital Trust V". 2. Delaware Trustee. The name and business address of the trustee of the Trust in the State of Delaware are Wilmington Trust Company, 1100 North Market Street, Wilmington, Delaware 19890-0001, Attn: Corporate Trust Administration. 3. Effective Date. This Certificate of Trust shall be effective upon filing with the Secretary of State of the State of Delaware. IN WITNESS WHEREOF, the undersigned, being the trustees of the Trust, have duly executed this Certificate of Trust in accordance with Section 3811(a) of the Act. WILMINGTON TRUST COMPANY, not in its individual capacity, but solely as trustee of the Trust By: /s/ BRUCE L. BISSON -------------------------------- Name: BRUCE L. BISSON ------------------------------ Title: VICE PRESIDENT ----------------------------- /s/ ANN B. CURTIS ------------------------------------ ANN B. CURTIS, not in her individual capacity, but solely as trustee of the Trust