<Page>

                                                              Exhibit 99.906Cert

                  CERTIFICATIONS PURSUANT TO SECTION 906 OF THE
                           SARBANES-OXLEY ACT OF 2002

David G. Booth, Principal Executive Officer, and Michael T. Scardina, Principal
Accounting Officer, of Dimensional Emerging Markets Value Fund Inc., a Maryland
corporation (the "Registrant"), each certify that:

     1.   The Registrant's periodic report on Form N-CSR for the period ended
          November 30, 2005 (the "Report") fully complies with the requirements
          of Section 13(a) or Section 15(d) of the Securities Exchange Act of
          1934, as amended, as applicable; and

     2.   The information contained in the Report fairly presents, in all
          material respects, the financial condition and results of operations
          of the Registrant.


By:    /s/ David G. Booth
       -----------------------------------
       David G. Booth
       Principal Executive Officer
       Dimensional Emerging Markets Value Fund Inc.

Date: February 3, 2006


By:    /s/ Michael T. Scardina
       -----------------------------------
       Michael T. Scardina
       Principal Accounting Officer
       Dimensional Emerging Markets Value Fund Inc.

Date: February 3, 2006