OMB APPROVAL OMB Number: 3235-0570 Expires: January 31, 2014 Estimated average burden hours per response.....20.6 UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM N-CSR CERTIFIED SHAREHOLDER REPORT OF REGISTERED MANAGEMENT INVESTMENT COMPANIES 		Investment Company Act file number 811-21664 Pioneer Series Trust V (Exact name of registrant as specified in charter) 60 State Street, Boston, MA 02109 (Address of principal executive offices) (ZIP code) Terrence J. Cullen, Pioneer Investment Management, Inc., 60 State Street, Boston, MA 02109 (Name and address of agent for service) Registrant's telephone number, including area code: (617) 742-7825 Date of fiscal year end: August 31 Date of reporting period: September 1, 2012 through August 31, 2013 Form N-CSR is to be used by management investment companies to file reports with the Commission not later than 10 days after the transmission to stockholders of any report that is required to be transmitted to stockholders under Rule 30e-1 under the Investment Company Act of 1940 (17 CFR 270.30e-1). The Commission may use the information provided on Form N-CSR in its regulatory, disclosure review, inspection, and policymaking roles. A registrant is required to disclose the information specified by Form N-CSR, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-CSR unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. ss. 3507. ITEM 1. REPORTS TO STOCKHOLDERS. Pioneer Global Equity Fund -------------------------------------------------------------------------------- Annual Report | August 31, 2013 -------------------------------------------------------------------------------- Ticker Symbols: Class A GLOSX Class B GBSLX Class C GCSLX Class Y PGSYX [LOGO] PIONEER Investments(R) visit us: us.pioneerinvestments.com Table of Contents Letter to Shareowners 2 Portfolio Management Discussion 4 Portfolio Summary 8 Prices and Distributions 9 Performance Update 10 Comparing Ongoing Fund Expenses 14 Schedule of Investments 16 Financial Statements 23 Notes to Financial Statements 31 Report of Independent Registered Public Accounting Firm 42 Trustees, Officers and Service Providers 43 Pioneer Global Equity Fund | Annual Report | 8/31/13 1 President's Letter Dear Shareowner, When we look at the U.S. economy as we head into the second half of 2013, we continue to see slow, but ongoing, growth. Employment has been steadily rising. Consumer incomes, savings, wealth, and debt-servicing capacity have been solid buttresses for the recovering housing and auto industries. Industrial activity is growing only modestly, but current corporate profits are generally solid and balance sheets appear able to support needed capital spending and dividend* payouts. The scaled-back "fiscal cliff" tax increases and spending cuts have meaningfully cut the budget deficit without, it seems, driving the economy back into recession. In addition, we feel that continuing slack in labor markets and capacity utilization offers the potential for continuing growth without bottlenecks and rising inflation. After observing the strengthening economic trends, the Federal Reserve (the Fed) has hinted that it may begin to scale back its bond purchases (currently $85 billion per month in quantitative easing, or "QE") later in 2013, and could terminate the purchases altogether sometime in 2014, depending on subsequent economic data releases. Pioneer believes that, barring an external shock, modest economic growth can be sustained at least over the next couple of years without continuous, aggressive intervention from the Fed. The Fed has also said that short-term interest rates are likely to remain near zero for some time to come. Given that inflation remains subdued and unemployment remains high, there is no urgency about raising rates. While inflation is not a near-term concern, the Fed's aggressive monetary policies helped investors drive long-term Treasury yields to unsustainably low levels. A return to more normal levels in response to expectations of a stronger economy and the potential for less QE resulted in disappointing returns for bond investors during the first half of 2013, but the stock market rewarded shareholders who were undaunted by the double-barreled threat of the "fiscal cliff" and debt-ceiling debates at the beginning of 2013. The Standard & Poor's 500 Index, a broad measure of the U.S. stock market, returned 13.82% during the first six months of 2013, while the Barclays Aggregate Bond Index, which tracks the performance of a higher-quality U.S. bond universe, returned -2.44%. Investors showed a rising preference for higher-yielding corporate paper over government bonds during the first half of 2013, helping the Bank of America Merrill Lynch High Yield Master II Index, which measures the performance of high-yield corporate bonds, to post a 1.50% return for the six months ended June 30, 2013. Three-month Treasury bills, generally regarded as essentially "risk free" by the markets, returned 0.03% in the first half of 2013. * Dividends are not guaranteed. 2 Pioneer Global Equity Fund | Annual Report | 8/31/13 There are certainly risks and uncertainties that continue to plague the global economy. Europe remains in recession and a number of countries in the emerging markets have experienced difficulties. Still, a potential ending of the European recession, continuing economic improvement in Japan in response to the new government's quantitative easing policies, and a "soft landing" of 7% growth in China could very well result in an improving global outlook over the remainder of 2013. There are also geopolitical worries abroad and political fights at home, and while most of the widely recognized risks we've outlined may already be "priced in" to the market, we believe investors should continue to expect market volatility. At Pioneer, we have long advocated the benefits of staying diversified and investing for the long term. And while diversification alone does not assure a profit or protect against loss in a declining market, we believe there are still opportunities for prudent investors to earn attractive returns. Our advice, as always, is to work closely with a trusted financial advisor to discuss your goals and work together to develop an investment strategy that meets your individual needs, keeping in mind that there is no single best strategy that works for every investor. Pioneer's investment teams have, since 1928, sought out attractive opportunities in global equity and bond markets, using in-depth research to identify undervalued individual securities, and using thoughtful risk management to construct portfolios which balance potential risks and rewards in an ever-changing world. We encourage you to learn more about Pioneer and our time-tested approach to investing by consulting with your financial advisor or visiting us online at us.pioneerinvestments.com. We greatly appreciate your trust in us, and we thank you for investing with Pioneer. Sincerely, /s/ Daniel K. Kingsbury Daniel K. Kingsbury President and CEO Pioneer Investment Management USA, Inc. Any information in this shareowner report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of opinion as of the date of this report. These statements should not be relied upon for any other purposes. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Pioneer Global Equity Fund | Annual Report | 8/31/13 3 Portfolio Management Discussion | 8/31/13 In the following interview, Marco Pirondini, Head of Equities, U.S., at Pioneer and a portfolio manager of Pioneer Global Equity Fund, discusses the factors that influenced the Fund's performance during the 12-month period ended August 31, 2013. Mr. Pirondini and David Glazer, a vice president and a portfolio manager at Pioneer, are responsible for the day-to-day management of the Fund. Q How would you characterize the investment environment in the global equity markets during the 12 months ended August 31, 2013? A Over the past 12 months, global investors were encouraged by continued intervention from the European Central Bank in an attempt to stabilize the European sovereign-debt situation. Market watchers also reacted positively to moves toward economic reform made by Japan's new government as well as new leadership for that country's central bank. Revised economic programs in Japan produced a major devaluation of the yen and sparked a sharp equity rally there during the 12-month period. In May of 2013, investors were rattled by Federal Reserve Board's (the Fed's) statements indicating that the U.S. central bank might soon consider tapering the pace of its monthly purchases of $85 billion in government and agency mortgage-backed securities. Most of the resulting market volatility was concentrated in the emerging markets, but the fixed-income and equity markets as a whole also corrected, and longer-term interest rates rose. Fed officials subsequently stated - based on mixed U.S. economic data - that any reduction of the pace of its asset purchases was not imminent, and stocks soon after regained their upward momentum. Q How did the Fund perform in that environment during the 12 months ended August 31, 2013? A Pioneer Global Equity Fund's Class A shares returned 19.17% at net asset value during the 12 months ended August 31, 2013, while the Fund's benchmark, the Morgan Stanley Capital International (MSCI) World ND Index (the MSCI Index)(1), returned 17.63%. During the same period, the average return of the 1,013 mutual funds in Morningstar's World Stock Funds category was 17.44%. 1 The MSCI information may only be used for your internal use, may not be reproduced or re-disseminated in any form and may not be used as a basis for or a component of any financial instruments or products or indices. None of the MSCI information is intended to constitute investment advice or a recommendation to make (or refrain from making) any kind of investment decision and may not be relied on as such. Historical data and analysis should not be taken as an indication or guarantee of any future performance analysis, forecast or prediction. The MSCI information is provided on an "as is" basis and the user of this information assumes the entire risk of any use made of this information. MSCI, each of its affiliates and each other person involved in or related to compiling, computing or creating any MSCI information (collectively, the "MSCI Parties") expressly disclaims all warranties (including, without limitation, any warranties of originality, accuracy, completeness, timeliness, non-infringement, merchantability and fitness for a particular purpose) with respect to this information. Without limiting any of the foregoing, in no event shall any MSCI Party have any liability for any direct, indirect, special, incidental, punitive, consequential (including, without limitation, lost profits) or any other damages. 4 Pioneer Global Equity Fund | Annual Report | 8/31/13 Q Would you review the Fund's overall investment approach? A We examine mid- and large-capitalization stocks worldwide, including those located in the emerging markets. From there, we build a diversified* portfolio. In selecting securities for the Fund's portfolio, we look for "growth at a reasonable price," and so there is a strong value component to our analysis. We seek to invest the Fund's assets in companies that are not only benefiting from operating efficiencies, as reflected in factors including increased market share and revenues, but that are also employing their capital efficiently. In particular, we emphasize companies with strong free cash flow, because that tends to provide companies with the flexibility to make share buybacks, reinvest in their businesses, make acquisitions and raise dividends**. We also look for stocks with attractive dividend yields as well as those trading at lower-than-market valuations. Finally, we attempt to assess not only the potential price gains for each stock, but also the potential for a decline in price if circumstances become unfavorable. We prefer to have the Fund hold stocks of companies with the highest upside potential, relative to their downside. Q What factors contributed to and detracted from the Fund's performance during the 12 months ended August 31, 2013? A During the period, the Fund was well positioned to capitalize on the positive trend in the equity markets, and both stock selection and sector allocation helped performance. In terms of sector allocation, the Fund strongly benefited from portfolio overweights to the health care sector as well from underweights to materials and utilities. On the other hand, portfolio underweights to information technology and consumer discretionary detracted slightly from returns. Stock selection in the energy sector made a substantial contribution to performance, and selection in industrials and consumer staples also added to the Fund's returns, while stock selection within information technology, telecom services and financials detracted from performance. Regarding individual stocks held in the portfolio, the Fund's position in the oil refining company Marathon Petroleum performed extremely well during the period, as many refiners, including Marathon, profited from comparatively low U.S. oil prices and the ability to export refined petroleum products at healthy margins. In addition, the Fund's position in the biotechnology firm Celgene added to returns as the company benefited from FDA drug approvals and strong sales of its existing products. The Fund's holdings in Alliance Global and Green Mountain Coffee Roasters also contributed strongly. * Diversification does not assure a profit nor protect against loss in a declining market. ** Dividends are not guaranteed. Pioneer Global Equity Fund | Annual Report | 8/31/13 5 Positions detracting from the Fund's performance included Apple and Freeport McMoRan Copper and Gold. Investors have punished Apple's shares over the past 12 months, despite the technology firm's continued strong revenue stream. We trimmed the Fund's position in Apple to limit losses. In the case of Freeport McMoRan, a U.S.-based mining company, market watchers disapproved of the company's recent - and expensive - acquisitions. Q What is your outlook? A Though the global economy currently presents a number of risks, including high sovereign-debt levels, the possibility of escalating conflict in the Middle East, and an economic slowdown in China, we nevertheless believe that global stocks appear inexpensive when compared with other financial assets. Corporations around the world are, in general, in excellent financial condition, with strong profitability and healthy balance sheets that can provide them with ample strategic flexibility. Even if we see just a modest level of global economic growth going forward, and despite the market's "wall of worry," we still look for respectable corporate earnings growth. We also think that central banks worldwide will remain supportive of the global economy as well as equity markets over the coming months. When central bank stimulus eventually does diminish, we think that major economies will be able to demonstrate ample growth on their own, which would also be a positive for global stocks. 6 Pioneer Global Equity Fund | Annual Report | 8/31/13 Please refer to the Schedule of Investments on pages 16-22 for a full listing of fund securities. Investing in foreign and/or emerging markets securities involves risks relating to interest rates, currency exchange rates, economic, and political conditions. The Fund is subject to currency risk, meaning that the fund could experience losses based on changes in the exchange rate between non-U.S. currencies and the U.S. dollar. Investing in small and mid-sized companies may offer the potential for higher returns, but are also subject to greater short-term price fluctuations than larger, more established companies. When interest rates rise, the prices of fixed-income securities in the Fund will generally fall. Conversely, when interest rates fall, the prices of fixed-income securities in the Fund will generally rise. The portfolio may invest in derivative securities, which may include futures and options. These types of instruments can increase price fluctuation. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making it more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. These risks may increase share price volatility. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of opinion as of the date of this report. These statements should not be relied upon for any other purposes. Pioneer Global Equity Fund | Annual Report | 8/31/13 7 Portfolio Summary | 8/31/13 Sector Distribution -------------------------------------------------------------------------------- (As a percentage of long-term holdings) [THE FOLLOWING DATA WAS REPRESENTED AS A PIE CHART IN THE PRINTED MATERIAL] Financials 19.8% Health Care 15.6% Information Technology 15.3% Consumer Staples 11.8% Industrials 9.5% Energy 9.4% Consumer Discretionary 9.4% Telecommunication Services 6.7% Materials 2.5% Geographical Distribution -------------------------------------------------------------------------------- (As a percentage of long-term holdings) [THE FOLLOWING DATA WAS REPRESENTED AS A BAR CHART IN THE PRINTED MATERIAL] United States 51.7% United Kingdom 10.0% Japan 9.9% Switzerland 5.7% Germany 4.1% Ireland 4.0% France 2.4% Netherlands 1.7% Spain 1.5% Canada 1.4% Other (individually less than 1%) 7.6% 10 Largest Holdings -------------------------------------------------------------------------------- (As a percentage of long-term holdings)* 1. Microsoft Corp. 3.18% -------------------------------------------------------------------------------- 2. Novartis AG 2.81 -------------------------------------------------------------------------------- 3. Green Mountain Coffee Roasters, Inc. 2.34 -------------------------------------------------------------------------------- 4. Yahoo!, Inc. 2.26 -------------------------------------------------------------------------------- 5. Vodafone Group Plc 2.23 -------------------------------------------------------------------------------- 6. 3M Co. 2.19 -------------------------------------------------------------------------------- 7. HSBC Holdings Plc 2.18 -------------------------------------------------------------------------------- 8. Vodafone Group Plc (A.D.R.) 2.05 -------------------------------------------------------------------------------- 9. Nippon Telegraph & Telephone Corp. 2.05 -------------------------------------------------------------------------------- 10. Occidental Petroleum Corp. 2.03 -------------------------------------------------------------------------------- * This list excludes temporary cash investments and derivative instruments. The portfolio is actively managed, and current holdings may be different. The holdings listed should not be considered recommendations to buy or sell any security listed. 8 Pioneer Global Equity Fund | Annual Report | 8/31/13 Prices and Distributions | 8/31/13 Net Asset Value per Share -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Class 8/31/13 8/31/12 -------------------------------------------------------------------------------- A $11.31 $9.64 -------------------------------------------------------------------------------- B $11.14 $9.48 -------------------------------------------------------------------------------- C $11.11 $9.47 -------------------------------------------------------------------------------- Y $11.37 $9.69 -------------------------------------------------------------------------------- Distributions per Share: 9/1/12-8/31/13 -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Net Investment Short-Term Long-Term Class Income Capital Gains Capital Gains -------------------------------------------------------------------------------- A $0.1590 $ -- $ -- -------------------------------------------------------------------------------- B $0.0527 $ -- $ -- -------------------------------------------------------------------------------- C $0.0677 $ -- $ -- -------------------------------------------------------------------------------- Y $0.2086 $ -- $ -- -------------------------------------------------------------------------------- The Morgan Stanley Capital International (MSCI) World ND Index is an unmanaged measure of the performance of stock markets in the developed world. Index returns are calculated monthly, assume reinvestment of dividends and, unlike Fund returns, do not reflect any fees, expenses or sales charges. It is not possible to invest directly in an index. The index defined here pertains to the "Value of $10,000 Investment" and "Value of $5 Million Investment" charts on pages 10-13. Pioneer Global Equity Fund | Annual Report | 8/31/13 9 Performance Update | 8/31/13 Class A Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Class A shares of Pioneer Global Equity Fund at public offering price during the periods shown, compared to that of the Morgan Stanley Capital International (MSCI) World ND Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- Net Asset Public Offering Period Value (NAV) Price (POP) -------------------------------------------------------------------------------- Life-of-Class 12/15/2005 3.69% 2.90% 5 Years 2.94 1.72 1 Year 19.17 12.30 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross Net -------------------------------------------------------------------------------- 1.72% 1.30% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $10,000 Investment Pioneer Global MSCI World Equity Fund ND Index 12/31/2005 9425.00 10000.00 8/31/2006 10547.00 10949.00 8/31/2007 12085.00 12807.00 8/31/2008 10794.00 11261.00 8/31/2009 9085.00 9323.00 8/31/2010 8982.00 9467.00 8/31/2011 9923.00 10836.00 8/31/2012 10470.00 11716.00 8/31/2013 12477.00 13781.00 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. NAV results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. POP returns reflect deduction of maximum 5.75% sales charge. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The net expense ratio reflects contractual expense limitations currently in effect through January 1, 2014, for Class A shares. There can be no assurance that Pioneer will extend the expense limitations beyond such time. Please see the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 10 Pioneer Global Equity Fund | Annual Report | 8/31/13 Performance Update | 8/31/13 Class B Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Class B shares of Pioneer Global Equity Fund during the periods shown, compared to that of the Morgan Stanley Capital International (MSCI) World ND Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- If If Period Held Redeemed -------------------------------------------------------------------------------- Life-of-Class 12/15/2005 2.76% 2.76% 5 Years 2.02 2.02 1 Year 18.13 14.13 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross Net -------------------------------------------------------------------------------- 3.14% 2.20% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $10,000 Investment Pioneer Global MSCI World Equity Fund ND Index 12/31/2005 10000.00 10000.00 8/31/2006 11111.00 10949.00 8/31/2007 12617.00 12807.00 8/31/2008 11172.00 11261.00 8/31/2009 9320.00 9323.00 8/31/2010 9133.00 9467.00 8/31/2011 9992.00 10836.00 8/31/2012 10452.00 11716.00 8/31/2013 12346.00 13781.00 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. "If Redeemed" returns reflect the deduction of applicable contingent deferred sales charge (CDSC). The maximum CDSC for Class B shares is 4% and declines over five years. For more complete information, please see the prospectus. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The net expense ratio reflects contractual expense limitations currently in effect through January 1, 2014, for Class B shares. There can be no assurance that Pioneer will extend the expense limitations beyond such time. Please see the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. Pioneer Global Equity Fund | Annual Report | 8/31/13 11 Performance Update | 8/31/13 Class C Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Class C shares of Pioneer Global Equity Fund during the periods shown, compared to that of the Morgan Stanley Capital International (MSCI) World ND Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- If If Period Held Redeemed -------------------------------------------------------------------------------- Life-of-Class 12/15/2005 2.76% 2.76% 5 Years 2.01 2.01 1 Year 18.11 18.11 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross Net -------------------------------------------------------------------------------- 2.53% 2.20% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $10,000 Investment Pioneer Global MSCI World Equity Fund ND Index 12/31/2005 10000.00 10000.00 8/31/2006 11111.00 10949.00 8/31/2007 12628.00 12807.00 8/31/2008 11179.00 11261.00 8/31/2009 9326.00 9323.00 8/31/2010 9139.00 9467.00 8/31/2011 9997.00 10836.00 8/31/2012 10453.00 11716.00 8/31/2013 12347.00 13781.00 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Class C shares held for less than one year are also subject to a 1% contingent deferred sales charge (CDSC). "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The net expense ratio reflects contractual expense limitations currently in effect through January 1, 2014, for Class C shares. There can be no assurance that Pioneer will extend the expense limitations beyond such time. Please see the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 12 Pioneer Global Equity Fund | Annual Report | 8/31/13 Performance Update | 8/31/13 Class Y Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $5 million investment made in Class Y shares of Pioneer Global Equity Fund during the periods shown, compared to that of the Morgan Stanley Capital International (MSCI) World ND Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- If If Period Held Redeemed -------------------------------------------------------------------------------- Life-of-Class 12/15/2005 4.01% 4.01% 5 Years 3.43 3.43 1 Year 19.75 19.75 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross Net -------------------------------------------------------------------------------- 0.97% 0.80% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $5 Million Investment Pioneer Global MSCI World Equity Fund ND Index 12/31/2005 5000000.00 5000000.00 8/31/2006 5595596.00 5474445.00 8/31/2007 6411652.00 6403612.00 8/31/2008 5726587.00 5630699.00 8/31/2009 4836744.00 4661475.00 8/31/2010 4808018.00 4733454.00 8/31/2011 5335128.00 5417874.00 8/31/2012 5659822.00 5857774.00 8/31/2013 6777847.00 6890617.00 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Performance shown for periods prior to the inception of the Fund's Class Y shares on December 31, 2008, is the NAV performance of the Fund's Class A shares. The performance does not reflect differences in expenses, including the Rule 12b-1 fees applicable to Class A shares. Since fees for Class A shares are generally higher than those of Class Y shares, the performance for Class Y shares prior to their inception would have been higher than the performance shown. Class Y shares are not subject to sales charges and are available for limited groups of eligible investors, including institutional investors. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The net expense ratio reflects contractual expense limitations currently in effect through January 1, 2014, for Class Y shares. There can be no assurance that Pioneer will extend the expense limitations beyond such time. Please see the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. Pioneer Global Equity Fund | Annual Report | 8/31/13 13 Comparing Ongoing Fund Expenses As a shareowner in the Fund, you incur two types of costs: (1) ongoing costs, including management fees, distribution and/or service (12b-1) fees, and other Fund expenses; and (2) transaction costs, including sales charges (loads) on purchase payments and redemption fees. This example is intended to help you understand your ongoing expenses (in dollars) of investing in the Fund and to compare these costs with the ongoing costs of investing in other mutual funds. The example is based on an investment of $1,000 at the beginning of the Fund's latest six-month period and held throughout the six months. Using the Tables -------------------------------------------------------------------------------- Actual Expenses The first table below provides information about actual account values and actual expenses. You may use the information in this table, together with the amount you invested, to estimate the expenses that you paid over the period as follows: (1) Divide your account value by $1,000 Example: an $8,600 account value (divided by) $1,000 = 8.6 (2) Multiply the result in (1) above by the corresponding share class's number in the third row under the heading entitled "Expenses Paid During Period" to estimate the expenses you paid on your account during this period. Expenses Paid on a $1,000 Investment in Pioneer Global Equity Fund Based on actual returns from March 1, 2013, through August 31, 2013. -------------------------------------------------------------------------------- Share Class A B C Y -------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 $1,000.00 Value on 3/1/13 -------------------------------------------------------------------------------- Ending Account $1,051.16 $1,046.05 $1,046.15 $1,053.77 Value on 8/31/13 -------------------------------------------------------------------------------- Expenses Paid $ 6.82 $ 11.45 $ 11.45 $ 4.24 During Period* -------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized net expense ratio plus the expense ratios of the underlying funds. These combined totals were 1.30%, 2.20%, 2.20% and 0.80% for Class A, Class B, Class C and Class Y shares, respectively. These combined ratios were multiplied by the average account value over the period, and then multiplied by 184/365 (to reflect the one-half year period) to calculate the "Expenses Paid During Period" in the table above. 14 Pioneer Global Equity Fund | Annual Report | 8/31/13 Hypothetical Example for Comparison Purposes The table below provides information about hypothetical account values and hypothetical expenses based on the Fund's actual expense ratio and an assumed rate of return of 5% per year before expenses, which is not the Fund's actual return. The hypothetical account values and expenses may not be used to estimate the actual ending account balance or expenses you paid for the period. You may use this information to compare the ongoing costs of investing in the Fund and other funds. To do so, compare this 5% hypothetical example with the 5% hypothetical examples that appear in the shareholder reports of the other funds. Please note that the expenses shown in the tables are meant to highlight your ongoing costs only and do not reflect any transaction costs, such as sales charges (loads) or redemption fees that are charged at the time of the transaction. Therefore, the table below is useful in comparing ongoing costs only and will not help you determine the relative total costs of owning different funds. In addition, if these transaction costs were included, your costs would have been higher. Expenses Paid on a $1,000 Investment in Pioneer Global Equity Fund Based on a hypothetical 5% return per year before expenses, reflecting the period from March 1, 2013, through August 31, 2013. -------------------------------------------------------------------------------- Share Class A B C Y -------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 $1,000.00 Value on 3/1/13 -------------------------------------------------------------------------------- Ending Account $1,018.55 $1,014.01 $1,014.01 $1,021.07 Value on 8/31/13 -------------------------------------------------------------------------------- Expenses Paid $ 6.72 $ 11.27 $ 11.27 $ 4.18 During Period* -------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized net expense ratio plus the expense ratios of the underlying funds. These combined totals were 1.30%, 2.20%, 2.20% and 0.80% for Class A, Class B, Class C and Class Y shares, respectively. These combined ratios were multiplied by the average account value over the period, and then multiplied by 184/365 (to reflect the one-half year period) to calculate the "Expenses Paid During Period" in the table above. Pioneer Global Equity Fund | Annual Report | 8/31/13 15 Schedule of Investments | 8/31/13 ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ COMMON STOCKS -- 98.7% ENERGY -- 9.4% Oil & Gas Equipment & Services -- 1.2% 7,100 Frank's International NV* $ 196,741 32,467 Halliburton Co. 1,558,416 ------------- $ 1,755,157 ------------------------------------------------------------------------------------ Integrated Oil & Gas -- 2.9% 32,700 Occidental Petroleum Corp. $ 2,884,467 21,200 Total SA 1,172,385 ------------- $ 4,056,852 ------------------------------------------------------------------------------------ Oil & Gas Exploration & Production -- 5.3% 30,200 Apache Corp. $ 2,587,536 724,400 CNOOC, Ltd. 1,449,470 8,100 EOG Resources, Inc. 1,272,105 32,100 Gulfport Energy Corp.* 1,893,900 2,400 Pioneer Natural Resources Co. 419,928 ------------- $ 7,622,939 ------------- Total Energy $ 13,434,948 ------------------------------------------------------------------------------------ MATERIALS -- 1.9% Commodity Chemicals -- 1.2% 23,900 LyondellBasell Industries NV $ 1,676,585 ------------------------------------------------------------------------------------ Fertilizers & Agricultural Chemicals -- 0.2% 3,500 Monsanto Co. $ 342,615 ------------------------------------------------------------------------------------ Specialty Chemicals -- 0.5% 9,600 WR Grace & Co.* $ 771,360 ------------- Total Materials $ 2,790,560 ------------------------------------------------------------------------------------ CAPITAL GOODS -- 9.0% Aerospace & Defense -- 2.2% 27,900 Raytheon Co. $ 2,103,939 11,127 United Technologies Corp. 1,113,813 ------------- $ 3,217,752 ------------------------------------------------------------------------------------ Electrical Components & Equipment -- 1.4% 14,600 Eaton Corp. Plc $ 924,472 10,400 Rockwell Automation, Inc. 1,011,192 ------------- $ 1,935,664 ------------------------------------------------------------------------------------ Heavy Electrical Equipment -- 0.8% 54,300 ABB, Ltd. $ 1,161,092 ------------------------------------------------------------------------------------ Industrial Conglomerates -- 2.2% 27,300 3M Co. $ 3,100,734 ------------------------------------------------------------------------------------ Construction & Farm Machinery & Heavy Trucks -- 0.8% 5,386,000 Nam Cheong, Ltd. $ 1,115,581 ------------------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. 16 Pioneer Global Equity Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ Industrial Machinery -- 1.6% 39,700 Ingersoll-Rand Plc $ 2,347,858 ------------- Total Capital Goods $ 12,878,681 ------------------------------------------------------------------------------------ COMMERCIAL SERVICES & SUPPLIES -- 0.5% Human Resource & Employment Services -- 0.5% 8,600 Towers Watson & Co. $ 707,350 ------------- Total Commercial Services & Supplies $ 707,350 ------------------------------------------------------------------------------------ AUTOMOBILES & COMPONENTS -- 3.9% Tires & Rubber -- 1.3% 43,800 Bridgestone Corp. $ 1,428,238 34,100 Pirelli & C. S.p.A. 402,231 ------------- $ 1,830,469 ------------------------------------------------------------------------------------ Automobile Manufacturers -- 2.6% 11,300 Daimler AG $ 774,804 11,300 Honda Motor Co., Ltd. 404,627 380,000 Mazda Motor Corp. 1,510,498 5,100 Volkswagen AG 1,133,072 ------------- $ 3,823,001 ------------- Total Automobiles & Components $ 5,653,470 ------------------------------------------------------------------------------------ CONSUMER DURABLES & APPAREL -- 1.7% Homebuilding -- 0.5% 51,200 West Holdings Corp. $ 703,619 ------------------------------------------------------------------------------------ Apparel, Accessories & Luxury Goods -- 1.2% 4,500 Christian Dior SA $ 769,870 9,600 Cie Financiere Richemont SA 909,544 ------------- $ 1,679,414 ------------- Total Consumer Durables & Apparel $ 2,383,033 ------------------------------------------------------------------------------------ CONSUMER SERVICES -- 1.2% Casinos & Gaming -- 0.5% 25,900 Grand Korea Leisure Co., Ltd. $ 746,631 ------------------------------------------------------------------------------------ Restaurants -- 0.7% 117,300 Domino's Pizza Group Plc $ 1,028,841 ------------- Total Consumer Services $ 1,775,472 ------------------------------------------------------------------------------------ MEDIA -- 0.8% Movies & Entertainment -- 0.8% 14,200 Viacom, Inc. (Class B) $ 1,129,752 ------------- Total Media $ 1,129,752 ------------------------------------------------------------------------------------ RETAILING -- 1.7% Department Stores -- 1.2% 38,900 Macy's, Inc. $ 1,728,327 ------------------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 17 Schedule of Investments | 8/31/13 (continued) ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ Apparel Retail -- 0.5% 10,600 Ross Stores, Inc. $ 712,956 ------------- Total Retailing $ 2,441,283 ------------------------------------------------------------------------------------ FOOD & STAPLES RETAILING -- 3.1% Drug Retail -- 2.1% 27,900 CVS Caremark Corp. $ 1,619,595 31,100 Walgreen Co. 1,494,977 ------------- $ 3,114,572 ------------------------------------------------------------------------------------ Food Distributors -- 0.6% 287,800 Metcash, Ltd. $ 830,632 ------------------------------------------------------------------------------------ Food Retail -- 0.4% 2,500 Magnit OJSC $ 556,788 ------------- Total Food & Staples Retailing $ 4,501,992 ------------------------------------------------------------------------------------ FOOD, BEVERAGE & TOBACCO -- 8.6% Brewers -- 0.8% 23,300 Molson Coors Brewing Co. $ 1,136,807 ------------------------------------------------------------------------------------ Soft Drinks -- 2.6% 24,300 Coca-Cola Enterprises, Inc. $ 908,820 34,600 PepsiCo, Inc. 2,758,658 ------------- $ 3,667,478 ------------------------------------------------------------------------------------ Packaged Foods & Meats -- 2.9% 38,400 Green Mountain Coffee Roasters, Inc.* $ 3,314,304 13,100 Nestle SA 858,267 ------------- $ 4,172,571 ------------------------------------------------------------------------------------ Tobacco -- 2.3% 60,100 Imperial Tobacco Group Plc $ 1,985,616 39,600 Japan Tobacco, Inc. 1,334,922 ------------- $ 3,320,538 ------------- Total Food, Beverage & Tobacco $ 12,297,394 ------------------------------------------------------------------------------------ HEALTH CARE EQUIPMENT & SERVICES -- 1.9% Health Care Equipment -- 1.9% 28,300 Covidien Plc $ 1,681,020 21,600 Medtronic, Inc. 1,117,800 ------------- $ 2,798,820 ------------- Total Health Care Equipment & Services $ 2,798,820 ------------------------------------------------------------------------------------ PHARMACEUTICALS, BIOTECHNOLOGY & LIFE SCIENCES -- 13.5% Biotechnology -- 1.8% 15,100 Celgene Corp.* $ 2,113,698 23,900 Prosensa Holding NV* 544,203 ------------- $ 2,657,901 ------------------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. 18 Pioneer Global Equity Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ Pharmaceuticals -- 10.9% 28,100 AstraZeneca Plc $ 1,382,112 9,600 Bayer AG 1,065,439 54,600 Novartis AG 3,980,669 96,300 Pfizer, Inc. 2,716,623 5,200 Roche Holding AG 1,296,857 14,700 Salix Pharmaceuticals, Ltd.* 984,018 15,357 Sanofi 1,474,521 20,000 Shire Plc 735,157 39,600 Teva Pharmaceutical Industries, Ltd. (A.D.R.) 1,513,512 4,700 Valeant Pharmaceuticals International, Inc.* 462,198 ------------- $ 15,611,106 ------------------------------------------------------------------------------------ Life Sciences Tools & Services -- 0.8% 12,700 Thermo Fisher Scientific, Inc. $ 1,128,141 ------------- Total Pharmaceuticals, Biotechnology & Life Sciences $ 19,397,148 ------------------------------------------------------------------------------------ BANKS -- 8.8% Diversified Banks -- 8.8% 233,700 Banco Bilbao Vizcaya Argentaria SA $ 2,226,511 7,741,300 Bank Pembangunan Daerah Jawa Barat Dan Banten Tbk PT 552,641 28,700 Doha Bank QSC 423,259 294,500 HSBC Holdings Plc 3,084,389 189,776 National Development Bank Plc 210,864 45,600 Nordea Bank AB 530,211 18,200 Royal Bank of Canada 1,121,515 32,400 Standard Chartered Plc 723,045 63,800 Sumitomo Mitsui Financial Group, Inc. 2,823,886 11,450 The Toronto-Dominion Bank 974,315 ------------- $ 12,670,636 ------------- Total Banks $ 12,670,636 ------------------------------------------------------------------------------------ DIVERSIFIED FINANCIALS -- 9.5% Other Diversified Financial Services -- 1.5% 33,800 Citigroup, Inc. $ 1,633,554 17,300 Intercorp Financial Services, Inc. 538,136 ------------- $ 2,171,690 ------------------------------------------------------------------------------------ Specialized Finance -- 1.1% 23,100 Deutsche Boerse AG $ 1,618,759 ------------------------------------------------------------------------------------ Consumer Finance -- 1.8% 12,800 American Express Co. $ 920,448 35,600 Discover Financial Services, Inc. 1,682,100 ------------- $ 2,602,548 ------------------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 19 Schedule of Investments | 8/31/13 (continued) ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ Investment Banking & Brokerage -- 5.1% 242,000 Daiwa Securities Group, Inc. $ 1,939,513 111,000 Morgan Stanley Co. 2,859,360 16,100 The Goldman Sachs Group, Inc. 2,449,293 ------------- $ 7,248,166 ------------- Total Diversified Financials $ 13,641,163 ------------------------------------------------------------------------------------ INSURANCE -- 0.9% Multi-line Insurance -- 0.9% 9,454 Allianz SE* $ 1,353,523 ------------- Total Insurance $ 1,353,523 ------------------------------------------------------------------------------------ REAL ESTATE -- 0.4% Industrial REIT -- 0.4% 600,000 Sabana Shari'ah Compliant Industrial Real Estate Investment Trust $ 520,920 ------------- Total Real Estate $ 520,920 ------------------------------------------------------------------------------------ SOFTWARE & SERVICES -- 7.5% Internet Software & Services -- 2.3% 117,900 Yahoo!, Inc.* $ 3,197,448 ------------------------------------------------------------------------------------ IT Consulting & Other Services -- 0.8% 78,600 SAIC, Inc. $ 1,184,502 ------------------------------------------------------------------------------------ Systems Software -- 4.4% 135,119 Microsoft Corp. $ 4,512,977 57,200 Oracle Corp. 1,822,392 ------------- $ 6,335,369 ------------- Total Software & Services $ 10,717,319 ------------------------------------------------------------------------------------ TECHNOLOGY HARDWARE & EQUIPMENT -- 6.0% Communications Equipment -- 1.4% 68,400 Cisco Systems, Inc. $ 1,594,404 6,900 Qualcomm, Inc. 457,332 ------------- $ 2,051,736 ------------------------------------------------------------------------------------ Computer Hardware -- 1.6% 4,785 Apple, Inc. $ 2,330,534 ------------------------------------------------------------------------------------ Computer Storage & Peripherals -- 1.3% 72,600 EMC Corp. $ 1,871,628 ------------------------------------------------------------------------------------ Electronic Components -- 0.8% 53,000 Hoya Corp. $ 1,125,674 ------------------------------------------------------------------------------------ Office Electronics -- 0.9% 121,600 Xerox Corp. $ 1,213,568 ------------- Total Technology Hardware & Equipment $ 8,593,140 ------------------------------------------------------------------------------------ The accompanying notes are an integral part of these financial statements. 20 Pioneer Global Equity Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------ Shares Value ------------------------------------------------------------------------------------ SEMICONDUCTORS & SEMICONDUCTOR EQUIPMENT -- 1.7% Semiconductor Equipment -- 0.4% 35,600 Teradyne, Inc.* $ 546,460 ------------------------------------------------------------------------------------ Semiconductors -- 1.3% 41,300 Maxim Integrated Products, Inc. $ 1,149,998 18,700 Xilinx, Inc. 811,954 ------------- $ 1,961,952 ------------- Total Semiconductors & Semiconductor Equipment $ 2,508,412 ------------------------------------------------------------------------------------ TELECOMMUNICATION SERVICES -- 6.7% Integrated Telecommunication Services -- 2.5% 57,100 Nippon Telegraph & Telephone Corp. $ 2,906,614 350,000 Telecom Corp. of New Zealand, Ltd. 613,370 ------------- $ 3,519,984 ------------------------------------------------------------------------------------ Wireless Telecommunication Services -- 4.2% 979,700 Vodafone Group Plc $ 3,157,452 90,000 Vodafone Group Plc (A.D.R.) 2,911,500 ------------- $ 6,068,952 ------------- Total Telecommunication Services $ 9,588,936 ------------------------------------------------------------------------------------ TOTAL COMMON STOCKS (Cost $128,985,868) $ 141,783,952 ------------------------------------------------------------------------------------ PURCHASED OPTIONS -- 0.0 % 900 Vodafone Group Plc $ 15,750 ------------------------------------------------------------------------------------ TOTAL PURCHASED OPTIONS (Cost $53,505) $ 15,750 ------------------------------------------------------------------------------------ TOTAL INVESTMENT IN SECURITIES -- 98.7% (Cost $129,039,373) (a) $ 141,799,702 ------------------------------------------------------------------------------------ OTHER ASSETS & LIABILITIES -- 1.3% $ 1,806,192 ------------------------------------------------------------------------------------ TOTAL NET ASSETS -- 100.0% $ 143,605,894 ==================================================================================== * Non-income producing security. + Amount rounds to less than 0.1%. (A.D.R.) American Depositary Receipts. REIT Real Estate Investment Trust. (a) At August 31, 2013, the net unrealized appreciation on investments based on cost for federal income tax purposes of $129,096,390 was as follows: Aggregate gross unrealized appreciation for all investments in which there is an excess of value over tax cost $ 15,325,784 Aggregate gross unrealized depreciation for all investments in which there is an excess of tax cost over value (2,622,472) ------------ Net unrealized appreciation $ 12,703,312 ============ The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 21 Schedule of Investments | 8/31/13 (continued) (b) Distribution of investments by country of issue, as a percentage of total investment in securities (excluding temporary cash investments), is as follows: United States 51.7% United Kingdom 10.0% Japan 9.9% Switzerland 5.7% Germany 4.1% Ireland 4.0% France 2.4% Netherlands 1.7% Spain 1.5% Canada 1.4% Other (individually less than 1%) 7.6% ------ 100.0% ====== Purchases and sales of securities (excluding temporary cash investments) for the year ended August 31, 2013 aggregated $216,333,673 and $219,634,682, respectively. Various inputs are used in determining the value of the Fund's investments. These inputs are summarized in the three broad levels listed below. Level 1 - quoted prices in active markets for identical securities. Level 2 - other significant observable inputs (including quoted prices for similar securities, interest rates, prepayment speeds, credit risk, etc.) See Notes to Financial Statements -- Note 1A. Level 3 - significant unobservable inputs (including the Fund's own assumptions in determining fair value of investments) See Notes to Financial Statements -- Note 1A. Generally, equity securities are categorized as Level 1, fixed income securities and senior loans as Level 2 and securities valued using fair value methods (other than prices supplied by independent pricing services) as Level 3. See Notes to Financial Statements -- Note 1A. The following is a summary of the inputs used as of August 31, 2013, in valuing the Fund's investments: --------------------------------------------------------------------------------------- Level 1 Level 2 Level 3 Total --------------------------------------------------------------------------------------- Common Stocks (U.S.) $87,223,701 $ -- $ -- $ 87,223,701 Common Stocks (Foreign) -- 54,560,251 -- 54,560,251 Purchased Options 15,750 -- -- 15,750 --------------------------------------------------------------------------------------- Total $87,239,451 $ 54,560,251 $ -- $141,799,702 ======================================================================================= Other Financial Instruments: Net Unrealized Appreciation On Forward Foreign Currency Settlement Contracts $ -- $ 8,690 $ -- $ 8,690 Net Unrealized Appreciation On Forward Foreign Currency Portfolio Hedge Contracts -- 124,075 -- 124,075 Futures Contracts 2,333 -- -- 2,333 --------------------------------------------------------------------------------------- Total $ 2,333 $ 132,765 $ -- $ 135,098 ======================================================================================= During the year ended August 31, 2013, there were no transfers between Levels 1, 2 and 3. The accompanying notes are an integral part of these financial statements. 22 Pioneer Global Equity Fund | Annual Report | 8/31/13 Statement of Assets and Liabilities | 8/31/13 ASSETS: Investment in securities (cost $129,039,373) $141,799,702 Cash 6,955,934 Foreign currencies, at value (cost $827,396) 823,294 Futures collateral 122,500 Receivables -- Investment securities sold 1,931,141 Fund shares sold 40,248 Dividends and foreign taxes withheld 446,169 Due from Pioneer Investment Management, Inc. 119,244 Net unrealized appreciation on forward foreign currency settlement contracts 8,690 Net unrealized appreciation on forward foreign currency portfolio hedge contracts 124,075 Other 19,783 ------------------------------------------------------------------------------------------------- Total assets $152,390,780 ------------------------------------------------------------------------------------------------- LIABILITIES: Payables -- Investment securities purchased $ 8,236,976 Fund shares repurchased 102,187 Variation margin 144,986 Due to affiliates 126,750 Accrued expenses 173,987 ------------------------------------------------------------------------------------------------- Total liabilities $ 8,784,886 ------------------------------------------------------------------------------------------------- NET ASSETS: Paid-in capital $175,197,812 Undistributed net investment income 2,279,756 Accumulated net realized loss on investments and foreign currency transactions (46,759,782) Net unrealized appreciation on investments 12,760,329 Net unrealized appreciation on forward foreign currency contracts and other assets and liabilities denominated in foreign currencies 125,446 Net unrealized appreciation on futures contracts 2,333 ------------------------------------------------------------------------------------------------- Total net assets $143,605,894 ================================================================================================= NET ASSET VALUE PER SHARE: (No par value, unlimited number of shares authorized) Class A (based on $62,996,066/5,569,812 shares) $ 11.31 Class B (based on $2,367,629/212,590 shares) $ 11.14 Class C (based on $6,516,199/586,383 shares) $ 11.11 Class Y (based on $71,726,000/6,309,707 shares) $ 11.37 MAXIMUM OFFERING PRICE: Class A ($11.31 (divided by) 94.25% ) $ 12.00 ================================================================================================= The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 23 Statement of Operations For the Year Ended 8/31/13 INVESTMENT INCOME: Dividends (net of foreign taxes withheld of $187,433) $ 3,644,211 Interest 34,758 ---------------------------------------------------------------------------------------- Total investment income $ 3,678,969 ---------------------------------------------------------------------------------------- EXPENSES: Management fees $ 1,041,356 Transfer agent fees Class A 188,269 Class B 26,795 Class C 19,571 Class Y 526 Distribution fees Class A 153,958 Class B 26,818 Class C 62,620 Shareholder communications expense 93,555 Administrative reimbursements 59,223 Custodian fees 80,288 Registration fees 113,214 Professional fees 44,660 Printing expense 36,695 Fees and expenses of nonaffiliated Trustees 6,548 Miscellaneous 2,142 ---------------------------------------------------------------------------------------- Total expenses $ 1,956,238 Less fees waived and expenses reimbursed by Pioneer Investment Management, Inc. (412,330) ---------------------------------------------------------------------------------------- Net expenses $ 1,543,908 ---------------------------------------------------------------------------------------- Net investment income $ 2,135,061 ---------------------------------------------------------------------------------------- REALIZED AND UNREALIZED GAIN (LOSS) ON INVESTMENTS, FUTURES CONTRACTS AND FOREIGN CURRENCY TRANSACTIONS: Net realized gain (loss) on: Investments $17,531,695 Futures contracts (206,471) Forward foreign currency contracts and other assets and liabilities denominated in foreign currencies 673,864 $17,999,088 ---------------------------------------------------------------------------------------- Change in net unrealized appreciation (depreciation) on: Investments $ 3,849,804 Futures contracts 56,833 Forward foreign currency contracts and other assets and liabilities denominated in foreign currencies 25,932 $ 3,932,569 ---------------------------------------------------------------------------------------- Net gain on investments, futures contracts and foreign currency transactions $21,931,657 ---------------------------------------------------------------------------------------- Net increase in net assets resulting from operations $24,066,718 ======================================================================================== The accompanying notes are an integral part of these financial statements. 24 Pioneer Global Equity Fund | Annual Report | 8/31/13 Statements of Changes in Net Assets -------------------------------------------------------------------------------------------- Year Ended Year Ended 8/31/13 8/31/12 -------------------------------------------------------------------------------------------- FROM OPERATIONS: Net investment income $ 2,135,061 $ 2,353,814 Net realized gain (loss) on investments, futures contracts and foreign currency transactions 17,999,088 (10,192,850) Change in net unrealized appreciation on investments, futures contracts and foreign currency transactions 3,932,569 13,732,398 -------------------------------------------------------------------------------------------- Net increase in net assets resulting from operations $ 24,066,718 $ 5,893,362 -------------------------------------------------------------------------------------------- DISTRIBUTIONS TO SHAREOWNERS: Net investment income: Class A ($0.16 and $0.13 per share, respectively) $ (917,101) $ (808,115) Class B ($0.05 and $0.02 per share, respectively) (14,373) (6,659) Class C ($0.07 and $0.03 per share, respectively) (39,684) (20,815) Class Y ($0.21 and $0.18 per share, respectively) (1,319,980) (1,109,955) -------------------------------------------------------------------------------------------- Total distributions to shareowners $ (2,291,138) $ (1,945,544) -------------------------------------------------------------------------------------------- FROM FUND SHARE TRANSACTIONS: Net proceeds from sale or exchange of shares $ 10,898,587 $ 8,241,391 Reinvestment of distributions 948,339 823,564 Cost of shares repurchased (15,721,764) (18,550,214) -------------------------------------------------------------------------------------------- Net decrease in net assets resulting from Fund share transactions $ (3,874,838) $ (9,485,259) -------------------------------------------------------------------------------------------- Net increase (decrease) in net assets $ 17,900,742 $ (5,537,441) NET ASSETS: Beginning of year 125,705,152 131,242,593 -------------------------------------------------------------------------------------------- End of year $143,605,894 $125,705,152 ============================================================================================ Undistributed net investment income $ 2,279,756 $ 1,532,192 ============================================================================================ The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 25 Statements of Changes in Net Assets (continued) --------------------------------------------------------------------------------------- '13 Shares '13 Amount '12 Shares '12 Amount --------------------------------------------------------------------------------------- Class A Shares sold 622,079 $ 6,711,950 353,272 $ 3,701,073 Reinvestment of distributions 87,882 888,496 88,144 774,789 Less shares repurchased (1,049,318) (11,277,005) (1,083,925) (10,114,432) --------------------------------------------------------------------------------------- Net decrease (339,357) $ (3,676,559) (642,509) $ (5,638,570) ======================================================================================= Class B Shares sold or exchanged 16,613 $ 170,182 18,790 $ 195,120 Reinvestment of distributions 1,414 14,158 749 6,512 Less shares repurchased (104,877) (1,102,463) (179,983) (1,638,775) --------------------------------------------------------------------------------------- Net decrease (86,850) $ (918,123) (160,444) $ (1,437,143) ======================================================================================= Class C Shares sold 96,013 $ 1,020,165 109,039 $ 1,039,083 Reinvestment of distributions 3,739 37,351 2,206 19,171 Less shares repurchased (113,209) (1,192,619) (219,894) (1,992,027) --------------------------------------------------------------------------------------- Net decrease (13,457) $ (135,103) (108,649) $ (933,773) ======================================================================================= Class Y Shares sold 289,411 $ 2,996,290 305,575 $ 3,306,115 Reinvestment of distributions 823 8,334 2,624 23,092 Less shares repurchased (196,154) (2,149,677) (524,778) (4,804,980) --------------------------------------------------------------------------------------- Net increase (decrease) 94,080 $ 854,947 (216,579) $ (1,475,773) ======================================================================================= The accompanying notes are an integral part of these financial statements. 26 Pioneer Global Equity Fund | Annual Report | 8/31/13 Financial Highlights ---------------------------------------------------------------------------------------------------------------------------- Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 ---------------------------------------------------------------------------------------------------------------------------- Class A Net asset value, beginning of period $ 9.64 $ 9.27 $ 8.44 $ 8.56 $ 10.42 ---------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.15 $ 0.17 $ 0.13 $ 0.08 $ 0.07 Net realized and unrealized gain (loss) on investments and foreign currency transactions 1.68 0.33 0.76 (0.17) (1.76) ---------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.83 $ 0.50 $ 0.89 $ (0.09) $ (1.69) ---------------------------------------------------------------------------------------------------------------------------- Distribution to shareowners: Net investment income (0.16) (0.13) (0.06) (0.03) (0.17) Net realized gain -- -- -- -- -- ---------------------------------------------------------------------------------------------------------------------------- Total distributions $ (0.16) $ (0.13) $ (0.06) $ (0.03) $ (0.17) ---------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 1.67 $ 0.37 $ 0.83 $ (0.12) $ (1.86) ---------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 11.31 $ 9.64 $ 9.27 $ 8.44 $ 8.56 ============================================================================================================================ Total return* 19.17% 5.50% 10.48% (1.13)% (15.83)% Ratio of net expenses to average net assets+ 1.30% 1.30% 1.30% 1.30% 1.30% Ratio of net investment income to average net assets+ 1.35% 1.71% 1.23% 0.82% 0.69% Portfolio turnover rate 160% 152% 194% 114% 120% Net assets, end of period (in thousands) $62,996 $56,970 $60,701 $61,466 $70,718 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 1.67% 1.72% 1.67% 1.71% 2.25% Net investment income (loss) 0.98% 1.29% 0.86% 0.41% (0.26)% ============================================================================================================================ * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 27 Financial Highlights (continued) ------------------------------------------------------------------------------------------------------------------------ Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 ------------------------------------------------------------------------------------------------------------------------ Class B Net asset value, beginning of period $ 9.48 $ 9.08 $ 8.30 $ 8.47 $ 10.28 ------------------------------------------------------------------------------------------------------------------------ Increase (decrease) from investment operations: Net investment income (loss) $ 0.09 $ 0.16 $ 0.07 $ 0.00(a) $ (0.02) Net realized and unrealized gain (loss) on investments and foreign currency transactions 1.62 0.26 0.71 (0.17) (1.70) ------------------------------------------------------------------------------------------------------------------------ Net increase (decrease) from investment operations $ 1.71 $ 0.42 $ 0.78 $ (0.17) $ (1.72) ------------------------------------------------------------------------------------------------------------------------ Distribution to shareowners: Net investment income (0.05) (0.02) -- -- (0.09) Net realized gain -- -- -- -- -- ------------------------------------------------------------------------------------------------------------------------ Total distributions $ (0.05) $ (0.02) $ -- $ -- $ (0.09) ------------------------------------------------------------------------------------------------------------------------ Net increase (decrease) in net asset value $ 1.66 $ 0.40 $ 0.78 $ (0.17) $ (1.81) ------------------------------------------------------------------------------------------------------------------------ Net asset value, end of period $ 11.14 $ 9.48 $ 9.08 $ 8.30 $ 8.47 ======================================================================================================================== Total return* 18.13% 4.60% 9.40% (2.01)% (16.57)% Ratio of net expenses to average net assets+ 2.20% 2.20% 2.20% 2.20% 2.20% Ratio of net investment income (loss) to average net assets+ 0.43% 0.79% 0.29% (0.11)% (0.01)% Portfolio turnover rate 160% 152% 194% 114% 120% Net assets, end of period (in thousands) $ 2,368 $ 2,838 $ 4,175 $ 5,587 $ 7,994 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 3.22% 3.14% 2.97% 2.93% 4.14% Net investment loss (0.59)% (0.15)% (0.49)% (0.84)% (1.95)% ======================================================================================================================== (a) Amount rounds to less than $0.01 per share. * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 28 Pioneer Global Equity Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------------------------------------------- Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 ------------------------------------------------------------------------------------------------------------------------- Class C Net asset value, beginning of period $ 9.47 $ 9.09 $ 8.31 $ 8.48 $ 10.26 ------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income (loss) $ 0.05 $ 0.10 $ 0.04 $ 0.00(b) $ (0.04) Net realized and unrealized gain (loss) on investments and foreign currency transactions 1.66 0.31 0.74 (0.17) (1.68) ------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.71 $ 0.41 $ 0.78 $ (0.17) $ (1.72) ------------------------------------------------------------------------------------------------------------------------- Distribution to shareowners: Net investment income (0.07) (0.03) -- -- (0.06) Net realized gain -- -- -- -- -- ------------------------------------------------------------------------------------------------------------------------- Total distributions $ (0.07) $ (0.03) $ -- $ -- $ (0.06) ------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 1.64 $ 0.38 $ 0.78 $ (0.17) $ (1.78) ------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 11.11 $ 9.47 $ 9.09 $ 8.31 $ 8.48 ========================================================================================================================= Total return* 18.11% 4.56% 9.39% (2.00)% (16.58)% Ratio of net expenses to average net assets+ 2.20% 2.20% 2.20% 2.20% 2.20% Ratio of net investment income (loss) to average net assets+ 0.45% 0.82% 0.35% (0.07)% 0.00%(a) Portfolio turnover rate 160% 152% 194% 114% 120% Net assets, end of period (in thousands) $ 6,516 $ 5,682 $ 6,439 $ 6,118 $ 6,910 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 2.51% 2.53% 2.48% 2.54% 3.76% Net investment income (loss) 0.14% 0.49% 0.07% (0.41)% (1.56)% ========================================================================================================================= (a) Amount rounds to less than 0.01%. (b) Amount rounds to less than $0.01 per share. * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer Global Equity Fund | Annual Report | 8/31/13 29 Financial Highlights (continued) -------------------------------------------------------------------------------------------------------------------------- Year Year Year Year 12/31/08 (a) Ended Ended Ended Ended to 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 -------------------------------------------------------------------------------------------------------------------------- Class Y Net asset value, beginning of period $ 9.69 $ 9.32 $ 8.49 $ 8.59 $ 7.25 -------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.20 $ 0.21 $ 0.18 $ 0.12 $ 0.06 Net realized and unrealized gain (loss) on investments and foreign currency transactions 1.69 0.34 0.76 (0.17) 1.28 -------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) from investment operations $ 1.89 $ 0.55 $ 0.94 $ (0.05) $ 1.34 -------------------------------------------------------------------------------------------------------------------------- Distribution to shareowners: Net investment income (0.21) (0.18) (0.11) (0.05) -- -------------------------------------------------------------------------------------------------------------------------- Total distributions $ (0.21) $ (0.18) $ (0.11) $ (0.05) $ -- -------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ 1.68 $ 0.37 $ 0.83 $ (0.10) $ 1.34 -------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 11.37 $ 9.69 $ 9.32 $ 8.49 $ 8.59 ========================================================================================================================== Total return* 19.75% 6.09% 10.96% (0.59)% 18.48%(b) Ratio of net expenses to average net assets+ 0.80% 0.80% 0.80% 0.80% 0.80%** Ratio of net investment income to average net assets+ 1.85% 2.22% 1.74% 1.33% 2.57%** Portfolio turnover rate 160% 152% 194% 114% 120% Net assets, end of period (in thousands) $71,726 $60,214 $59,927 $58,692 $ 60,071 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 1.00% 0.97% 0.95% 0.96% 1.10%** Net investment income 1.65% 2.05% 1.59% 1.17% 2.27%** ========================================================================================================================== (a) Class Y shares were first publicly offered on December 31, 2008. (b) Not annualized. * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions and the complete redemption of the investment at net asset value at the end of each period. ** Annualized. + Ratios with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 30 Pioneer Global Equity Fund | Annual Report | 8/31/13 Notes to Financial Statements | 8/31/13 1. Organization and Significant Accounting Policies Pioneer Global Equity Fund, formerly Pioneer Global Select Equity Fund (the Fund), is one of two portfolios comprising Pioneer Series Trust V, a Delaware statutory trust. The Fund is registered under the Investment Company Act of 1940 as a diversified, open-end management investment company. The Fund commenced operations on December 15, 2005. The Fund's investment objective is to seek long-term capital growth. The Fund offers four classes of shares designated as Class A, Class B, Class C and Class Y shares. Class Y shares were first publicly offered on December 31, 2008. Effective as of the close of business on December 31, 2009, Class B shares are no longer offered to new or existing shareholders, except that dividends and/or capital gain distributions may continue to be reinvested in Class B shares, and shareholders may exchange their Class B shares for Class B shares of other Pioneer funds, as permitted by existing exchange privileges. Each class of shares represents an interest in the same portfolio of investments of the Fund and has identical rights (based on relative net asset values) to assets and liquidation proceeds. Share classes can bear different rates of class-specific fees and expenses such as transfer agent and distribution fees. Differences in class-specific fees and expenses will result in differences in net investment income and, therefore, the payment of different dividends from net investment income earned by each class. The Amended and Restated Declaration of Trust of the Fund gives the Board the flexibility to specify either per-share voting or dollar-weighted voting when submitting matters for shareholder approval. Under per-share voting, each share of a class of the Fund is entitled to one vote. Under dollar-weighted voting, a shareholder's voting power is determined not by the number of shares owned, but by the dollar value of the shares on the record date. Each share class has exclusive voting rights with respect to matters affecting only that class, including with respect to the distribution plan for that class. There is no distribution plan for Class Y shares. Class B shares convert to Class A shares approximately eight years after the date of purchase. The Fund's financial statements have been prepared in conformity with U.S. generally accepted accounting principles that require the management of the Fund to, among other things, make estimates and assumptions that affect the reported amounts of assets and liabilities, the disclosure of contingent assets and liabilities at the date of the financial statements, and the reported amounts of income, expenses and gain or loss on investments during the reporting period. Actual results could differ from those estimates. Pioneer Global Equity Fund | Annual Report | 8/31/13 31 The following is a summary of significant accounting policies followed by the Fund in the preparation of its financial statements, which are consistent with those policies generally accepted in the investment company industry: A. Security Valuation Security transactions are recorded as of trade date. The net asset value of the Fund is computed once daily, on each day the New York Stock Exchange (NYSE) is open, as of the close of regular trading on the NYSE. In computing the net asset value, securities that have traded on an exchange are valued using the last sale price on the principal exchange where they are traded. Securities that have not traded on the date of valuation, or securities for which sale prices are not available, generally are valued using the mean between the last bid and asked prices. Short-term fixed income securities with remaining maturities of sixty days or less generally are valued at amortized cost. Shares of money market mutual funds are valued at such funds' net asset value. The Fund invests primarily in securities of non-U.S. issuers. The principal exchanges and markets for such securities have closing times prior to the close of the NYSE. However, the value of these securities may be influenced by changes in global markets occurring after the closing times of the local exchanges and markets up to the time the Fund determines its net asset value. Consequently, the Board of Trustees of the Fund has determined that daily adjustments to the valuation of securities of non-U.S. issuers by utilizing an independent pricing service that supplies an appropriate fair value factor is appropriate for the Fund. Securities for which independent pricing services are unable to supply prices or for which market prices and/or quotations are not readily available or are considered to be unreliable are valued at the direction or with the approval of the Valuation Committee using fair value methods pursuant to procedures adopted by the Board of Trustees. The Valuation Committee is comprised of certain members of the Board of Trustees. Inputs used when applying fair value methods to value a security may include credit ratings, the financial condition of the company, current market conditions and comparable securities. The Fund may use fair value methods if it is determined that a significant event has occurred after the close of the exchange or market on which the security trades and prior to the determination of the Fund's net asset value. Examples of a significant event might include political or economic news, corporate restructurings, natural disasters, terrorist activity or trading halts. Thus, the valuation of the Fund's securities may differ significantly from exchange prices and such differences could be material. Pioneer Investment Management, Inc. (PIM), the Fund's investment advisor, 32 Pioneer Global Equity Fund | Annual Report | 8/31/13 is responsible for monitoring developments that may impact fair valued securities and for discussing and assessing fair values on an ongoing basis, and at least quarterly, with the Valuation Committee. At August 31, 2013, no securities were valued using fair value methods (other than securities valued using prices supplied by independent pricing services). Dividend income is recorded on the ex-dividend date, except that certain dividends from foreign securities where the ex-dividend date may have passed are recorded as soon as the Fund becomes aware of the ex-dividend data in the exercise of reasonable diligence. Interest income, including interest on income bearing cash accounts, is recorded on the accrual basis. Dividend and interest income are reported net of unrecoverable foreign taxes withheld at the applicable country rates. Gains and losses on sales of investments are calculated on the identified cost method for both financial reporting and federal income tax purposes. B. Federal Income Taxes It is the Fund's policy to comply with the requirements of the Internal Revenue Code applicable to regulated investment companies and to distribute all of its taxable income and net realized capital gains, if any, to its shareowners. Therefore, no provision for federal income taxes is required. As of August 31, 2013, the Fund had not accrued any interest and penalties with respect to uncertain tax positions, which, if applicable, would be recorded as an income tax expense in the Statement of Operations. Tax returns filed within the prior three years are subject to examination by Federal and State tax authorities. The amount and character of income and capital gain distributions to shareowners are determined in accordance with federal income tax rules, which may differ from U.S. generally accepted accounting principles. Distributions in excess of net investment income or net realized gains are temporary overdistributions for financial statement purposes resulting from differences in the recognition or classification of income or distributions for financial statement and tax purposes. Capital accounts within the financial statements are adjusted for permanent book/tax differences to reflect tax character, but are not adjusted for temporary differences. At August 31, 2013, the Fund reclassified $903,641 to increase undistributed net investment income and $903,641 to increase accumulated net realized loss on investments to reflect permanent book/tax differences. These adjustments have no impact on net assets or the results of operations. At August 31, 2013, the Fund had a net capital loss carryforward of $46,692,095 which will expire in 2016 if not utilized. Pioneer Global Equity Fund | Annual Report | 8/31/13 33 The tax character of distributions paid during the years ended August 31, 2013 and August 31, 2012 was as follows: ---------------------------------------------------------------------------- 2013 2012 ---------------------------------------------------------------------------- Distributions paid from: Ordinary income $2,291,138 $1,945,544 ---------------------------------------------------------------------------- Total $2,291,138 $1,945,544 ============================================================================ The following shows the components of distributable earnings on a federal income tax basis at August 31, 2013: ---------------------------------------------------------------------------- 2013 ---------------------------------------------------------------------------- Distributable earnings: Undistributed ordinary income $ 2,395,494 Capital loss carryforward (46,692,095) Net unrealized appreciation 12,704,683 ---------------------------------------------------------------------------- Total $(31,591,918) ============================================================================ The difference between book-basis and tax-basis net unrealized appreciation is attributable to the tax deferral of losses on wash sales, the mark-to-market of foreign currency contracts and futures contracts and the tax basis adjustments on partnerships. C. Fund Shares The Fund records sales and repurchases of its shares as of trade date. Pioneer Funds Distributor, Inc. (PFD), the principal underwriter for the Fund and a wholly owned indirect subsidiary of UniCredit S.p.A. (UniCredit), earned $6,444 in underwriting commissions on the sale of Class A shares during the year ended August 31, 2013. D. Foreign Currency Translation The books and records of the Fund are maintained in U.S. dollars. Amounts denominated in foreign currencies are translated into U.S. dollars using current exchange rates. Net realized gains and losses on foreign currency transactions, if any, represent, among other things, the net realized gains and losses on foreign currency contracts, disposition of foreign currencies and the difference between the amount of income accrued and the U.S. dollars actually received. Further, the effects of changes in foreign currency exchange rates on investments are not segregated in the Statement of Operations from the effects of changes in the market prices of those securities but are included with the net realized and unrealized gain or loss on investments. 34 Pioneer Global Equity Fund | Annual Report | 8/31/13 E. Forward Foreign Currency Contracts The Fund may enter into forward foreign currency contracts (contracts) for the purchase or sale of a specific foreign currency at a fixed price on a future date. All contracts are marked to market daily at the applicable exchange rates, and any resulting unrealized appreciation or depreciation are recorded in the Fund's financial statements. The Fund records realized gains and losses at the time a portfolio hedge is offset by entry into a closing transaction or extinguished by delivery of the currency. Risks may arise upon entering into these contracts from the potential inability of counterparties to meet the terms of the contract and from unanticipated movements in the value of foreign currencies relative to the U.S. dollar (see Note 6). F. Class Allocations Income, common expenses and realized and unrealized gains and losses are calculated at the Fund level and allocated daily to each class of shares based on its respective percentage of adjusted net assets at the beginning of the day. Distribution fees are calculated based on the average daily net asset value attributable to Class A, Class B and Class C shares of the Fund, respectively (see Note 4). Class Y shares do not pay distribution fees. All expenses and fees paid to the transfer agent, Pioneer Investment Management Shareholder Services, Inc. (PIMSS), for its services are allocated among the classes of shares based on the number of accounts in each class and the ratable allocation of related out-of-pocket expenses (see Note 3). Distributions to shareowners are recorded as of the ex-dividend date. Distributions paid by the Fund with respect to each class of shares are calculated in the same manner and at the same time, except that net investment income dividends to Class A, Class B, Class C and Class Y shares can reflect different transfer agent and distribution expense rates. G. Risks Investing in foreign and/or emerging markets securities involves risks relating to interest rates, currency exchange rates and economic and political conditions. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making the Fund more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. The Fund's prospectus contains unaudited information regarding the Fund's principal risks. Please refer to that document when considering the Fund's principal risks. Pioneer Global Equity Fund | Annual Report | 8/31/13 35 H. Futures Contracts The Fund may enter into futures transactions in order to attempt to hedge against changes in interest rates, securities prices and currency rates or to seek to increase total return. Futures contracts are types of derivatives. All futures contracts entered into by the Fund are traded on a futures exchange. Upon entering into a futures contract, the Fund is required to deposit with a broker an amount of cash or securities equal to the minimum "initial margin" requirements of the associated futures exchange. The amount of cash deposited with the broker as collateral at August 31, 2013 was $122,500. Subsequent payments for futures contracts ("variation margin") are paid or received by the Fund, depending on the daily fluctuation in the value of the contracts, and are recorded by the Fund as unrealized appreciation or depreciation. When the contract is closed, the Fund realizes a gain or loss equal to the difference between the opening and closing value of the contract as well as any fluctuation in foreign currency exchange rates where applicable. The use of futures contracts involves, to varying degrees, elements of market, interest rate, currency exchange rate and counterparty risks, which may exceed the amounts recognized by the Fund. Changes in value of the contracts may not directly correlate to the changes in value of the underlying securities. These risks may decrease the effectiveness of the Fund's hedging strategies and potentially result in a loss. The average number of contracts open during the year ended August 31, 2013 was 8. At August 31, 2013, open futures contracts were as follows: ---------------------------------------------------------------------------- Number of Contracts Settlement Unrealized Type Long/(Short) Month Value Appreciation ---------------------------------------------------------------------------- S&P 500 Future (7) 9/13 $(2,854,775) $2,333 ---------------------------------------------------------------------------- Total $2,333 ============================================================================ 36 Pioneer Global Equity Fund | Annual Report | 8/31/13 I. Purchased Options The Fund may purchase call and put options in order to attempt to hedge against changes in the value of portfolio securities or to seek to increase total return. Purchased call and put options entitle the Fund to buy and sell a specified number of shares or units of a particular security, currency or index at a specified price at a specific date or within a specific period of time. Upon the purchase of a call or put option, the premium paid by the Fund is included in the Statement of Assets and Liabilities as an investment. All premiums are marked-to-market daily, and any unrealized appreciation or depreciation are recorded in the Fund's financial statements. As the purchaser of an index option, the Fund has the right to receive a cash payment equal to any depreciation in the value of the index below the strike price of the option (in the case of a put) or equal to any appreciation in the value of the index over the strike price of the option (in the case of a call) as of the valuation date of the option. Premiums paid for purchased calls and put options which have expired are treated as realized losses on investments in the Statement of Operations. Upon the exercise or closing of a purchased put option, the premium is offset against the proceeds on the sale of the underlying security or financial instrument in order to determine the realized gain or loss on investments. Upon the exercise or closing of a purchased call option, the premium is added to the cost of the security or financial instrument. The risk associated with purchasing options is limited to the premium originally paid. The average number of contracts open during the year ended August 31, 2013 was 86. Purchased option contracts outstanding at year end are listed at the end of the Fund's schedule of investments. 2. Management Agreement PIM, a wholly owned indirect subsidiary of UniCredit, manages the Fund's portfolio. Management fees are calculated daily at the annual rate equal to 0.75% of the Fund's average daily net assets up to $500 million, 0.70% of the next $500 million of the Fund's average daily net assets and 0.65% of the Fund's average daily net assets over $1 billion. For the year ended August 31, 2013, the effective management fee (excluding waivers and/or assumption of expenses) was equivalent to 0.75% of the Fund's average daily net assets. PIM has contractually agreed to limit ordinary operating expenses of the Fund to the extent required to reduce Fund expenses to 1.30%, 2.20%, 2.20%, and 0.80% of the average daily net assets attributable to Class A, Class B, Class C and Class Y shares, respectively. Fees waived and expenses reimbursed during the year ended August 31, 2013 are reflected on the Statement of Operations. These expense limitations are in effect through January 1, 2014. There can be no assurance that PIM will extend the expense limitation agreement for a class of shares beyond the date referred to above. Pioneer Global Equity Fund | Annual Report | 8/31/13 37 In addition, under the management and administration agreements, certain other services and costs, including accounting, regulatory reporting and insurance premiums, are paid by the Fund as administrative reimbursements. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $98,219 in management fees, administrative costs and certain other reimbursements payable to PIM at August 31, 2013. 3. Transfer Agent PIMSS, a wholly owned indirect subsidiary of UniCredit, provides substantially all transfer agent and shareowner services to the Fund at negotiated rates. In addition, the Fund reimburses PIMSS for out-of-pocket expenses incurred by PIMSS related to shareholder communications activities such as proxy and statement mailings, outgoing phone calls and omnibus relationship contracts. For the year ended August 31, 2013, such out-of-pocket expenses by class of shares were as follows: -------------------------------------------------------------------------------- Shareholder Communications: -------------------------------------------------------------------------------- Class A $73,140 Class B 6,189 Class C 12,317 Class Y 1,909 -------------------------------------------------------------------------------- Total: $93,555 -------------------------------------------------------------------------------- Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $26,494 in transfer agent fees and out-of-pocket reimbursements payable to PIMSS at August 31, 2013. 4. Distribution Plan The Fund has adopted a Distribution Plan pursuant to Rule 12b-1 of the Investment Company Act of 1940 with respect to its Class A, Class B and Class C shares. Pursuant to the Plan, the Fund pays PFD 0.25% of the average daily net assets attributable to Class A shares as compensation for personal services and/or account maintenance services or distribution services with regard to Class A shares. Pursuant to the Plan, the Fund also pays PFD 1.00% of the average daily net assets attributable to Class B and Class C shares. The fee for Class B and Class C shares consists of a 0.25% service fee and a 0.75% distribution fee paid as compensation for personal services and/or account maintenance services or distribution services with regard to Class B and Class C shares. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $2,037 in distribution fees payable to PFD at August 31, 2013. 38 Pioneer Global Equity Fund | Annual Report | 8/31/13 In addition, redemptions of each class of shares (except Class Y shares) may be subject to a contingent deferred sales charge (CDSC). A CDSC of 1.00% may be imposed on redemptions of certain net asset value purchases of Class A shares within 12 months of purchase. Class B shares that are redeemed within five years of purchase are subject to a CDSC at declining rates beginning at 4.00%, based on the lower of cost or market value of shares being redeemed. Redemptions of Class C shares within 12 months of purchase are subject to a CDSC of 1.00%, based on the lower of cost or market value of shares being redeemed. Shares purchased as part of an exchange remain subject to any CDSC that applied to the original purchase of those shares. There is no CDSC for Class Y shares. Proceeds from the CDSCs are paid to PFD. For the year ended August 31, 2013, CDSCs in the amount of $2,040 were paid to PFD. 5. Expense Offsets Arrangements The Fund has entered into certain expense offset arrangements with PIMSS, which may result in a reduction in the Fund's total expenses due to interest earned on cash held by PIMSS. For the year ended August 31, 2013, the Fund's expenses were not reduced under such arrangements. 6. Forward Foreign Currency Contracts At August 31, 2013, the Fund had entered into various forward foreign currency contracts that obligate the Fund to deliver or take delivery of currencies at specified future maturity dates. Alternatively, prior to the settlement date of a forward foreign currency contract, the Fund may close out such contract by entering into an offsetting contract. The Fund's gross forward currency settlement contracts receivable and payable were $1,339,163 and $1,330,473 respectively, resulting in a net receivable of $8,690. The average value of settlement contracts open during the year ended August 31, 2013 was $2,348,839. The average value of portfolio hedges open during the year ended August 31, 2013 was $14,626,608. Open portfolio hedges at August 31, 2013 were as follows: ---------------------------------------------------------------------------------------- Net In Net Contracts Exchange Settlement Unrealized Currency to Deliver For Date Value Appreciation ---------------------------------------------------------------------------------------- JPY (Japanese Yen) (300,000,000) (3,097,817) 9/30/13 $(3,056,118) $ 41,699 JPY (Japanese Yen) 300,000,000 2,973,742 9/30/13 3,056,118 82,376 ---------------------------------------------------------------------------------------- $124,075 ======================================================================================== Pioneer Global Equity Fund | Annual Report | 8/31/13 39 7. Additional Disclosures about Derivative Instruments and Hedging Activities Values of derivative instruments as of August 31, 2013 were as follows: ---------------------------------------------------------------------------------------------------- Derivatives Not Accounted for as Hedging Instruments Asset Derivatives 2013 Liabilities Derivatives 2013 Under Accounting ----------------------------- ----------------------------- Standards Codification Balance Sheet Balance Sheet (ASC) 815 Location Value Location Value ---------------------------------------------------------------------------------------------------- Forward Foreign Currency Net unrealized Net unrealized Settlement Contracts* appreciation on depreciation on forward foreign forward foreign currency currency settlement settlement contracts $ 8,690 contracts $-- Forward Foreign Currency Net unrealized Net unrealized Portfolio Hedge Contracts** appreciation on depreciation on forward foreign forward foreign currency portfolio currency portfolio hedge contracts $124,075 hedge contracts $-- Futures Contracts*** Net unrealized Net unrealized appreciation on depreciation on futures futures contracts $ 2,333 contracts $-- ---------------------------------------------------------------------------------------------------- Total $135,098 $-- ---------------------------------------------------------------------------------------------------- * Forward Foreign Currency Settlement Contracts are shown as a net unrealized appreciation on forward foreign currency settlement contracts on the Statement of Assets and Liabilities. ** Forward Foreign Currency Portfolio Hedge Contracts are shown as a net unrealized appreciation on forward foreign currency portfolio hedge contracts on the Statement of Assets and Liabilities. *** Reflects the net unrealized appreciation on futures contracts (see Note 1H). 40 Pioneer Global Equity Fund | Annual Report | 8/31/13 The effect of derivative instruments on the Statement of Operations for the year ended August 31, 2013 was as follows: ------------------------------------------------------------------------------------------------- Change in Derivatives Not Unrealized Accounted for as Realized Gain Appreciation or Hedging Instruments or (Loss) on (Depreciation) Under Accounting Location of Gain or (Loss) Derivatives on Derivatives Standards Codification on Derivatives Recognized Recognized Recognized (ASC) 815 in Income in Income in Income ------------------------------------------------------------------------------------------------- Forward Foreign Net realized loss on forward Currency Settlement foreign currency contracts Contracts and other assets and liabilities denominated in foreign currencies $(117,936) Forward Foreign Change in unrealized Currency Settlement appreciation (depreciation) Contracts on forward foreign currency contracts and other assets and liabilities denominated in foreign currencies $ (3,465) Forward Foreign Net realized gain on forward Currency Portfolio foreign currency contracts and Hedge Contracts other assets and liabilities denominated in foreign currencies $ 832,024 Forward Foreign Change in unrealized appreciation Currency Portfolio on forward foreign currency Hedge Contracts contracts and other assets and liabilities denominated in foreign currencies $17,051 Futures Contracts Net realized loss on futures contracts $(206,471) Futures Contracts Change in net unrealized appreciation on futures contracts $56,833 Pioneer Global Equity Fund | Annual Report | 8/31/13 41 Report of Independent Registered Public Accounting Firm To the Board of Trustees of Pioneer Series Trust V and the Shareowners of Pioneer Global Equity Fund: -------------------------------------------------------------------------------- We have audited the accompanying statement of assets and liabilities, including the schedule of investments, of Pioneer Global Equity Fund, one of the portfolios constituting Pioneer Series Trust V (the "Trust"), as of August 31, 2013, and the related statement of operations for the year then ended, the statements of changes in net assets for each of the two years in the period then ended, and the financial highlights for each of the periods indicated therein. These financial statements and financial highlights are the responsibility of the Trust's management. Our responsibility is to express an opinion on these financial statements and financial highlights based on our audits. We conducted our audits in accordance with the standards of the Public Company Accounting Oversight Board (United States). Those standards require that we plan and perform the audit to obtain reasonable assurance about whether the financial statements and financial highlights are free of material misstatement. We were not engaged to perform an audit of the Trust's internal control over financial reporting. Our audits included consideration of internal control over financial reporting as a basis for designing audit procedures that are appropriate in the circumstances, but not for the purpose of expressing an opinion on the effectiveness of the Trust's internal control over financial reporting. Accordingly, we express no such opinion. An audit also includes examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements and financial highlights, assessing the accounting principles used and significant estimates made by management, and evaluating the overall financial statement presentation. Our procedures included confirmation of securities owned as of August 31, 2013 by correspondence with the custodian, or others or by other appropriate auditing procedures where replies from others were not received. We believe that our audits provide a reasonable basis for our opinion. In our opinion, the financial statements and financial highlights referred to above present fairly, in all material respects, the financial position of Pioneer Global Equity Fund, one of the portfolios constituting Pioneer Series Trust V, at August 31, 2013, the results of its operations for the year then ended, the changes in its net assets for each of the two years in the period then ended, and the financial highlights for each of the periods indicated therein, in conformity with U.S. generally accepted accounting principles. /s/ Ernst & Young LLP Boston, Massachusetts October 28, 2013 42 Pioneer Global Equity Fund | Annual Report | 8/31/13 Trustees, Officers and Service Providers Investment Adviser Pioneer Investment Management, Inc. Custodian and Sub-Administrator Brown Brothers Harriman & Co. Independent Registered Public Accounting Firm Ernst & Young LLP Principal Underwriter Pioneer Funds Distributor, Inc. Legal Counsel Bingham McCutchen LLP Shareowner Services and Transfer Agent Pioneer Investment Management Shareholder Services, Inc. Proxy voting policies and procedures of the Fund are available without charge, upon request, by calling our toll free number (1-800-225-6292). Information regarding how the Fund voted proxies relating to portfolio securities during the most recent 12-month period ended June 30 is publicly available to shareowners at us.pioneerinvestments.com. This information is also available on the Securities and Exchange Commission's web site at www.sec.gov. Trustees and Officers The Fund's Trustees and Officers are listed on the following pages, together with their principal occupations during at least the past five years. Trustees who are interested persons of the Fund within the meaning of the 1940 Act are referred to as Interested Trustees. Trustees who are not interested persons of the Fund are referred to as Independent Trustees. Each of the Trustees, except Mr. Cogan and Mr. West, serves as a trustee of each of the 52 U.S. registered investment portfolios for which Pioneer serves as investment adviser (the "Pioneer Funds"). Each of Mr. Cogan and Mr. West serves as a Trustee of 47 Pioneer funds. The address for all Trustees and all officers of the Fund is 60 State Street, Boston, Massachusetts 02109. The Statement of Additional Information of the Fund includes additional information about the Trustees and is available, without charge, upon request, by calling 1-800-225-6292. Pioneer Global Equity Fund | Annual Report | 8/31/13 43 Independent Trustees ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ Thomas J. Perna (62) Trustee since Chairman and Chief Executive Officer, Director, Broadridge Chairman of the Board 2006. Serves until Quadriserv, Inc. (technology products for Financial Solutions, Inc. and Trustee a successor securities lending industry) (2008 - present); (investor communications and trustee is elected private investor (2004 - 2008); and Senior securities processing or earlier Executive Vice President, The Bank of New York provider for financial retirement or (financial and securities services) (1986 - 2004) services industry) (2009 - removal. present); Director, Quadriserv, Inc. (2005 - present); and Commissioner, New Jersey State Civil Service Commission (2011 - present) ------------------------------------------------------------------------------------------------------------------------------------ David R. Bock (69) Trustee since Managing Partner, Federal City Capital Advisors Director of Enterprise Trustee 2005. Serves until (corporate advisory services company) (1997 - Community Investment, Inc. a successor 2004 and 2008 - present); Interim Chief (privately-held affordable trustee is elected Executive Officer, Oxford Analytica, Inc. housing finance company) or earlier (privately held research and consulting company) (1985 - 2010); Director of retirement or (2010); Executive Vice President and Chief Oxford Analytica, Inc. (2008 removal. Financial Officer, I-trax, Inc. (publicly traded - present); Director of The health care services company) (2004 - 2007); and Swiss Helvetia Fund, Inc. Executive Vice President and Chief Financial (closed-end fund) (2010 - Officer, Pedestal Inc. (internet-based mortgage present); and Director of trading company) (2000 - 2002) New York Mortgage Trust (publicly traded mortgage REIT) (2004 - 2009, 2012 - present) ------------------------------------------------------------------------------------------------------------------------------------ Benjamin M. Friedman (68) Trustee since William Joseph Maier Professor of Political Trustee, Mellon Trustee 2008. Serves until Economy, Harvard University (1972 - present) Institutional Funds a successor Investment Trust and Mellon trustee is elected Institutional Funds Master or earlier Portfolio (oversaw 17 retirement or portfolios in fund complex) removal. (1989-2008) ------------------------------------------------------------------------------------------------------------------------------------ 44 Pioneer Global Equity Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ Margaret B.W. Graham (66) Trustee since Founding Director, Vice President and Corporate None Trustee 2005. Serves until Secretary, The Winthrop Group, Inc. (consulting a successor firm) (1982-present); Desautels Faculty of trustee is elected Management, McGill University (1999 - present); or earlier and Manager of Research Operations and retirement or Organizational Learning, Xerox PARC, Xerox's removal. advance research center (1990-1994) ------------------------------------------------------------------------------------------------------------------------------------ Marguerite A. Piret (65) Trustee since President and Chief Executive Officer, Newbury, Director of New America Trustee 2005. Serves until Piret & Company, Inc. (investment banking firm) High Income Fund, Inc. a successor (1981 - present) (closed-end investment trustee is elected company) (2004 - present); or earlier and member, Board of retirement or Governors, Investment removal. Company Institute (2000 - 2006) ------------------------------------------------------------------------------------------------------------------------------------ Stephen K. West (84) Trustee since Senior Counsel, Sullivan & Cromwell LLP (law Director, The Swiss Trustee 2005. Serves until firm) (1998 - present); and Partner, Sullivan & Helvetia Fund, Inc. a successor Cromwell LLP (prior to 1998) (closed-end investment trustee is elected company); and Director, or earlier Invesco, Ltd. (formerly retirement or AMVESCAP, PLC) (investment removal. manager) (1997-2005) ------------------------------------------------------------------------------------------------------------------------------------ Pioneer Global Equity Fund | Annual Report | 8/31/13 45 Interested Trustees ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ John F. Cogan, Jr. (87)* Trustee since Non-Executive Chairman and a director of Pioneer None Trustee, President and 2005. Serves until Investment Management USA Inc. ("PIM-USA"); Chief a successor Chairman and a director of Pioneer; Chairman and Executive Officer of the trustee is elected Director of Pioneer Institutional Asset Fund or earlier Management, Inc. (since 2006); Director of Pioneer retirement or Alternative Investment Management Limited (Dublin) removal. (until October 2011); President and a director of Pioneer Alternative Investment Management (Bermuda) Limited and affiliated funds; Deputy Chairman and a director of Pioneer Global Asset Management S.p.A. ("PGAM") (until April 2010); Director of Nano-C, Inc. (since 2003); Director of Cole Management Inc. (2004 - 2011); Director of Fiduciary Counseling, Inc. (until December 2011); President of all of the Pioneer Funds; and Retired Partner, Wilmer Cutler Pickering Hale and Dorr LLP ------------------------------------------------------------------------------------------------------------------------------------ Daniel K. Kingsbury (54)* Trustee since Director, CEO and President of PIM-USA (since None Trustee and Executive 2007. Serves until February 2007); Director and President of Pioneer Vice President a successor and Pioneer Institutional Asset Management, Inc. trustee is elected (since February 2007); Executive Vice President of or earlier all of the Pioneer Funds (since March 2007); retirement or Director of PGAM (2007 - 2010); Head of New Europe removal. Division, PGAM (2000 - 2005); Head of New Markets Division, PGAM (2005 - 2007) ------------------------------------------------------------------------------------------------------------------------------------ * Mr. Cogan and Mr. Kingsbury are Interested Trustees because they are officers or directors of the Fund's investment adviser and certain of its affiliates. 46 Pioneer Global Equity Fund | Annual Report | 8/31/13 Fund Officers ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Officer ------------------------------------------------------------------------------------------------------------------------------------ Christopher J. Kelley (48) Since 2005. Serves Vice President and Associate General Counsel of Pioneer None Secretary at the discretion of since January 2008 and Secretary of all of the Pioneer the Board. Funds since June 2010; Assistant Secretary of all of the Pioneer Funds from September 2003 to May 2010; and Vice President and Senior Counsel of Pioneer from July 2002 to December 2007 ------------------------------------------------------------------------------------------------------------------------------------ Carol B. Hannigan (52) Since 2010. Serves Fund Governance Director of Pioneer since December 2006 None Assistant Secretary at the discretion of and Assistant Secretary of all the Pioneer Funds since the Board. June 2010; Manager - Fund Governance of Pioneer from December 2003 to November 2006; and Senior Paralegal of Pioneer from January 2000 to November 2003 ------------------------------------------------------------------------------------------------------------------------------------ Thomas Reyes (50) Since 2010. Serves Counsel of Pioneer since June 2007 and Assistant Secretary None Assistant Secretary at the discretion of of all the Pioneer Funds since June 2010; and Vice the Board. President and Counsel at State Street Bank from October 2004 to June 2007 ------------------------------------------------------------------------------------------------------------------------------------ Mark E. Bradley (53) Since 2008. Serves Vice President - Fund Treasury of Pioneer; Treasurer of None Treasurer and Chief at the discretion of all of the Pioneer Funds since March 2008; Deputy Financial the Board. Treasurer of Pioneer from March 2004 to February 2008; and and Accounting Officer of Assistant Treasurer of all of the Pioneer Funds from March the Fund 2004 to February 2008 ------------------------------------------------------------------------------------------------------------------------------------ Luis I. Presutti (48) Since 2005. Serves Assistant Vice President - Fund Treasury of Pioneer; and None Assistant Treasurer at the discretion of Assistant Treasurer of all of the Pioneer Funds the Board. ------------------------------------------------------------------------------------------------------------------------------------ Gary Sullivan (55) Since 2005. Serves Fund Accounting Manager - Fund Treasury of Pioneer; and None Assistant Treasurer at the discretion of Assistant Treasurer of all of the Pioneer Funds the Board. ------------------------------------------------------------------------------------------------------------------------------------ David F. Johnson (33) Since 2009. Serves Fund Administration Manager - Fund Treasury of Pioneer None Assistant Treasurer at the discretion of since November 2008; Assistant Treasurer of all of the the Board. Pioneer Funds since January 2009; and Client Service Manager - Institutional Investor Services at State Street Bank from March 2003 to March 2007 ------------------------------------------------------------------------------------------------------------------------------------ Pioneer Global Equity Fund | Annual Report | 8/31/13 47 Fund Officers (continued) ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Officer ------------------------------------------------------------------------------------------------------------------------------------ Jean M. Bradley (60) Since 2010. Serves Chief Compliance Officer of Pioneer and of all the None Chief Compliance Officer at the discretion of Pioneer Funds since March 2010; Director of Adviser and the Board. Portfolio Compliance at Pioneer since October 2005; and Senior Compliance Officer for Columbia Management Advisers, Inc. from October 2003 to October 2005 ------------------------------------------------------------------------------------------------------------------------------------ Kelley O'Donnell (42) Since 2006. Serves Director--Transfer Agency Compliance of Pioneer and None Anti-Money Laundering at the discretion of Anti-Money Laundering Officer of all the Pioneer Funds Officer the Board. since 2006 ------------------------------------------------------------------------------------------------------------------------------------ 48 Pioneer Global Equity Fund | Annual Report | 8/31/13 This page for your notes. Pioneer Global Equity Fund | Annual Report | 8/31/13 49 This page for your notes. 50 Pioneer Global Equity Fund | Annual Report | 8/31/13 This page for your notes. Pioneer Global Equity Fund | Annual Report | 8/31/13 51 This page for your notes. 52 Pioneer Global Equity Fund | Annual Report | 8/31/13 How to Contact Pioneer We are pleased to offer a variety of convenient ways for you to contact us for assistance or information. Call us for: -------------------------------------------------------------------------------- Account Information, including existing accounts, new accounts, prospectuses, applications and service forms 1-800-225-6292 FactFone(SM) for automated fund yields, prices, account information and transactions 1-800-225-4321 Retirement plans information 1-800-622-0176 Write to us: -------------------------------------------------------------------------------- PIMSS, Inc. P.O. Box 55014 Boston, Massachusetts 02205-5014 Our toll-free fax 1-800-225-4240 Our internet e-mail address ask.pioneer@pioneerinvestments.com (for general questions about Pioneer only) Visit our web site: us.pioneerinvestments.com This report must be preceded or accompanied by a prospectus. The Fund files a complete schedule of investments with the Securities and Exchange Commission for the first and third quarters for each fiscal year on Form N-Q. Shareholders may view the filed Form N-Q by visiting the Commission's web site at http://www.sec.gov. The filed form may also be viewed and copied at the Commission's Public Reference Room in Washington, DC. Information regarding the operations of the Public Reference Room may be obtained by calling 1-800-SEC-0330. [LOGO] PIONEER Investments(R) Pioneer Investment Management, Inc. 60 State Street Boston, MA 02109 us.pioneerinvestments.com Securities offered through Pioneer Funds Distributor, Inc. 60 State Street, Boston, MA 02109 Underwriter of Pioneer Mutual Funds, Member SIPC (C) 2013 Pioneer Investments 19431-07-1013 Pioneer High Income Municipal Fund -------------------------------------------------------------------------------- Annual Report | August 31, 2013 -------------------------------------------------------------------------------- Ticker Symbols: Class A PIMAX Class C HICMX Class Y HIMYX [LOGO] PIONEER Investments(R) visit us: us.pioneerinvestments.com Table of Contents Letter to Shareowners 2 Portfolio Management Discussion 4 Portfolio Summary 8 Prices and Distributions 9 Performance Update 10 Comparing Ongoing Fund Expenses 13 Schedule of Investments 15 Financial Statements 25 Notes to Financial Statements 32 Report of Independent Registered Public Accounting Firm 39 Trustees, Officers and Service Providers 40 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 1 President's Letter Dear Shareowner, When we look at the U.S. economy as we head into the second half of 2013, we continue to see slow, but ongoing, growth. Employment has been steadily rising. Consumer incomes, savings, wealth, and debt-servicing capacity have been solid buttresses for the recovering housing and auto industries. Industrial activity is growing only modestly, but current corporate profits are generally solid and balance sheets appear able to support needed capital spending and dividend* payouts. The scaled-back "fiscal cliff" tax increases and spending cuts have meaningfully cut the budget deficit without, it seems, driving the economy back into recession. In addition, we feel that continuing slack in labor markets and capacity utilization offers the potential for continuing growth without bottlenecks and rising inflation. After observing the strengthening economic trends, the Federal Reserve (the Fed) has hinted that it may begin to scale back its bond purchases (currently $85 billion per month in quantitative easing, or "QE") later in 2013, and could terminate the purchases altogether sometime in 2014, depending on subsequent economic data releases. Pioneer believes that, barring an external shock, modest economic growth can be sustained at least over the next couple of years without continuous, aggressive intervention from the Fed. The Fed has also said that short-term interest rates are likely to remain near zero for some time to come. Given that inflation remains subdued and unemployment remains high, there is no urgency about raising rates. While inflation is not a near-term concern, the Fed's aggressive monetary policies helped investors drive long-term Treasury yields to unsustainably low levels. A return to more normal levels in response to expectations of a stronger economy and the potential for less QE resulted in disappointing returns for bond investors during the first half of 2013, but the stock market rewarded shareholders who were undaunted by the double-barreled threat of the "fiscal cliff" and debt-ceiling debates at the beginning of 2013. The Standard & Poor's 500 Index, a broad measure of the U.S. stock market, returned 13.82% during the first six months of 2013, while the Barclays Aggregate Bond Index, which tracks the performance of a higher-quality U.S. bond universe, returned -2.44%. Investors showed a rising preference for higher-yielding corporate paper over government bonds during the first half of 2013, helping the Bank of America Merrill Lynch High Yield Master II Index, which measures the performance of high-yield corporate bonds, to post a 1.50% return for the six months ended June 30, 2013. Three-month Treasury bills, generally regarded as essentially "risk free" by the markets, returned 0.03% in the first half of 2013. * Dividends are not guaranteed. 2 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 There are certainly risks and uncertainties that continue to plague the global economy. Europe remains in recession and a number of countries in the emerging markets have experienced difficulties. Still, a potential ending of the European recession, continuing economic improvement in Japan in response to the new government's quantitative easing policies, and a "soft landing" of 7% growth in China could very well result in an improving global outlook over the remainder of 2013. There are also geopolitical worries abroad and political fights at home, and while most of the widely recognized risks we've outlined may already be "priced in" to the market, we believe investors should continue to expect market volatility. At Pioneer, we have long advocated the benefits of staying diversified and investing for the long term. And while diversification alone does not assure a profit or protect against loss in a declining market, we believe there are still opportunities for prudent investors to earn attractive returns. Our advice, as always, is to work closely with a trusted financial advisor to discuss your goals and work together to develop an investment strategy that meets your individual needs, keeping in mind that there is no single best strategy that works for every investor. Pioneer's investment teams have, since 1928, sought out attractive opportunities in global equity and bond markets, using in-depth research to identify undervalued individual securities, and using thoughtful risk management to construct portfolios which balance potential risks and rewards in an ever-changing world. We encourage you to learn more about Pioneer and our time-tested approach to investing by consulting with your financial advisor or visiting us online at us.pioneerinvestments.com. We greatly appreciate your trust in us, and we thank you for investing with Pioneer. Sincerely, /s/ Daniel K. Kingsbury Daniel K. Kingsbury President and CEO Pioneer Investment Management USA, Inc. Any information in this shareowner report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of opinion as of the date of this report. These statements should not be relied upon for any other purposes. Past performance is no guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 3 Portfolio Management Discussion | 8/31/13 In the following interview, portfolio manager David Eurkus reviews the market environment for high-yield municipal investments and the performance of Pioneer High Income Municipal Fund during the 12 months ended August 31, 2013. Mr. Eurkus, a senior vice president and a portfolio manager at Pioneer, manages the Fund along with Jonathan Chirunga, a vice president and a portfolio manager at Pioneer. Mr. Chirunga was named as a portfolio manager on the Fund on May 17, 2013, replacing Timothy Pynchon. Q How would you describe the investment environment for high-yield municipal bonds during the 12 months ended August 31, 2013? A During the first eight months of the period, from September 2012 through April 2013, favorable market conditions supported high-yield municipal bonds, continuing a trend that had prevailed throughout the 2012 calendar year. Investors were attracted to high-yield municipal securities because of their very attractive spreads - or yield advantages - over higher-quality municipals and even over many taxable bonds with similar quality ratings. Against a backdrop of steady, albeit slow, growth in the domestic economy, the competitive yields of municipal securities, and especially those of high-yield municipals, generated growing demand. Investors became even more attracted to tax-advantaged investments after some marginal income tax rates rose at the start of 2013. All of that changed, however, in May 2013 as municipal securities (including high-yield debt) fell out of favor as a result of a series of developments that undermined investor sentiment. Perhaps the biggest development was the suggestion by Federal Reserve (Fed) Chairman Ben Bernanke that the U.S. central bank might consider tapering the pace of its monthly purchases of government bonds and agency mortgages (quantitative easing), a program that had helped to keep interest rates low and provided some support to economic growth. The Fed's suggestion led to fears that interest rates could start rising, a development that could hurt the overall bond market. The second negative development was the well-publicized bankruptcy of the City of Detroit, which raised worries about the financial stability of other large cities. The final negative factor was the publication of an article reporting on the financial difficulties faced by the Commonwealth of Puerto Rico, which added to investors' growing worries about the stability of the municipal-debt market. 4 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 The negative developments from May through August of 2013 resulted in a sharp decline of municipal bond prices and significant underperformance of the asset class relative to U.S. Treasuries and many other segments of the fixed-income market as the 12-month period drew to a close. That represented a departure from municipals' long-term track record of outperforming Treasuries and other taxable bonds during bond market corrections. Furthermore, because of their greater sensitivity to credit risk, lower-rated municipal bonds with higher yields substantially underperformed investment-grade municipals. Q How did the Fund perform in that environment during the 12 months ended August 31, 2013? A Pioneer High Income Municipal Fund's Class A shares returned -4.26% at net asset value during the 12 months ended August 31, 2013, while the Fund's benchmark, the Barclays High Yield Municipal Bond Index (the Barclays Index), returned -3.91%. During the same period, the average return of the 160 mutual funds in Morningstar's High Yield Municipal Debt category was -5.89%. Q What elements of the Fund's positioning had the biggest effect on benchmark-relative returns during the 12 months ended August 31, 2013? A The Fund had been performing relatively well before the market downturn, but returns took a hit as investor sentiment turned negative during the final four months of the fiscal year. The Fund's performance declined as the demand for high-yield municipal debt shrank and institutional investors, including mutual funds, began selling some of their municipal-related investments. The Fund slightly underperformed the benchmark Barclays Index during the 12-month period, as the portfolio's exposures to underperforming sectors within the municipal asset class were particularly damaging to returns. The underperforming sectors included municipal bonds backed by continuing care retirement communities (CCRCs), tobacco litigation settlement securities, and project finance bonds. The disappointing results during the period occurred despite the Fund's traditional emphasis on project revenue bonds, which are securities backed by the revenue streams produced from specific public projects rather than by general municipal revenues. To attempt to control risks within the portfolio, we have focused on holding project revenue securities because we believe they tend to be less sensitive to changes in the financial health conditions of issuing municipalities or public agencies. It should be noted that the Fund had no exposure to either the City of Detroit's or the Commonwealth of Puerto Rico's debt during the period. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 5 Q Which individual securities had the biggest effect on the Fund's benchmark- relative underperformance during the 12 months ended August 31, 2013? A The Fund's positions in securities backed by several individual projects had sizable effects on benchmark-relative results. The underperformers included bonds used to help finance a steel plant in Erie County, New York, and new dormitory construction at Florida Keys Community College. Positions in securities backed by expected revenues from a corrections facility and an airport refueling station also were significant detractors from benchmark- relative performance. Q How do you plan to position the Fund moving forward? A To attempt to control risk in an unsettled market, we have been moving to add greater diversification* to the Fund's portfolio of investments. In so doing, we are placing the greatest emphasis on intensive, fundamental credit research to ensure that we understand all the dynamics affecting the financial health of each individual holding in the portfolio. At the same time, we also are conscious of our mandate to provide shareholders with attractive, tax-advantaged income. As we increase the Fund's level of diversification, we expect to reduce our emphasis on health care facility bonds, which accounted for more than half the Fund's net assets at the end of the period on August 31, 2013. Many of the securities were CCRCs, which performed poorly in the latter part of the 12-month period. In general, we believe that the prices of many high-yield municipal securities have fallen excessively, particularly relative to their long-term credit record. Since the 1930s, municipal securities are second only to U.S. Treasuries with respect to avoiding credit defaults, and they also have a relatively good record in recovering assets in the event of defaults. As the high-yield municipal market continues to expand, we also think investors potentially could benefit from the greater diversification of risks. Furthermore, we believe new technologies and the development of new investment opportunities in the energy and transportation industries, especially shipping, also could offer important, significant investment opportunities. Going forward, we remain committed to conducting the highest-quality credit research when selecting the Fund's investments, and to be mindful of our responsibility to our shareholders to be careful managers of their assets, even as we endeavor to seek out attractive sources of tax-advantaged income for the Fund. * Diversification does not assure a profit nor protect against loss in a declining market. 6 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Please refer to the Schedule of Investments on pages 15-24 for a full listing of Fund securities. Investments in high-yield or lower rated securities are subject to greater-than- average price volatility, illiquidity and possibility of default. When interest rates rise, the prices of fixed-income securities in the Fund will generally fall. Conversely, when interest rates fall, the prices of fixed income securities in the fund will generally rise. Investments in the Fund are subject to possible loss due to the financial failure of issuers of underlying securities and their inability to meet their debt obligations. Prepayment risk is the chance that an issuer may exercise its right to prepay its security, if falling interest rates prompt the issuer to do so. Forced to reinvest the unanticipated proceeds at lower interest rates, the Fund would experience a decline in income and lose the opportunity for additional price appreciation. The portfolio may invest in mortgage-backed securities, which during times of fluctuating interest rates may increase or decrease more than other fixed-income securities. Mortgage-backed securities are also subject to pre-payments. The Fund may invest in inverse floating-rate obligations (a type of derivative instrument), which may have price volatility and involve leverage risk. A portion of income may be subject to local, state, federal, and/or alternative minimum tax. Capital gains, if any, are subject to a capital gains tax. At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making it more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. These risks may increase share price volatility. Past performance is not a guarantee of future results, and there is no guarantee that market forecasts discussed will be realized. Any information in this shareholder report regarding market or economic trends or the factors influencing the Fund's historical or future performance are statements of opinion as of the date of this report. These opinions should not be relied upon for any other purposes. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 7 Portfolio Summary | 8/31/13 Portfolio Quality -------------------------------------------------------------------------------- (As a percentage of total investment portfolio) [THE FOLLOWING DATA WAS REPRESENTED AS A PIE CHART IN THE PRINTED MATERIAL] AA 0.3% A 1.5% BBB 2.0% BB 4.5% B 7.0% CCC 2.2% Not Rated 82.5% Bond ratings are ordered highest to lowest in portfolio. Based on Standard & Poor's measures, AAA (highest possible rating) through BBB are considered investment grade; BB or lower ratings are considered non-investment grade. Cash equivalents and some bonds may not be rated. Sector Distribution -------------------------------------------------------------------------------- (As a percentage of total investment portfolio) [THE FOLLOWING DATA WAS REPRESENTED AS A PIE CHART IN THE PRINTED MATERIAL] Health 50.8% Pollution Control Revenue 16.3% Education 12.5% Various Revenues 7.6% Special Revenues 4.7% Transportation 4.2% Housing 2.0% Insured 1.8% General Obligation 0.1% 10 Largest Holdings -------------------------------------------------------------------------------- (As a percentage of debt holdings)* 1. Jefferson County Industrial Development Corp. Texas, 8.25%, 7/1/32 3.90% ------------------------------------------------------------------------------------ 2. Sanger Industrial Development Corp., 8.0%, 7/1/38 3.78 ------------------------------------------------------------------------------------ 3. City of Philippi West Virginia, 7.75%, 10/1/44 3.74 ------------------------------------------------------------------------------------ 4. Illinois Finance Authority, 8.125%, 2/15/40 2.63 ------------------------------------------------------------------------------------ 5. West Virginia Hospital Finance Authority, 9.125%, 10/1/41 2.27 ------------------------------------------------------------------------------------ 6. Public Finance Authority, 7.0%, 10/1/42 2.07 ------------------------------------------------------------------------------------ 7. Capital Trust Agency, Inc., 7.75%, 1/1/41 1.85 ------------------------------------------------------------------------------------ 8. Public Finance Authority, 8.25%, 6/1/46 1.80 ------------------------------------------------------------------------------------ 9. Bloomington Port Authority, 9.0%, 12/1/35 1.77 ------------------------------------------------------------------------------------ 10. Illinois Finance Authority, 8.25%, 5/15/45 1.72 ------------------------------------------------------------------------------------ * This list excludes temporary cash investments and derivative instruments. The portfolio is actively managed, and current holdings may be different. The holdings listed should not be considered recommendations to buy or sell any security listed. 8 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Prices and Distributions | 8/31/13 Net Asset Value per Share -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Class 8/31/13 8/31/12 -------------------------------------------------------------------------------- A $7.19 $7.94 -------------------------------------------------------------------------------- C $7.19 $7.94 -------------------------------------------------------------------------------- Y $7.10 $7.84 -------------------------------------------------------------------------------- Distributions per Share: 9/1/12-8/31/13 -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Net Investment Short-Term Long-Term Class Income Capital Gains Capital Gains -------------------------------------------------------------------------------- A $ 0.4420 $ -- $ -- -------------------------------------------------------------------------------- C $ 0.3823 $ -- $ -- -------------------------------------------------------------------------------- Y $ 0.4531 $ -- $ -- -------------------------------------------------------------------------------- Index Definitions -------------------------------------------------------------------------------- The Barclays High Yield Municipal Bond Index is an unmanaged measure of the performance of the high-yield municipal bond market. Index returns are calculated monthly, assume reinvestment of dividends and, unlike Fund returns, do not reflect any fees, expenses or sales charges. It is not possible to invest directly in an index. The index defined here pertains to the "Value of $10,000 Investment" and "Value of $5 Million Investment" charts shown on pages 10-12. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 9 Performance Update | 8/31/13 Class A Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Class A shares of Pioneer High Income Municipal Fund at public offering price during the periods shown, compared to that of the Barclays High Yield Municipal Bond Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- Net Asset Public Offering Period Value (NAV) Price (POP) -------------------------------------------------------------------------------- Life-of-Class (10/17/06) 1.67% 0.99% 5 Years 3.04 2.10 1 Year -4.26 -8.53 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross -------------------------------------------------------------------------------- 0.89% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $10,000 Investment Pioneer High Income Barclays High Yield Municipal Fund Municipal Bond Index 10/31/2006 $ 9,550 $ 10,000 8/31/2007 $ 9,662 $ 10,076 8/31/2008 $ 9,184 $ 9,635 8/31/2009 $ 7,861 $ 8,750 8/31/2010 $ 9,838 $ 10,682 8/31/2011 $ 10,018 $ 11,051 8/31/2012 $ 11,144 $ 12,752 8/31/2013 $ 10,669 $ 12,253 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. NAV results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. POP returns reflect deduction of maximum 4.50% sales charge. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 10 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Performance Update | 8/31/13 Class C Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $10,000 investment made in Class C shares of Pioneer High Income Municipal Fund during the periods shown, compared to that of the Barclays High Yield Municipal Bond Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- If If Period Held Redeemed -------------------------------------------------------------------------------- Life-of-Class (10/17/06) 0.81% 0.81% 5 Years 2.25 2.25 1 Year -4.98 -4.98 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross -------------------------------------------------------------------------------- 1.63% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $10,000 Investment Pioneer High Income Barclays High Yield Municipal Fund Municipal Bond Index 10/31/2006 $ 10,000 $ 10,000 8/31/2007 $ 10,026 $ 10,076 8/31/2008 $ 9,430 $ 9,635 8/31/2009 $ 7,999 $ 8,750 8/31/2010 $ 9,928 $ 10,682 8/31/2011 $ 10,046 $ 11,051 8/31/2012 $ 11,094 $ 12,752 8/31/2013 $ 10,541 $ 12,253 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Class C shares held for less than one year are also subject to a 1% contingent deferred sales charge (CDSC). "If Held" results represent the percent change in net asset value per share. Returns would have been lower had sales charges been reflected. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 11 Performance Update | 8/31/13 Class Y Shares Investment Returns -------------------------------------------------------------------------------- The mountain chart on the right shows the change in value of a $5 million investment made in Class Y shares of Pioneer High Income Municipal Fund during the periods shown, compared to that of the Barclays High Yield Municipal Bond Index. Average Annual Total Returns (As of August 31, 2013) -------------------------------------------------------------------------------- If If Period Held Redeemed -------------------------------------------------------------------------------- Life-of-Class (10/17/06) 1.59% 1.59% 5 Years 3.12 3.12 1 Year -4.05 -4.05 -------------------------------------------------------------------------------- Expense Ratio (Per prospectus dated December 31, 2012) -------------------------------------------------------------------------------- Gross -------------------------------------------------------------------------------- 0.67% -------------------------------------------------------------------------------- [THE FOLLOWING DATA WAS REPRESENTED AS A MOUNTAIN CHART IN THE PRINTED MATERIAL] Value of $5 Million Investment Pioneer High Income Barclays High Yield Municipal Fund Municipal Bond Index 10/31/2006 $ 5,000,000 $ 5,000,000 8/31/2007 $ 5,040,643 $ 5,037,963 8/31/2008 $ 4,765,972 $ 4,817,672 8/31/2009 $ 4,084,381 $ 4,374,981 8/31/2010 $ 5,094,276 $ 5,340,982 8/31/2011 $ 5,197,079 $ 5,525,277 8/31/2012 $ 5,790,897 $ 6,376,035 8/31/2013 $ 5,556,051 $ 6,126,737 Call 1-800-225-6292 or visit us.pioneerinvestments.com for the most recent month-end performance results. Current performance may be lower or higher than the performance data quoted. The performance data quoted represents past performance, which is no guarantee of future results. Investment return and principal value will fluctuate, and shares, when redeemed, may be worth more or less than their original cost. Class Y shares are not subject to sales charges and are available for limited groups of eligible investors, including institutional investors. All results are historical and assume the reinvestment of dividends and capital gains. Other share classes are available for which performance and expenses will differ. Performance results reflect any applicable expense waivers in effect during the periods shown. Without such waivers Fund performance would be lower. Waivers may not be in effect for all funds. Certain fee waivers are contractual through a specified period. Otherwise, fee waivers can be rescinded at any time. See the prospectus and financial statements for more information. The performance table and graph do not reflect the deduction of fees and taxes that a shareowner would pay on Fund distributions or the redemption of Fund shares. 12 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Comparing Ongoing Fund Expenses As a shareowner in the Fund, you incur two types of costs: (1) ongoing costs, including management fees, distribution and/or service (12b-1) fees, and other Fund expenses; and (2) transaction costs, including sales charges (loads) on purchase payments. This example is intended to help you understand your ongoing expenses (in dollars) of investing in the Fund and to compare these costs with the ongoing costs of investing in other mutual funds. The example is based on an investment of $1,000 at the beginning of the Fund's latest six-month period and held throughout the six months. Using the Tables -------------------------------------------------------------------------------- Actual Expenses The first table below provides information about actual account values and actual expenses. You may use the information in this table, together with the amount you invested, to estimate the expenses that you paid over the period as follows: 1. Divide your account value by $1,000 Example: an $8,600 account value (divided by) $1,000 = 8.6 2. Multiply the result in (1) above by the corresponding share class's number in the third row under the heading entitled "Expenses Paid During Period" to estimate the expenses you paid on your account during this period. Expenses Paid on a $1,000 Investment in Pioneer High Income Municipal Fund Based on actual returns from March 1, 2013, through August 31, 2013. -------------------------------------------------------------------------------- Share Class A C Y -------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 Value on 3/1/13 -------------------------------------------------------------------------------- Ending Account Value $ 910.60 $ 905.99 $ 911.29 (after expenses) on 8/31/13 -------------------------------------------------------------------------------- Expenses Paid $ 4.24 $ 7.83 $ 3.47 During Period* -------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized net expense ratio of 0.88%, 1.63% and 0.72% for Class A, Class C and Class Y shares, respectively, multiplied by the average account value over the period, multiplied by 184/365 (to reflect the one-half year period). Pioneer High Income Municipal Fund | Annual Report | 8/31/13 13 Hypothetical Example for Comparison Purposes The table below provides information about hypothetical account values and hypothetical expenses based on the Fund's actual expense ratio and an assumed rate of return of 5% per year before expenses, which is not the Fund's actual return. The hypothetical account values and expenses may not be used to estimate the actual ending account balance or expenses you paid for the period. You may use this information to compare the ongoing costs of investing in the Fund and other funds. To do so, compare this 5% hypothetical example with the 5% hypothetical examples that appear in the shareholder reports of the other funds. Please note that the expenses shown in the tables are meant to highlight your ongoing costs only and do not reflect any transaction costs, such as sales charges (loads) that are charged at the time of the transaction. Therefore, the table below is useful in comparing ongoing costs only and will not help you determine the relative total costs of owning different funds. In addition, if these transaction costs were included, your costs would have been higher. Expenses Paid on a $1,000 Investment in Pioneer High Income Municipal Fund Based on a hypothetical 5% return per year before expenses, reflecting the period from March 1, 2013, through August 31, 2013. -------------------------------------------------------------------------------- Share Class A C Y -------------------------------------------------------------------------------- Beginning Account $1,000.00 $1,000.00 $1,000.00 Value on 3/1/13 -------------------------------------------------------------------------------- Ending Account Value $1,020.77 $1,016.99 $1,021.58 (after expenses) on 8/31/13 -------------------------------------------------------------------------------- Expenses Paid $ 4.48 $8.29 $3.67 During Period* -------------------------------------------------------------------------------- * Expenses are equal to the Fund's annualized net expense ratio of 0.88%, 1.63% and 0.72% for Class A, Class C and Class Y shares, respectively, multiplied by the average account value over the period, multiplied by 184/365 (to reflect the one-half year period). 14 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Schedule of Investments | 8/31/13 ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- MUNICIPAL BONDS -- 110.9% Alabama -- 0.8% 2,000,000 NR/NR Huntsville-Redstone Village Special Care Facilities Financing Authority, 6.875%, 1/1/43 $ 1,961,460 2,580,000 NR/NR Huntsville-Redstone Village Special Care Facilities Financing Authority, 7.5%, 1/1/47 2,661,296 ------------- $ 4,622,756 ----------------------------------------------------------------------------------------------------------- Alaska -- 1.5% 12,600,000 NR/B2 Northern Tobacco Securitization Corp., 5.0%, 6/1/46 $ 8,412,516 ----------------------------------------------------------------------------------------------------------- Arizona -- 0.8% 750,000 NR/NR Pima County Industrial Development Authority, 8.5%, 7/1/39 $ 808,230 3,925,000 NR/NR San Luis Facility Development Corp., 8.375%, 5/1/27 3,451,410 ------------- $ 4,259,640 ----------------------------------------------------------------------------------------------------------- California -- 5.1% 4,000,000 NR/NR California County Tobacco Securitization Agency, 5.0%, 6/1/47 $ 2,843,800 3,500,000 B-/NR California County Tobacco Securitization Agency, 5.25%, 6/1/45 2,577,260 4,000,000 NR/B2 California County Tobacco Securitization Agency, 5.25%, 6/1/45 2,964,480 3,250,000 NR/B2 California County Tobacco Securitization Agency, 5.65%, 6/1/41 2,457,942 6,300,000 BB/NR California Municipal Finance Authority, 6.0%, 7/1/42 5,784,408 3,000,000 BB+/NR California School Finance Authority, 7.375%, 10/1/43 3,000,000 2,000,000 NR/NR California Statewide Communities Development Authority, 7.5%, 6/1/42 2,124,920 315,559 NR/NR California Statewide Communities Development Authority, 9.0%, 12/1/38 (c) 2,739 4,000,000 AA-/Aa3 Pittsburg Unified School District, 9/1/38 (d) 715,120 3,925,000 AA-/Aa3 Pittsburg Unified School District, 9/1/39 (d) 648,646 2,500,000 AA-/Aa3 Pittsburg Unified School District, 9/1/41 (d) 405,225 1,925,000 AA-/Aa3 Pittsburg Unified School District, 9/1/42 (d) 291,830 6,395,000 B-/Caa1 Tobacco Securitization Authority of Northern California, 5.375%, 6/1/38 4,863,525 ------------- $ 28,679,895 ----------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 15 Schedule of Investments | 8/31/13 (continued) ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Colorado -- 2.8% 38,000,000 BBB/Baa2 E-470 Public Highway Authority, 9/1/40 (d) $ 7,391,380 1,500,000 BBB/Baa2 E-470 Public Highway Authority, 9/1/41 (d) 273,855 8,000,000 NR/NR Kremmling Memorial Hospital District, 7.125%, 12/1/45 8,078,240 ------------- $ 15,743,475 ----------------------------------------------------------------------------------------------------------- Florida -- 12.7% 5,000,000 NR/NR Alachua County Health Facilities Authority, 8.125%, 11/15/41 $ 5,307,450 5,000,000 NR/NR Alachua County Health Facilities Authority, 8.125%, 11/15/46 5,294,050 5,000,000 NR/NR Capital Trust Agency, Inc., 7.375%, 1/1/48 4,043,850 11,000,000 NR/B1 Capital Trust Agency, Inc., 7.75%, 1/1/41 11,587,730 5,900,000 NR/NR Collier County Industrial Development Authority, 14.0%, 5/15/15 5,950,504 3,740,000 NR/NR County of Lake Florida, 7.125%, 11/1/42 3,210,715 1,820,000 NR/NR County of Liberty Florida, 8.25%, 7/1/28 1,358,630 1,450,000 NR/NR County of Palm Beach Florida, 6/1/16 (144A) (d) 1,450,000 2,290,000 NR/NR County of Palm Beach Florida, 2.0%, 6/1/16 2,291,832 10,380,000 NR/NR Florida Development Finance Corp., 7.625%, 6/15/41 10,711,122 5,000,000 NR/NR Florida Development Finance Corp., 7.75%, 6/15/42 5,226,700 4,000,000 BB/NR Lee County Industrial Development Authority Florida, 5.375%, 6/15/37 3,569,120 3,000,000 BB/NR Lee County Industrial Development Authority Florida, 5.75%, 6/15/42 2,766,780 4,175,000 NR/NR Sarasota County Health Facilities Authority, 5.625%, 7/1/27 3,805,429 2,285,000 NR/NR Sarasota County Health Facilities Authority, 5.75%, 7/1/37 1,977,142 3,640,000 NR/NR Sarasota County Health Facilities Authority, 5.75%, 7/1/45 3,058,292 ------------- $ 71,609,346 ----------------------------------------------------------------------------------------------------------- Georgia -- 2.2% 6,000,000 B/NR Clayton County Development Authority, 8.75%, 6/1/29 $ 6,776,340 3,650,000 NR/NR Fulton County Residential Care Facilities for the Elderly Authority, 5.0%, 7/1/27 3,265,509 3,000,000 NR/NR Fulton County Residential Care Facilities for the Elderly Authority, 5.125%, 7/1/42 2,418,480 ------------- $ 12,460,329 ----------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 16 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Hawaii -- 0.3% 700,000 NR/NR Hawaii State Department of Budget & Finance, 7.5%, 11/15/15 $ 701,554 1,000,000 NR/NR Hawaii State Department of Budget & Finance, 9.0%, 11/15/44 1,108,670 ------------- $ 1,810,224 ----------------------------------------------------------------------------------------------------------- Illinois -- 11.5% 2,634,795 NR/NR Illinois Finance Authority, 11/15/52 (d) $ 107,157 526,959 NR/NR Illinois Finance Authority, 11/15/52 (d) 114,571 526,959 NR/NR Illinois Finance Authority, 11/15/52 (d) 179,198 7,000,000 NR/NR Illinois Finance Authority, 5.625%, 2/15/37 6,157,130 2,165,000 NR/NR Illinois Finance Authority, 6.0%, 5/15/43 1,716,542 485,000 NR/NR Illinois Finance Authority, 7.0%, 11/15/17 474,946 970,000 NR/NR Illinois Finance Authority, 7.0%, 11/15/27 864,639 770,000 NR/NR Illinois Finance Authority, 7.0%, 11/15/27 731,431 5,085,000 NR/NR Illinois Finance Authority, 7.625%, 5/15/25 5,365,234 1,750,000 NR/NR Illinois Finance Authority, 8.0%, 5/15/30 1,698,812 3,295,000 NR/NR Illinois Finance Authority, 8.0%, 5/15/40 3,446,998 965,000 NR/NR Illinois Finance Authority, 8.0%, 5/15/46 1,006,852 17,000,000 NR/NR Illinois Finance Authority, 8.125%, 2/15/40 16,514,310 2,250,000 BB/NR Illinois Finance Authority, 8.125%, 5/15/40 2,155,320 7,275,000 NR/NR Illinois Finance Authority, 8.25%, 2/15/46 7,118,006 11,135,000 BB/NR Illinois Finance Authority, 8.25%, 5/15/45 10,798,946 4,213,653 4.00 NR/NR Illinois Finance Authority, Floating Rate Note, 11/15/52 2,247,647 2,950,000 NR/NR Southwestern Illinois Development Authority, 5.625%, 11/1/26 2,298,316 2,500,000 NR/NR Southwestern Illinois Development Authority, 6.625%, 6/1/37 2,118,000 ------------- $ 65,114,055 ----------------------------------------------------------------------------------------------------------- Indiana -- 5.8% 1,000,000 NR/NR City of Carmel Indiana, 6.0%, 11/15/22 $ 962,300 1,550,000 NR/NR City of Carmel Indiana, 7.0%, 11/15/27 1,551,860 1,750,000 NR/NR City of Carmel Indiana, 7.0%, 11/15/32 1,717,188 6,000,000 NR/NR City of Carmel Indiana, 7.125%, 11/15/42 5,823,660 5,950,000 NR/NR City of Carmel Indiana, 7.125%, 11/15/47 5,724,971 3,500,000 NR/NR City of Crown Point Indiana, 8.0%, 11/15/39 3,762,325 4,575,000 NR/NR City of Terre Haute Indiana, 6.0%, 8/1/39 3,955,545 2,435,000 NR/NR County of St. Joseph Indiana, 6.0%, 5/15/38 2,343,809 2,340,000 NR/NR Vigo County Hospital Authority, 5.8%, 9/1/47 (144A) 2,281,664 The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 17 Schedule of Investments | 8/31/13 (continued) ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Indiana -- (continued) 4,000,000 BB/NR Vigo County Hospital Authority, 8.0%, 9/1/41 $ 4,551,600 ------------- $ 32,674,922 ----------------------------------------------------------------------------------------------------------- Iowa -- 0.8% 1,315,000 NR/NR Iowa Finance Authority, 5.0%, 11/15/21 $ 854,224 1,445,000 NR/NR Iowa Finance Authority, 5.5%, 11/15/27 926,317 4,365,000 BB/NR Iowa Finance Authority, 5.5%, 11/15/37 2,754,009 ------------- $ 4,534,550 ----------------------------------------------------------------------------------------------------------- Louisiana -- 2.5% 9,635,000 NR/NR Louisiana Public Facilities Authority, 9.75%, 8/1/14 $ 9,557,631 5,800,000 NR/NR Tensas Parish Law Enforcement District, 8.5%, 10/1/26 (c) 4,621,382 ------------- $ 14,179,013 ----------------------------------------------------------------------------------------------------------- Maryland -- 0.6% 4,115,000 NR/NR County of Howard Maryland, 5.25%, 4/1/27 $ 3,631,529 ----------------------------------------------------------------------------------------------------------- Massachusetts -- 1.2% 1,116,746 NR/NR Massachusetts Development Finance Agency, 11/15/56 (d) $ 6,243 224,523 NR/NR Massachusetts Development Finance Agency, 5.5%, 11/15/46 154,297 1,235,770 NR/NR Massachusetts Development Finance Agency, 6.25%, 11/15/26 1,070,696 2,224,798 NR/NR Massachusetts Development Finance Agency, 6.25%, 11/15/39 1,764,732 751,584 NR/NR Massachusetts Development Finance Agency, 6.25%, 11/15/46 579,997 2,000,000 NR/NR Massachusetts Development Finance Agency, 6.75%, 10/15/37 2,012,620 2,500,000 NR/NR Massachusetts Development Finance Agency, 7.25%, 6/1/16 (c) 167,500 500,000 NR/NR Massachusetts Development Finance Agency, 7.5%, 6/1/29 (c) 34,500 880,000 NR/NR Massachusetts Development Finance Agency, 7.625%, 10/15/37 930,776 2,000,000 NR/NR Massachusetts Development Finance Agency, 7.875%, 6/1/44 (c) 138,000 3,500,000 NR/NR Massachusetts Health & Educational Facilities Authority, 6.5%, 1/15/38 (c) 12,985 ------------- $ 6,872,346 ----------------------------------------------------------------------------------------------------------- Michigan -- 4.8% 5,485,000 BBB-/NR Flint International Academy, 5.75%, 10/1/37 $ 5,094,084 4,560,000 NR/NR Michigan Public Educational Facilities Authority, 5.875%, 6/1/37 3,974,268 The accompanying notes are an integral part of these financial statements. 18 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Michigan -- (continued) 290,000 BB/NR Michigan Public Educational Facilities Authority, 7.25%, 4/1/20 $ 303,453 2,020,000 BB/NR Michigan Public Educational Facilities Authority, 8.0%, 4/1/40 2,109,829 1,750,000 NR/NR Michigan State Hospital Finance Authority, 5.5%, 11/15/35 1,463,035 3,175,000 NR/NR Michigan Strategic Fund, 7.25%, 1/1/39 3,225,165 4,000,000 6.62 NR/NR Michigan Strategic Fund, Floating Rate Note, 11/1/41 3,846,880 7,135,000 6.75 A/A2 Michigan Strategic Fund, Floating Rate Note, 3/1/40 7,160,757 ------------- $ 27,177,471 ----------------------------------------------------------------------------------------------------------- Minnesota -- 2.3% 10,000,000 NR/NR Bloomington Port Authority, 9.0%, 12/1/35 $ 11,072,700 1,500,000 NR/NR City of Brooklyn Park Minnesota, 9.25%, 3/1/39 1,646,910 ------------- $ 12,719,610 ----------------------------------------------------------------------------------------------------------- Missouri -- 2.3% 6,090,000 BB/NR Community Memorial Hospital District, 6.68%, 12/1/34 $ 5,734,527 4,500,000 NR/NR Kirkwood Industrial Development Authority, 8.25%, 5/15/45 4,956,615 2,125,000 NR/NR St. Louis County Industrial Development Authority, 6.125%, 8/15/42 1,897,306 500,000 NR/Ca St. Louis Industrial Development Authority, 7.2%, 12/15/28 (c) 164,975 1,365,000 NR/Ca St. Louis Industrial Development Authority, 7.25%, 12/15/35 (c) 450,382 ------------- $ 13,203,805 ----------------------------------------------------------------------------------------------------------- New Jersey -- 1.0% 6,000,000 NR/NR New Jersey Economic Development Authority, 6.625%, 1/1/37 $ 5,729,100 ----------------------------------------------------------------------------------------------------------- New York -- 3.5% 6,930,000 NR/NR The Erie County Industrial Development Agency, 6.0%, 11/15/36 $ 6,060,978 8,000,000 NR/NR The Erie County Industrial Development Agency, 9.25%, 10/1/30 4,236,320 10,000,000 NR/NR The Erie County Industrial Development Agency, 9.25%, 10/1/30 5,295,400 1,795,000 NR/NR The Erie County Industrial Development Agency, 9.25%, 10/1/30 950,524 4,000,000 BB+/NR Westchester Tobacco Asset Securitization New York, 5.125%, 6/1/45 3,026,360 ------------- $ 19,569,582 ----------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 19 Schedule of Investments | 8/31/13 (continued) ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- North Carolina -- 1.2% 1,665,000 NR/NR North Carolina Medical Care Commission, 7.75%, 3/1/31 $ 1,762,269 4,725,000 NR/NR North Carolina Medical Care Commission, 7.75%, 3/1/41 4,934,696 ------------- $ 6,696,965 ----------------------------------------------------------------------------------------------------------- Pennsylvania -- 4.3% 1,400,000 BB+/NR Allegheny County Industrial Development Authority, 6.0%, 7/15/38 $ 1,170,176 4,800,000 B-/Caa2 Pennsylvania Economic Development Financing Authority, 6.0%, 6/1/31 4,636,944 2,005,000 CCC+/Caa3 Pennsylvania Economic Development Financing Authority, 7.5%, 5/1/20 2,160,087 8,575,000 CCC+/Caa3 Pennsylvania Economic Development Financing Authority, 8.0%, 5/1/29 9,495,269 1,000,000 BB-/NR Philadelphia Authority for Industrial Development, 6.5%, 6/15/33 (144A) 970,670 1,000,000 BB+/NR Philadelphia Authority for Industrial Development, 6.625%, 12/15/41 1,001,760 5,000,000 BB-/NR Philadelphia Authority for Industrial Development, 6.75%, 6/15/43 (144A) 4,834,650 ------------- $ 24,269,556 ----------------------------------------------------------------------------------------------------------- Rhode Island -- 1.9% 2,085,000 NR/NR Central Falls Detention Facility Corp., 7.25%, 7/15/35 $ 1,593,816 8,100,000 NR/NR Rhode Island Health & Educational Building Corp., 8.375%, 1/1/46 8,959,005 ------------- $ 10,552,821 ----------------------------------------------------------------------------------------------------------- Texas -- 20.2% 10,125,000 5.40 CC/C Brazos River Authority, Floating Rate Note, 10/1/29 $ 1,315,642 234,442 NR/NR Gulf Coast Industrial Development Authority, 7.0%, 12/1/36 (c) 2,108 9,685,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/31 (d) 2,927,485 7,635,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/32 (d) 2,141,083 1,120,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/33 (d) 291,670 765,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/34 (d) 185,245 1,690,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/35 (d) 379,490 425,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/35 (d) 95,434 The accompanying notes are an integral part of these financial statements. 20 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Texas -- (continued) 10,000,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/38 (d) $ $ 1,791,000 10,000,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/39 (d) 1,672,900 1,290,000 A/Baa1 Harris County-Houston Sports Authority, 11/15/41 (d) 207,148 345,000 NR/NR HFDC of Central Texas, Inc., 6.375%, 11/15/19 305,422 1,600,000 NR/NR HFDC of Central Texas, Inc., 7.75%, 11/15/29 1,119,264 6,825,000 NR/NR HFDC of Central Texas, Inc., 7.75%, 11/15/44 4,711,434 24,000,000 NR/NR Jefferson County Industrial Development Corp. Texas, 8.25%, 7/1/32 24,477,113 1,520,000 BB/NR Kinney County Public Facilities Corp., 7.0%, 11/1/25 1,418,434 3,820,000 NR/NR Red River Health Facilities Development Corp., 12.0%, 12/14/17 3,665,099 5,000,000 NR/NR Red River Health Facilities Development Corp., 7.25%, 12/15/47 4,661,050 2,000,000 NR/NR Red River Health Facilities Development Corp., 8.0%, 11/15/46 2,101,040 24,000,000 NR/NR Sanger Industrial Development Corp., 8.0%, 7/1/38 23,702,880 1,130,000 BB/Ba Tarrant County Cultural Education Facilities Finance Corp., 7.5%, 11/15/16 1,131,526 1,775,000 BB/NR Tarrant County Cultural Education Facilities Finance Corp., 8.0%, 11/15/28 1,854,698 2,250,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.0%, 11/15/29 2,358,338 120,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.0%, 11/15/34 126,545 5,000,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.125%, 11/15/39 5,214,750 8,350,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.125%, 11/15/44 8,800,984 5,000,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.25%, 11/15/44 5,225,300 5,000,000 NR/NR Tarrant County Cultural Education Facilities Finance Corp., 8.25%, 11/15/44 5,222,750 1,000,000 NR/NR Texas Midwest Public Facility Corp., 9.0%, 10/1/30 (c) 456,140 7,000,000 NR/NR Travis County Health Facilities Development Corp., 7.125%, 1/1/46 6,618,710 ------------- $ 114,180,682 ----------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 21 Schedule of Investments | 8/31/13 (continued) ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- Utah -- 2.2% 825,000 BB/NR City of Spanish Fork City Utah, 5.55%, 11/15/21 (144A) $ 801,133 3,150,000 NR/NR City of Spanish Fork City Utah, 5.7%, 11/15/36 (144A) 2,657,781 1,510,000 NR/NR Utah State Charter School Finance Authority, 7.25%, 5/15/21 1,559,604 1,985,000 NR/NR Utah State Charter School Finance Authority, 8.125%, 5/15/31 2,056,857 5,145,000 NR/NR Utah State Charter School Finance Authority, 8.5%, 5/15/41 5,428,798 ------------- $ 12,504,173 ----------------------------------------------------------------------------------------------------------- Washington -- 4.3% 1,435,000 NR/NR Washington State Housing Finance Commission, 5.25%, 1/1/17 $ 1,401,708 8,500,000 NR/NR Washington State Housing Finance Commission, 5.625%, 1/1/27 7,660,030 9,160,000 NR/NR Washington State Housing Finance Commission, 5.625%, 1/1/38 7,687,622 8,000,000 NR/NR Washington State Housing Finance Commission, 6.75%, 10/1/47 7,812,000 ------------- $ 24,561,360 ----------------------------------------------------------------------------------------------------------- West Virginia -- 6.7% 25,000,000 NR/NR City of Philippi West Virginia, 7.75%, 10/1/44 $ 23,446,500 12,000,000 NR/NR West Virginia Hospital Finance Authority, 9.125%, 10/1/41 14,262,960 ------------- $ 37,709,460 ----------------------------------------------------------------------------------------------------------- Wisconsin -- 7.6% 14,382,500 NR/NR Public Finance Authority, 7.0%, 10/1/42 $ 12,989,986 10,325,000 NR/NR Public Finance Authority, 8.25%, 6/1/46 11,270,770 8,750,000 NR/NR Public Finance Authority, 8.375%, 6/1/20 8,761,638 2,480,000 NR/NR Public Finance Authority, 8.375%, 6/1/37 2,517,002 7,250,000 NR/NR Public Finance Authority, 8.625%, 6/1/47 7,438,210 ------------- $ 42,977,606 ----------------------------------------------------------------------------------------------------------- TOTAL MUNICIPAL BONDS (Cost $635,185,441) $ 626,456,787 ----------------------------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. 22 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 ----------------------------------------------------------------------------------------------------------- Floating S&P/Moody's Principal Rate (b) Ratings Amount ($) (unaudited) (unaudited) Value ----------------------------------------------------------------------------------------------------------- MUNICIPAL COLLATERALIZED DEBT OBLIGATION -- 0.1% 1,175,000 0.00 NR/NR Non-Profit Preferred Funding Trust I, Floating Rate Note, 9/15/37 (144A) $ 635,393 TOTAL MUNICIPAL COLLATERALIZED DEBT OBLIGATION (Cost $1,172,407) $ 635,393 ----------------------------------------------------------------------------------------------------------- TOTAL INVESTMENT IN SECURITIES -- 111.0% (Cost $636,357,848) (a) (e) $ 627,092,180 ----------------------------------------------------------------------------------------------------------- OTHER ASSETS & LIABILITIES -- (11.0)% $ (61,981,642) ----------------------------------------------------------------------------------------------------------- TOTAL NET ASSETS -- 100.0% $ 565,110,538 =========================================================================================================== NR Not rated by either S&P or Moody's. (144A) Security is exempt from registration under Rule 144A of the Securities Act of 1933. Such securities may be resold normally to qualified institutional buyers in a transaction exempt from registration. At August 31, 2013, the value of these securities amounted to $13,631,291 or 2.4% of total net assets. (a) At August 31, 2013, the net unrealized depreciation on investments based on cost for federal income tax purposes of $635,852,575 was as follows: Aggregate gross unrealized appreciation for all investments in which there is an excess of value over tax cost $30,941,301 Aggregate gross unrealized depreciation for all investments in which there is an excess of tax cost over value (39,701,696) ----------- Net unrealized depreciation $(8,760,395) =========== (b) Debt obligation with a variable interest rate. Rate shown is rate at end of period. (c) Security is in default and is non-income producing. (d) Security issued with a zero coupon. Income is earned through accretion of discount. (e) The concentration of investments by type of obligation/market sector is as follows: Revenue Bonds: Health 50.8% Pollution Control Revenue 16.3 Education 12.5 Various Revenues 7.6 Special Revenues 4.7 Transportation 4.2 Housing 2.0 Insured 1.8 General Obligation 0.1 -------------------------------------------------------------------------------- 100.0% ================================================================================ The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 23 Schedule of Investments | 8/31/13 (continued) Purchases and sales of securities (excluding temporary cash investments) for the year ended August 31, 2013 aggregated $130,505,682 and $234,373,300, respectively. Various inputs are used in determining the value of the Fund's investments. These inputs are summarized in the three broad levels listed below. Level 1 - quoted prices in active markets for identical securities Level 2 - other significant observable inputs (including quoted prices for similar securities, interest rates, prepayment speeds, credit risk, etc.) See Notes to Financial Statements -- Note 1A. Level 3 - significant unobservable inputs (including the Fund's own assumptions in determining fair value of investments) See Notes to Financial Statements -- Note 1A. Generally, equity securities are categorized as Level 1, fixed income securities and senior loans as Level 2 and securities valued using fair value methods (other than prices supplied by independent pricing services) as Level 3. See Notes to Financial Statements -- Note 1A. The following is a summary of the inputs used as of August 31, 2013, in valuing the Fund's investments: ---------------------------------------------------------------------------------------------- Level 1 Level 2 Level 3 Total ---------------------------------------------------------------------------------------------- Municipal Bonds $ -- $626,456,787 $ -- $626,456,787 Municipal Collateralized Debt Obligation -- 635,393 -- 635,393 ---------------------------------------------------------------------------------------------- Total $ -- $627,092,180 $ -- $627,092,180 ============================================================================================== During the year ended August 31, 2013, there were no transfers between Levels 1, 2 and 3. The accompanying notes are an integral part of these financial statements. 24 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Statement of Assets and Liabilities | 8/31/13 ASSETS: Investment in securities, at value (cost $636,357,848) $627,092,180 Receivables -- Investment securities sold 2,860,097 Fund shares sold 1,608,124 Interest 14,870,971 Other 50,692 -------------------------------------------------------------------------------- Total assets $646,482,064 ================================================================================ LIABILITIES: Payables -- Investment securities purchased $ 3,000,000 Due to custodian 667,653 Fund shares repurchased 7,364,858 Dividends 731,789 Loan payable 69,300,000 Due to affiliates 150,342 Accrued expenses 156,884 -------------------------------------------------------------------------------- Total liabilities $ 81,371,526 ================================================================================ NET ASSETS: Paid-in capital $620,951,358 Undistributed net investment income 9,245,949 Accumulated net realized loss on investments (55,821,101) Net unrealized depreciation on investments (9,265,668) -------------------------------------------------------------------------------- Total net assets $565,110,538 ================================================================================ NET ASSET VALUE PER SHARE: (No par value, unlimited number of shares authorized) Class A (based on $250,162,724/34,809,029 shares) $ 7.19 Class C (based on $195,289,791/27,165,418 shares) $ 7.19 Class Y (based on $119,658,023/16,864,820 shares) $ 7.10 MAXIMUM OFFERING PRICE: Class A ($7.19 (divided by) 95.5%) $ 7.53 ================================================================================ The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 25 Statement of Operations For the Year Ended 8/31/13 INVESTMENT INCOME: Interest $57,001,489 ------------------------------------------------------------------------------------------------- Total investment income $ 57,001,489 ------------------------------------------------------------------------------------------------- EXPENSES: Management fees $ 3,916,880 Transfer agent fees Class A 59,925 Class C 27,100 Class Y 5,370 Distribution fees Class A 874,744 Class C 2,637,183 Shareholder communications expense 557,449 Administrative reimbursement 230,181 Custodian fees 10,114 Registration fees 140,763 Professional fees 74,117 Printing expense 37,991 Fees and expenses of nonaffiliated Trustees 31,059 Miscellaneous 85,970 ------------------------------------------------------------------------------------------------- Total expenses $ 8,688,846 ------------------------------------------------------------------------------------------------- Net investment income $ 48,312,643 ------------------------------------------------------------------------------------------------- REALIZED AND UNREALIZED GAIN (LOSS) ON INVESTMENTS: Net realized gain on investments $ 15,135,141 ------------------------------------------------------------------------------------------------- Change in net unrealized depreciation on investments $(86,344,407) ------------------------------------------------------------------------------------------------- Net loss on investments $(71,209,266) ------------------------------------------------------------------------------------------------- Net decrease in net assets resulting from operations $(22,896,623) ================================================================================================= The accompanying notes are an integral part of these financial statements. 26 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Statements of Changes in Net Assets --------------------------------------------------------------------------------------- Year Ended Year Ended 8/31/13 8/31/12 --------------------------------------------------------------------------------------- FROM OPERATIONS: Net investment income $ 48,312,643 $ 46,755,657 Net realized gain (loss) on investments 15,135,141 (48,600,216) Change in net unrealized appreciation (depreciation) on investments (86,344,407) 74,917,059 --------------------------------------------------------------------------------------- Net increase (decrease) in net assets resulting from operations $ (22,896,623) $ 73,072,500 --------------------------------------------------------------------------------------- DISTRIBUTIONS TO SHAREOWNERS: Net investment income: Class A ($0.44 and $0.45 per share, respectively) $ (19,349,016) $ (21,800,656) Class C ($0.38 and $0.40 per share, respectively) (12,640,678) (12,938,091) Class Y ($0.45 and $0.46 per share, respectively) (10,604,265) (10,347,762) --------------------------------------------------------------------------------------- Total distributions to shareowners $ (42,593,959) $ (45,086,509) --------------------------------------------------------------------------------------- FROM FUND SHARE TRANSACTIONS: Net proceeds from sale of shares $ 259,833,657 $ 357,337,828 Reinvestment of distributions 32,589,669 32,534,258 Cost of shares repurchased (476,972,507) (424,526,655) --------------------------------------------------------------------------------------- Net decrease in net assets resulting from Fund share transactions $ (184,549,181) $ (34,654,569) --------------------------------------------------------------------------------------- Net decrease in net assets $ (250,039,763) $ (6,668,578) NET ASSETS: Beginning of year 815,150,301 821,818,879 --------------------------------------------------------------------------------------- End of year $ 565,110,538 $ 815,150,301 --------------------------------------------------------------------------------------- Undistributed net investment income $ 9,245,949 $ 2,968,496 --------------------------------------------------------------------------------------- The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 27 Statements of Changes in Net Assets (continued) ----------------------------------------------------------------------------------------------- '13 Shares '13 Amount '12 Shares '12 Amount ----------------------------------------------------------------------------------------------- Class A Shares sold 14,993,517 $ 120,667,855 24,812,011 $ 186,195,866 Reinvestment of distributions 1,982,918 15,747,383 2,268,621 16,933,920 Less shares repurchased (29,176,427) (231,678,201) (30,082,711) (221,684,126) ----------------------------------------------------------------------------------------------- Net decrease (12,199,992) $ (95,262,963) (3,002,079) $ (18,554,340) =============================================================================================== Class C Shares sold 5,733,047 $ 46,286,122 10,210,281 $ 76,722,170 Reinvestment of distributions 1,208,628 9,597,190 1,182,530 8,840,084 Less shares repurchased (13,216,214) (103,481,378) (10,256,515) (75,810,384) ----------------------------------------------------------------------------------------------- Net increase (decrease) (6,274,539) $ (47,598,066) 1,136,296 $ 9,751,870 =============================================================================================== Class Y Shares sold 11,686,311 $ 92,879,680 12,738,784 $ 94,419,792 Reinvestment of distributions 921,213 7,245,096 914,996 6,760,254 Less shares repurchased (18,272,467) (141,812,928) (17,562,747) (127,032,145) ----------------------------------------------------------------------------------------------- Net decrease (5,664,943) $ (41,688,152) (3,908,967) $ (25,852,099) =============================================================================================== The accompanying notes are an integral part of these financial statements. 28 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Financial Highlights --------------------------------------------------------------------------------------------------------------------------- Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 --------------------------------------------------------------------------------------------------------------------------- Class A Net asset value, beginning of period $ 7.94 $ 7.58 $ 7.97 $ 6.84 $ 8.70 --------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.53 $ 0.47 $ 0.53 $ 0.55 $ 0.56 Net realized and unrealized gain (loss) on investments (0.84) 0.34 (0.40) 1.12 (1.86) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net assets from investment operations $ (0.31) $ 0.81 $ 0.13 $ 1.67 $ (1.30) --------------------------------------------------------------------------------------------------------------------------- Distributions to shareowners: Net investment income (0.44) (0.45) (0.52) (0.55) (0.56) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (0.75) $ 0.36 $ (0.39) $ 1.12 $ (1.86) --------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 7.19 $ 7.94 $ 7.58 $ 7.97 $ 6.84 =========================================================================================================================== Total return* (4.26)% 11.24% 1.83% 25.15% (14.41)% Ratio of net expenses to average net assets+ 0.88% 0.89% 0.88% 0.90% 0.90% Ratio of net investment income to average net assets+ 6.26% 6.25% 6.98% 7.08% 8.32% Portfolio turnover rate 17% 54% 65% 15% 50% Net assets, end of period (in thousands) $250,163 $373,039 $378,883 $311,324 $38,312 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 0.88% 0.89% 0.88% 0.95% 1.28% Net investment income 6.26% 6.25% 6.98% 7.03% 7.95% =========================================================================================================================== * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratio with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 29 Financial Highlights (continued) --------------------------------------------------------------------------------------------------------------------------- Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 --------------------------------------------------------------------------------------------------------------------------- Class C Net asset value, beginning of period $ 7.94 $ 7.58 $ 7.96 $ 6.83 $ 8.68 --------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.46 $ 0.41 $ 0.47 $ 0.49 $ 0.50 Net realized and unrealized gain (loss) on investments (0.83) 0.35 (0.39) 1.12 (1.85) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net assets from investment operations $ (0.37) $ 0.76 $ 0.08 $ 1.61 $ (1.35) --------------------------------------------------------------------------------------------------------------------------- Distributions to shareowners: Net investment income (0.38) (0.40) (0.46) (0.48) (0.50) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (0.75) $ 0.36 $ (0.38) $ 1.13 $ (1.85) --------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 7.19 $ 7.94 $ 7.58 $ 7.96 $ 6.83 =========================================================================================================================== Total return* (4.98)% 10.42% 1.19% 24.11% (15.17)% Ratio of net expenses to average net assets+ 1.63% 1.63% 1.63% 1.69% 1.80% Ratio of net investment income to average net assets+ 5.53% 5.50% 6.24% 6.31% 7.44% Portfolio turnover rate 17% 54% 65% 15% 50% Net assets, end of period (in thousands) $195,290 $265,448 $244,848 $184,068 $22,319 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 1.63% 1.63% 1.63% 1.69% 1.98% Net investment income 5.53% 5.50% 6.24% 6.31% 7.26% =========================================================================================================================== * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions, the complete redemption of the investment at net asset value at the end of each period and no sales charges. Total return would be reduced if sales charges were taken into account. + Ratio with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. 30 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 --------------------------------------------------------------------------------------------------------------------------- Year Year Year Year Year Ended Ended Ended Ended Ended 8/31/13 8/31/12 8/31/11 8/31/10 8/31/09 --------------------------------------------------------------------------------------------------------------------------- Class Y Net asset value, beginning of period $ 7.84 $ 7.49 $ 7.88 $ 6.80 $ 8.63 --------------------------------------------------------------------------------------------------------------------------- Increase (decrease) from investment operations: Net investment income $ 0.53 $ 0.48 $ 0.53 $ 0.57 $ 0.55 Net realized and unrealized gain (loss) on investments (0.82) 0.33 (0.39) 1.08 (1.83) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net assets from investment operations $ (0.29) $ 0.81 $ 0.14 $ 1.65 $ (1.28) --------------------------------------------------------------------------------------------------------------------------- Distributions to shareowners: Net investment income (0.45) (0.46) (0.53) (0.56) (0.55) --------------------------------------------------------------------------------------------------------------------------- Net increase (decrease) in net asset value $ (0.74) $ 0.35 $ (0.39) $ 1.09 $ (1.83) --------------------------------------------------------------------------------------------------------------------------- Net asset value, end of period $ 7.10 $ 7.84 $ 7.49 $ 7.88 $ 6.80 =========================================================================================================================== Total return* (4.05)% 11.43% 2.02% 24.73% (14.30)% Ratio of net expenses to average net assets+ 0.72% 0.67% 0.67% 0.67% 0.99% Ratio of net investment income to average net assets+ 6.40% 6.46% 7.21% 7.32% 8.23% Portfolio turnover rate 17% 54% 65% 15% 50% Net assets, end of period (in thousands) $119,658 $176,664 $198,089 $77,757 $ 2,317 Ratios with no waiver of fees and assumption of expenses by the Adviser and no reduction for fees paid indirectly: Total expenses 0.72% 0.67% 0.67% 0.67% 1.04% Net investment income 6.40% 6.46% 7.21% 7.32% 8.18% =========================================================================================================================== * Assumes initial investment at net asset value at the beginning of each period, reinvestment of all distributions and the complete redemption of the investment at net asset value at the end of each period. + Ratio with no reduction for fees paid indirectly. The accompanying notes are an integral part of these financial statements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 31 Notes to Financial Statements | 8/31/13 1. Organization and Significant Accounting Policies Pioneer High Income Municipal Fund (the Fund) is one of two portfolios comprising Pioneer Series Trust V, a Delaware statutory trust. The Fund is registered under the Investment Company Act of 1940 as an open-end management investment company. The Fund is non-diversified. The investment objective of the Fund is to maximize total return through a combination of income that is exempt from regular federal income tax and capital appreciation. The Fund offers three classes of shares designated as Class A, Class C and Class Y shares. Each class of shares represents an interest in the same portfolio of investments of the Fund and has identical rights (based on relative net asset values) to assets and liquidation proceeds. Share classes can bear different rates of class-specific fees and expenses such as transfer agent and distribution fees. Differences in class-specific fees and expenses will result in differences in net investment income and, therefore, the payment of different dividends from net investment income earned by each class. The Amended and Restated Declaration of Trust of the Fund gives the Board the flexibility to specify either per share voting or dollar-weighted voting when submitting matters for shareholder approval. Under per share voting, each share of a class of the Fund is entitled to one vote. Under dollar-weighted voting, a shareholder's voting power is determined not by the number of shares owned, but by the dollar value of the shares on the record date. Each share class has exclusive voting rights with respect to matters affecting only that class, including with respect to the distribution plan for that class. There is no distribution plan for Class Y shares. The Fund's financial statements have been prepared in conformity with U.S. generally accepted accounting principles that require the management of the Fund to, among other things, make estimates and assumptions that affect the reported amounts of assets and liabilities, the disclosure of contingent assets and liabilities at the date of the financial statements, and the reported amounts of income, expenses, and gain or loss on investments during the reporting period. Actual results could differ from those estimates. The following is a summary of significant accounting policies followed by the Fund in the preparation of its financial statements which are consistent with those policies generally accepted in the investment company industry: 32 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 A. Security Valuation Security transactions are recorded as of trade date. The net asset value of the Fund is computed once daily, on each day the New York Stock Exchange (NYSE) is open, as of the close of regular trading on the NYSE. Fixed income securities with remaining maturity of more than sixty days are valued at prices supplied by independent pricing services, which consider such factors as market prices, market events, quotations from one or more brokers, Treasury spreads, yields, maturities and ratings. Valuations may be supplemented by dealers and other sources, as required. Short-term fixed income securities with remaining maturities of sixty days or less generally are valued at amortized cost. Securities for which independent pricing services are unable to supply prices or for which market prices and/or quotations are not readily available or are considered to be unreliable are valued at the direction or with the approval of the Valuation Committee using fair value methods pursuant to procedures adopted by the Board of Trustees. Inputs used when applying fair value methods to value a security may include credit ratings, the financial condition of the company, current market conditions and comparable securities. The Valuation Committee is comprised of certain members of the Board of Trustees. The Fund may use fair value methods if it is determined that a significant event has occurred after the close of the exchange or market on which the security trades and prior to the determination of the Fund's net asset value. Examples of a significant event might include political or economic news, corporate restructurings, natural disasters, terrorist activity or trading halts. Thus, the valuation of the Fund's securities may differ significantly from exchange prices and such differences could be material. Pioneer Investment Management, Inc. (PIM), the Fund's investment advisor, is responsible for monitoring developments that may impact fair valued securities and for discussing and assessing fair values on an ongoing basis, and at least quarterly, with the Valuation Committee. At August 31, 2013, there were no securities that were valued using fair value methods (other than securities valued using prices supplied by independent pricing services). Discount and premium on debt securities are accreted or amortized, respectively, daily into interest income on a yield-to-maturity basis with a corresponding increase or decrease in the cost basis of the security. Interest income is recorded on the accrual basis. Gains and losses on sales of investments are calculated on the identified cost method for both financial reporting and federal income tax purposes. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 33 B. Federal Income Taxes It is the Fund's policy to comply with the requirements of the Internal Revenue Code applicable to regulated investment companies and to distribute all of its taxable income and net realized capital gains, if any, to its shareowners. Therefore, no provision for federal income taxes is required. As of August 31, 2013, the Fund had not accrued any interest and penalties with respect to uncertain tax positions, which, if applicable, would be recorded as an income tax expense in the Statement of Operations. Tax returns filed within the prior three years remain subject to examination by Federal and State tax authorities. The amount and character of income and capital gain distributions to shareowners are determined in accordance with federal income tax rules, which may differ from U.S. generally accepted accounting principles. Distributions in excess of net investment income or net realized gains are temporary overdistributions for financial statement purposes resulting from differences in the recognition or classification of income or distributions for financial statement and tax purposes. Capital accounts within the financial statements are adjusted for permanent book/tax differences to reflect tax character, but are not adjusted for temporary differences. At August 31, 2013, the Fund reclassified $558,769 to increase undistributed net investment income, and $558,769 to increase accumulated net realized loss on investments to reflect permanent book/tax differences. These adjustments have no impact on net assets or the results of operations. At August 31, 2013, the Fund was permitted to carry forward indefinitely $21,970,565 of short-term losses and $25,201,388 of long-term losses under the Regulated Investment Company Modernization Act of 2010 without limitation. Additionally, at August 31, 2013, the Fund had a net capital loss carryforward of $8,649,148 of which the following amounts will expire between 2017 and 2018 if not utilized: $2,640,380 in 2017 and $6,008,768 in 2018. Since new losses are required to be used first, loss carryforwards that are subject to expiration may be more likely to expire unused. The tax character of distributions paid during the years ended August 31, 2013 and August 31, 2012 was as follows: -------------------------------------------------------------------------------- 2013 2012 -------------------------------------------------------------------------------- Distributions paid from: Tax-exempt income $40,383,212 $42,419,842 Ordinary income 2,210,747 2,666,667 -------------------------------------------------------------------------------- Total $42,593,959 $45,086,509 ================================================================================ 34 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 The following shows the components of distributable earnings on a federal income tax-basis at August 31, 2013: -------------------------------------------------------------------------------- 2013 -------------------------------------------------------------------------------- Distributable earnings: Undistributed tax-exempt income $ 9,472,465 Capital loss carryforward (55,821,101) Dividend payable (731,789) Net unrealized depreciation (8,760,395) -------------------------------------------------------------------------------- Total $(55,840,820) ================================================================================ The difference between book-basis and tax-basis net unrealized depreciation is attributable to adjustments related to interest on defaulted bonds, the tax treatment of premium and amortization and tax-basis adjustments on partnerships. C. Fund Shares The Fund records sales and repurchases of its shares as of trade date. Pioneer Funds Distributor, Inc. (PFD), the principal underwriter for the Fund and a wholly owned indirect subsidiary of UniCredit S.p.A. (UniCredit), earned $130,874 in underwriting commissions on the sale of Class A shares during the year ended August 31, 2013. D. Class Allocations Income, common expenses and realized and unrealized gains and losses are calculated at the Fund level and allocated daily to each class of shares based on its respective percentage of adjusted net assets at the beginning of the day. Distribution fees are calculated based on the average daily net asset value attributable to Class A and Class C shares of the Fund, respectively (see Note 4). Class Y shares do not pay distribution fees. All expenses and fees paid to the transfer agent, Pioneer Investment Management Shareholder Services, Inc. (PIMSS), for its services are allocated among the classes of shares based on the number of accounts in each class and the ratable allocation of related out-of-pocket expenses (see Note 3). The Fund declares, as daily dividends, substantially all of its net investment income. All dividends are paid on a monthly basis. Short-term capital gain distributions, if any, may be declared with the daily dividends. Distributions to shareowners are recorded as of the ex-dividend date. Distributions paid by the Fund with respect to each class of shares are calculated in the same manner and at the same time, except that net investment income dividends to Class A, Class C, and Class Y shares can reflect different transfer agent and distribution expense rates. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 35 E. Risks At times, the Fund's investments may represent industries or industry sectors that are interrelated or have common risks, making the Fund more susceptible to any economic, political, or regulatory developments or other risks affecting those industries and sectors. The Fund's prospectus contains unaudited information regarding the Fund's principal risks. Please refer to that document when considering the Fund's principal risks. 2. Management Agreement PIM, a wholly owned indirect subsidiary of UniCredit, manages the Fund's portfolio. Management fees are calculated daily at the annual rate equal to 0.50% of the Fund's average daily net assets up to $500 million; 0.475% of the next $500 million of the Fund's average daily net assets and 0.45% of the Fund's average daily net assets over $1 billion. For the year ended August 31, 2013, the effective management fee (excluding waivers and/or assumption of expenses) was equivalent to 0.49% of the Fund's average daily net assets. PIM has contractually agreed to limit ordinary operating expenses (excluding taxes, commissions, interest and extraordinary expenses) of the Fund to the extent required to reduce Fund expenses to 0.90% and 1.80% of the average daily net assets attributable to Class A shares and Class C shares, respectively. Class Y shares do not have an expense limitation. These expense limitations are in effect through January 1, 2015. There can be no assurance that PIM will extend the expense limitation agreement for a class of shares beyond the date referred to above. In addition, under the management and administration agreements, certain other services and costs, including accounting, regulatory reporting and insurance premiums, are paid by the Fund as administrative reimbursements. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $29,931 in management fees, administrative costs and certain other reimbursements payable to PIM at August 31, 2013. 3. Transfer Agent PIMSS, a wholly owned indirect subsidiary of UniCredit, provides substantially all transfer agent and shareowner services to the Fund at negotiated rates. In addition, the Fund reimburses PIMSS for out-of-pocket expenses incurred by PIMSS related to shareholder communications activities such as proxy and statement mailings, outgoing phone calls and omnibus relationship contracts. For the year ended August 31, 2013, such out-of-pocket expenses by class of shares were as follows: 36 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 -------------------------------------------------------------------------------- Shareholder Communications: -------------------------------------------------------------------------------- Class A $146,771 Class C 124,928 Class Y 285,750 -------------------------------------------------------------------------------- Total $557,449 ================================================================================ Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $98,999 in transfer agent fees and out-of-pocket reimbursements payable to PIMSS at August 31, 2013. 4. Distribution Plan The Fund has adopted a Distribution Plan pursuant to Rule 12b-1 of the Investment Company Act of 1940 with respect to its Class A and Class C shares. Pursuant to the Plan, the Fund pays PFD 0.25% of the average daily net assets attributable to Class A shares as compensation for personal services and/or account maintenance services or distribution services with regard to Class A shares. Pursuant to the Plan, the Fund also pays PFD 1.00% of the average daily net assets attributable to Class C shares. The fee for Class C shares consists of a 0.25% service fee and a 0.75% distribution fee paid as compensation for personal services and/or account maintenance services or distribution services with regard to Class C shares. Included in "Due to affiliates" reflected on the Statement of Assets and Liabilities is $21,412 in distribution fees payable to PFD at August 31, 2013. In addition, redemptions of each class of shares (except Class Y shares) may be subject to a contingent deferred sales charge (CDSC). A CDSC of 1.00% may be imposed on redemptions of certain net asset value purchases of Class A shares within 12 months of purchase. Redemptions of Class C shares within 12 months of purchase are subject to a CDSC of 1.00%, based on the lower of cost or market value of shares being redeemed. Shares purchased as part of an exchange remain subject to any CDSC that applied to the original purchase of those shares. There is no CDSC for Class Y shares. Proceeds from the CDSCs are paid to PFD. For the year ended August 31, 2013, CDSCs in the amount of $93,541 were paid to PFD. 5. Expense Offset Arrangements The Fund has entered into certain expense offset arrangements with PIMSS which may result in a reduction in the Fund's total expenses due to interest earned on cash held by PIMSS. For the year ended August 31, 2013, the Fund's expenses were not reduced under such arrangements. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 37 6. Line of Credit Facility The Fund, along with certain other funds in the Pioneer Family of Funds (the Funds), participates in a committed, unsecured revolving line of credit facility. Borrowings are used solely for temporary or emergency purposes. The Fund may borrow up to the lesser of the amount available under the facility or the limits set for borrowing by the Fund's prospectus and the 1940 Act. The credit facility is in the amount of $215 million. Under such facility, depending on the type of loan, interest on borrowings is payable at the London Interbank Offered Rate (LIBOR) plus 0.90% on an annualized basis, or the Alternate Base Rate, which is the greater of (a) the facility's administrative agent's daily announced prime rate on the borrowing date, (b) 2% plus the Federal Funds Rate on the borrowing date and (c) 2% plus the overnight Euro dollar rate on the borrowing date. The Funds pay an annual commitment fee to participate in the credit facility. The commitment fee is allocated among participating Funds based on an allocation schedule set forth in the credit agreement. For the year ended August 31, 2013, the average daily amount of borrowings outstanding during the period for the Fund was $38,501,471. The related weighted average annualized interest rate for the period was 0.99%, and the total interest expense on such borrowings was $71,696, which is included in miscellaneous expense, located on the Statement of Operations. As of August 31, 2013, borrowings outstanding were $69,300,000. 38 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Report of Independent Registered Public Accounting Firm To the Board of Trustees of Pioneer Series Trust V and the Shareowners of Pioneer High Income Municipal Fund: -------------------------------------------------------------------------------- We have audited the accompanying statement of assets and liabilities, including the schedule of investments, of Pioneer High Income Municipal Fund, one of the portfolios constituting Pioneer Series Trust V (the "Trust"), as of August 31, 2013, and the related statement of operations for the year then ended, the statements of changes in net assets for each of the two years in the period then ended, and the financial highlights for each of the five years in the period then ended. These financial statements and financial highlights are the responsibility of the Trust's management. Our responsibility is to express an opinion on these financial statements and financial highlights based on our audits. We conducted our audits in accordance with the standards of the Public Company Accounting Oversight Board (United States). Those standards require that we plan and perform the audit to obtain reasonable assurance about whether the financial statements and financial highlights are free of material misstatement. We were not engaged to perform an audit of the Trust's internal control over financial reporting. Our audits included consideration of internal control over financial reporting as a basis for designing audit procedures that are appropriate in the circumstances, but not for the purpose of expressing an opinion on the effectiveness of the Trust's internal control over financial reporting. Accordingly, we express no such opinion. An audit also includes examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements and financial highlights, assessing the accounting principles used and significant estimates made by management, and evaluating the overall financial statement presentation. Our procedures included confirmation of securities owned as of August 31, 2013 by correspondence with the custodian or others or by other appropriate auditing procedures where replies from others were not received. We believe that our audits provide a reasonable basis for our opinion. In our opinion, the financial statements and financial highlights referred to above present fairly, in all material respects, the financial position of Pioneer High Income Municipal Fund, one of the portfolios constituting Pioneer Series Trust V, at August 31, 2013, the results of its operations for the year then ended, the changes in its net assets for each of the two years in the period then ended, and the financial highlights for each of the five years in the period then ended, in conformity with U.S. generally accepted accounting principles. /s/ Ernst & Young LLP Boston, Massachusetts October 28, 2013 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 39 Trustees, Officers and Service Providers Investment Adviser Pioneer Investment Management, Inc. Custodian and Sub-Administrator Brown Brothers Harriman & Co. Independent Registered Public Accounting Firm Ernst & Young LLP Principal Underwriter Pioneer Funds Distributor, Inc. Legal Counsel Bingham McCutchen LLP Shareowner Services and Transfer Agent Pioneer Investment Management Shareholder Services, Inc. Proxy voting policies and procedures of the Funds are available without charge, upon request, by calling our toll free number (1-800-225-6292). Information regarding how the Funds voted proxies relating to portfolio securities during the most recent 12-month period ended June 30 is publicly available to share- owners at us.pioneerinvestments.com. This information is also available on the Securities and Exchange Commission's web site at www.sec.gov. Trustees and Officers The Fund's Trustees and Officers are listed on the following pages, together with their principal occupations during at least the past five years. Trustees who are interested persons of the Fund within the meaning of the 1940 Act are referred to as Interested Trustees. Trustees who are not interested persons of the Fund are referred to as Independent Trustees. Each of the Trustees, except Mr. Cogan and Mr. West, serves as a trustee of each of the 52 U.S. registered investment portfolios for which Pioneer serves as investment adviser (the "Pioneer Funds"). Each of Mr. Cogan and Mr. West serves as a Trustee of 47 Pioneer funds. The address for all Trustees and all officers of the Fund is 60 State Street, Boston, Massachusetts 02109. The Statement of Additional Information of the Fund includes additional information about the Trustees and is available, without charge, upon request, by calling 1-800-225-6292. 40 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Independent Trustees ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ Thomas J. Perna (62) Trustee since 2006. Chairman and Chief Executive Officer, Quadriserv, Director, Broadridge Financial Chairman of the Board Serves until a Inc. (technology products for securities lending Solutions, Inc. (investor and Trustee successor trustee industry) (2008 - present); private investor (2004 communications and securities is elected or - 2008); and Senior Executive Vice President, The processing provider for earlier retirement Bank of New York (financial and securities financial services industry) or removal. services) (1986 - 2004) (2009 - present); Director, Quadriserv, Inc. (2005 - present); and Commissioner, New Jersey State Civil Service Commission (2011 - present) ------------------------------------------------------------------------------------------------------------------------------------ David R. Bock (69) Trustee since 2005. Managing Partner, Federal City Capital Advisors Director of Enterprise Trustee Serves until a (corporate advisory services company) (1997 - 2004 Community Investment, Inc. successor trustee and 2008 - present); Interim Chief Executive (privately-held affordable is elected or Officer, Oxford Analytica, Inc. (privately held housing finance company) (1985 earlier retirement research and consulting company) (2010); Executive - 2010); Director of Oxford or removal. Vice President and Chief Financial Officer, Analytica, Inc. (2008 - I-trax, Inc. (publicly traded health care services present); Director of The company) (2004 - 2007); and Executive Vice Swiss Helvetia Fund, Inc. President and Chief Financial Officer, Pedestal (closed-end fund) (2010 - Inc. (internet-based mortgage trading company) present); and Director of New (2000 - 2002) York Mortgage Trust (publicly traded mortgage REIT) (2004 - 2009, 2012 - present) ------------------------------------------------------------------------------------------------------------------------------------ Benjamin M. Friedman (68) Trustee since 2008. William Joseph Maier Professor of Political Trustee, Mellon Institutional Trustee Serves until a Economy, Harvard University (1972 - present) Funds Investment Trust and successor trustee Mellon Institutional Funds is elected or Master Portfolio (oversaw 17 earlier retirement portfolios in fund complex) or removal. (1989-2008) ------------------------------------------------------------------------------------------------------------------------------------ Pioneer High Income Municipal Fund | Annual Report | 8/31/13 41 Independent Trustees (continued) ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ Margaret B.W. Graham (66) Trustee since 2005. Founding Director, Vice President and Corporate None Trustee Serves until a Secretary, The Winthrop Group, Inc. (consulting successor trustee firm) (1982-present); Desautels Faculty of is elected or Management, McGill University (1999 - present); earlier retirement and Manager of Research Operations and or removal. Organizational Learning, Xerox PARC, Xerox's advance research center (1990-1994) ------------------------------------------------------------------------------------------------------------------------------------ Marguerite A. Piret (65) Trustee since 2005. President and Chief Executive Officer, Newbury, Director of New America High Trustee Serves until a Piret & Company, Inc. (investment banking firm) Income Fund, Inc. (closed-end successor trustee (1981 - present) investment company) (2004 - is elected or present); and member, Board of earlier retirement Governors, Investment Company or removal. Institute (2000 - 2006) ------------------------------------------------------------------------------------------------------------------------------------ Stephen K. West (84) Trustee since 2005. Senior Counsel, Sullivan & Cromwell LLP (law Director, The Swiss Helvetia Trustee Serves until a firm) (1998 - present); and Partner, Sullivan & Fund, Inc. (closed-end successor trustee Cromwell LLP (prior to 1998) investment company); and is elected or Director, Invesco, Ltd. earlier retirement (formerly AMVESCAP, PLC) or removal. (investment manager) (1997-2005) ------------------------------------------------------------------------------------------------------------------------------------ 42 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 Interested Trustees ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Trustee ------------------------------------------------------------------------------------------------------------------------------------ John F. Cogan, Jr. (87)* Trustee since 2005. Non-Executive Chairman and a director of Pioneer None Trustee, President and Serves until a Investment Management USA Inc. ("PIM-USA"); Chairman Chief Executive Officer of successor trustee is and a director of Pioneer; Chairman and Director of the Fund elected or earlier Pioneer Institutional Asset Management, Inc. (since retirement or 2006); Director of Pioneer Alternative Investment removal. Management Limited (Dublin) (until October 2011); President and a director of Pioneer Alternative Investment Management (Bermuda) Limited and affiliated funds; Deputy Chairman and a director of Pioneer Global Asset Management S.p.A. ("PGAM") (until April 2010); Director of Nano-C, Inc. (since 2003); Director of Cole Management Inc. (2004 - 2011); Director of Fiduciary Counseling, Inc. (until December 2011); President of all of the Pioneer Funds; and Retired Partner, Wilmer Cutler Pickering Hale and Dorr LLP ------------------------------------------------------------------------------------------------------------------------------------ Daniel K. Kingsbury (54)* Trustee since 2007. Director, CEO and President of PIM-USA (since February None Trustee and Executive Vice Serves until a 2007); Director and President of Pioneer and Pioneer President successor trustee is Institutional Asset Management, Inc. (since February elected or earlier 2007); Executive Vice President of all of the Pioneer retirement or Funds (since March 2007); Director of PGAM (2007 - removal. 2010); Head of New Europe Division, PGAM (2000 - 2005); Head of New Markets Division, PGAM (2005 - 2007) ------------------------------------------------------------------------------------------------------------------------------------ * Mr. Cogan and Mr. Kingsbury are Interested Trustees because they are officers or directors of the Fund's investment adviser and certain of its affiliates. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 43 Fund Officers ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Officer ------------------------------------------------------------------------------------------------------------------------------------ Christopher J. Kelley (48) Since 2005. Serves at Vice President and Associate General Counsel of Pioneer None Secretary the discretion of the since January 2008 and Secretary of all of the Pioneer Board. Funds since June 2010; Assistant Secretary of all of the Pioneer Funds from September 2003 to May 2010; and Vice President and Senior Counsel of Pioneer from July 2002 to December 2007 ------------------------------------------------------------------------------------------------------------------------------------ Carol B. Hannigan (52) Since 2010. Serves at Fund Governance Director of Pioneer since December 2006 None Assistant Secretary the discretion of the and Assistant Secretary of all the Pioneer Funds since Board. June 2010; Manager - Fund Governance of Pioneer from December 2003 to November 2006; and Senior Paralegal of Pioneer from January 2000 to November 2003 ------------------------------------------------------------------------------------------------------------------------------------ Thomas Reyes (50) Since 2010. Serves at Counsel of Pioneer since June 2007 and Assistant None Assistant Secretary the discretion of the Secretary of all the Pioneer Funds since June 2010; and Board. Vice President and Counsel at State Street Bank from October 2004 to June 2007 ------------------------------------------------------------------------------------------------------------------------------------ Mark E. Bradley (53) Since 2008. Serves at Vice President - Fund Treasury of Pioneer; Treasurer of None Treasurer and Chief the discretion of the all of the Pioneer Funds since March 2008; Deputy Financial and Accounting Board. Treasurer of Pioneer from March 2004 to February 2008; Officer of the Fund and Assistant Treasurer of all of the Pioneer Funds from March 2004 to February 2008 ------------------------------------------------------------------------------------------------------------------------------------ Luis I. Presutti (48) Since 2005. Serves at Assistant Vice President - Fund Treasury of Pioneer; None Assistant Treasurer the discretion of the and Assistant Treasurer of all of the Pioneer Funds Board. ------------------------------------------------------------------------------------------------------------------------------------ Gary Sullivan (55) Since 2005. Serves at Fund Accounting Manager - Fund Treasury of Pioneer; and None Assistant Treasurer the discretion of the Assistant Treasurer of all of the Pioneer Funds Board. ------------------------------------------------------------------------------------------------------------------------------------ David F. Johnson (33) Since 2009. Serves at Fund Administration Manager - Fund Treasury of Pioneer None Assistant Treasurer the discretion of the since November 2008; Assistant Treasurer of all of the Board. Pioneer Funds since January 2009; and Client Service Manager - Institutional Investor Services at State Street Bank from March 2003 to March 2007 ------------------------------------------------------------------------------------------------------------------------------------ 44 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 ------------------------------------------------------------------------------------------------------------------------------------ Name, Age and Term of Office and Other Directorships Position Held with the Fund Length of Service Principal Occupation Held by Officer ------------------------------------------------------------------------------------------------------------------------------------ Jean M. Bradley (60) Since 2010. Serves at Chief Compliance Officer of Pioneer and of all the None Chief Compliance Officer the discretion of the Pioneer Funds since March 2010; Director of Adviser Board. and Portfolio Compliance at Pioneer since October 2005; and Senior Compliance Officer for Columbia Management Advisers, Inc. from October 2003 to October 2005 ------------------------------------------------------------------------------------------------------------------------------------ Kelley O'Donnell (42) Since 2006. Serves at Director-Transfer Agency Compliance of Pioneer and None Anti-Money Laundering the discretion of the Anti-Money Laundering Officer of all the Pioneer Funds Officer Board. since 2006 ------------------------------------------------------------------------------------------------------------------------------------ Pioneer High Income Municipal Fund | Annual Report | 8/31/13 45 This page for your notes. 46 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 This page for your notes. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 47 This page for your notes. 48 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 This page for your notes. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 49 This page for your notes. 50 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 This page for your notes. Pioneer High Income Municipal Fund | Annual Report | 8/31/13 51 This page for your notes. 52 Pioneer High Income Municipal Fund | Annual Report | 8/31/13 How to Contact Pioneer We are pleased to offer a variety of convenient ways for you to contact us for assistance or information. Call us for: -------------------------------------------------------------------------------- Account Information, including existing accounts, new accounts, prospectuses, applications and service forms 1-800-225-6292 FactFone(SM) for automated fund yields, prices, account information and transactions 1-800-225-4321 Retirement plans information 1-800-622-0176 Write to us: -------------------------------------------------------------------------------- PIMSS, Inc. P.O. Box 55014 Boston, Massachusetts 02205-5014 Our toll-free fax 1-800-225-4240 Our internet e-mail address ask.pioneer@pioneerinvestments.com (for general questions about Pioneer only) Visit our web site: us.pioneerinvestments.com This report must be preceded or accompanied by a prospectus. The Fund files a complete schedule of investments with the Securities and Exchange Commission for the first and third quarters for each fiscal year on Form N-Q. Shareholders may view the filed Form N-Q by visiting the Commission's web site at http://www.sec.gov. The filed form may also be viewed and copied at the Commission's Public Reference Room in Washington, DC. Information regarding the operations of the Public Reference Room may be obtained by calling 1-800-SEC-0330. [LOGO] PIONEER Investments(R) Pioneer Investment Management, Inc. 60 State Street Boston, MA 02109 us.pioneerinvestments.com Securities offered through Pioneer Funds Distributor, Inc. 60 State Street, Boston, MA 02109 Underwriter of Pioneer Mutual Funds, Member SIPC (C) 2013 Pioneer Investments 21203-06-1013 ITEM 2. CODE OF ETHICS. (a) Disclose whether, as of the end of the period covered by the report, the registrant has adopted a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party. If the registrant has not adopted such a code of ethics, explain why it has not done so. The registrant has adopted, as of the end of the period covered by this report, a code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer and controller. (b) For purposes of this Item, the term "code of ethics" means written standards that are reasonably designed to deter wrongdoing and to promote: (1) Honest and ethical conduct, including the ethical handling of actual or apparent conflicts of interest between personal and professional relationships; (2) Full, fair, accurate, timely, and understandable disclosure in reports and documents that a registrant files with, or submits to, the Commission and in other public communications made by the registrant; (3) Compliance with applicable governmental laws, rules, and regulations; (4) The prompt internal reporting of violations of the code to an appropriate person or persons identified in the code; and (5) Accountability for adherence to the code. (c) The registrant must briefly describe the nature of any amendment, during the period covered by the report, to a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item. The registrant must file a copy of any such amendment as an exhibit pursuant to Item 10(a), unless the registrant has elected to satisfy paragraph (f) of this Item by posting its code of ethics on its website pursuant to paragraph (f)(2) of this Item, or by undertaking to provide its code of ethics to any person without charge, upon request, pursuant to paragraph (f)(3) of this Item. The registrant has made no amendments to the code of ethics during the period covered by this report. (d) If the registrant has, during the period covered by the report, granted a waiver, including an implicit waiver, from a provision of the code of ethics to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions, regardless of whether these individuals are employed by the registrant or a third party, that relates to one or more of the items set forth in paragraph (b) of this Item, the registrant must briefly describe the nature of the waiver, the name of the person to whom the waiver was granted, and the date of the waiver. Not applicable. (e) If the registrant intends to satisfy the disclosure requirement under paragraph (c) or (d) of this Item regarding an amendment to, or a waiver from, a provision of its code of ethics that applies to the registrant's principal executive officer, principal financial officer, principal accounting officer or controller, or persons performing similar functions and that relates to any element of the code of ethics definition enumerated in paragraph (b) of this Item by posting such information on its Internet website, disclose the registrant's Internet address and such intention. Not applicable. (f) The registrant must: (1) File with the Commission, pursuant to Item 12(a)(1), a copy of its code of ethics that applies to the registrant's principal executive officer,principal financial officer, principal accounting officer or controller, or persons performing similar functions, as an exhibit to its annual report on this Form N-CSR (see attachment); (2) Post the text of such code of ethics on its Internet website and disclose, in its most recent report on this Form N-CSR, its Internet address and the fact that it has posted such code of ethics on its Internet website; or (3) Undertake in its most recent report on this Form N-CSR to provide to any person without charge, upon request, a copy of such code of ethics and explain the manner in which such request may be made. 	See Item 10(2) ITEM 3. AUDIT COMMITTEE FINANCIAL EXPERT. (a) (1) Disclose that the registrant's board of trustees has determined that the registrant either: (i) Has at least one audit committee financial expert serving on its audit committee; or (ii) Does not have an audit committee financial expert serving on its audit committee. The registrant's Board of Trustees has determined that the registrant has at least one audit committee financial expert. (2) If the registrant provides the disclosure required by paragraph (a)(1)(i) of this Item, it must disclose the name of the audit committee financial expert and whether that person is "independent." In order to be considered "independent" for purposes of this Item, a member of an audit committee may not, other than in his or her capacity as a member of the audit committee, the board of trustees, or any other board committee: (i) Accept directly or indirectly any consulting, advisory, or other compensatory fee from the issuer; or (ii) Be an "interested person" of the investment company as defined in Section 2(a)(19) of the Act (15 U.S.C. 80a-2(a)(19)). Ms. Marguerite A. Piret, an independent trustee, is such an audit committee financial expert. (3) If the registrant provides the disclosure required by paragraph (a)(1) (ii) of this Item, it must explain why it does not have an audit committee financial expert. Not applicable. ITEM 4. PRINCIPAL ACCOUNTANT FEES AND SERVICES. (a) Disclose, under the caption AUDIT FEES, the aggregate fees billed for each of the last two fiscal years for professional services rendered by the principal accountant for the audit of the registrant's annual financial statements or services that are normally provided by the accountant in connection with statutory and regulatory filings or engagements for those fiscal years. Pioneer Series Trust V: Fees for audit services provided to the Trust, including fees associated with the filings of its Form N-1A, totaled approximately $62,148in 2013 and approximately $119,982 in 2012. (b) Disclose, under the caption AUDIT-RELATED FEES, the aggregate fees billed in each of the last two fiscal years for assurance and related services by the principal accountant that are reasonably related to the performance of the audit of the registrant's financial statements and are not reported under paragraph (a) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Pioneer Series Trust V: Audit-Related Fees There were no audit-related services in 2013 or 2012. (c) Disclose, under the caption TAX FEES, the aggregate fees billed in each of the last two fiscal years for professional services rendered by the principal accountant for tax compliance, tax advice, and tax planning. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Pioneer Series Trust V: Fees for tax compliance services, primarily for tax returns, totaled $16,262in 2013 and $33,070 in 2012. (d) Disclose, under the caption ALL OTHER FEES, the aggregate fees billed in each of the last two fiscal years for products and services provided by the principal accountant, other than the services reported in paragraphs (a) through (c) of this Item. Registrants shall describe the nature of the services comprising the fees disclosed under this category. Pioneer Series Trust V: Other Fees There were no other services provided to the Trust during the fiscal years ended August 31, 2013 and 2012. (e) (1) Disclose the audit committee's pre-approval policies and procedures described in paragraph (c)(7) of Rule 2-01 of Regulation S-X. PIONEER FUNDS APPROVAL OF AUDIT, AUDIT-RELATED, TAX AND OTHER SERVICES PROVIDED BY THE INDEPENDENT AUDITOR SECTION I - POLICY PURPOSE AND APPLICABILITY The Pioneer Funds recognize the importance of maintaining the independence of their outside auditors. Maintaining independence is a shared responsibility involving Pioneer Investment Management, Inc ("PIM"), the audit committee and the independent auditors. The Funds recognize that a Fund's independent auditors: 1) possess knowledge of the Funds, 2) are able to incorporate certain services into the scope of the audit, thereby avoiding redundant work, cost and disruption of Fund personnel and processes, and 3) have expertise that has value to the Funds. As a result, there are situations where it is desirable to use the Fund's independent auditors for services in addition to the annual audit and where the potential for conflicts of interests are minimal. Consequently, this policy, which is intended to comply with Rule 210.2-01(C)(7), sets forth guidelines and procedures to be followed by the Funds when retaining the independent audit firm to perform audit, audit-related tax and other services under those circumstances, while also maintaining independence. Approval of a service in accordance with this policy for a Fund shall also constitute approval for any other Fund whose pre-approval is required pursuant to Rule 210.2-01(c)(7)(ii). In addition to the procedures set forth in this policy, any non-audit services that may be provided consistently with Rule 210.2-01 may be approved by the Audit Committee itself and any pre-approval that may be waived in accordance with Rule 210.2-01(c)(7)(i)(C) is hereby waived. Selection of a Fund's independent auditors and their compensation shall be determined by the Audit Committee and shall not be subject to this policy. SECTION II - POLICY ---------------- -------------------------------- ------------------------------------------------- SERVICE SERVICE CATEGORY DESCRIPTION SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES CATEGORY ---------------- -------------------------------- ------------------------------------------------- I. AUDIT Services that are directly o Accounting research assistance SERVICES related to performing the o SEC consultation, registration independent audit of the Funds statements, and reporting o Tax accrual related matters o Implementation of new accounting standards o Compliance letters (e.g. rating agency letters) o Regulatory reviews and assistance regarding financial matters o Semi-annual reviews (if requested) o Comfort letters for closed end offerings ---------------- -------------------------------- ------------------------------------------------- II. Services which are not o AICPA attest and agreed-upon procedures AUDIT-RELATED prohibited under Rule o Technology control assessments SERVICES 210.2-01(C)(4) (the "Rule") o Financial reporting control assessments and are related extensions of o Enterprise security architecture the audit services support the assessment audit, or use the knowledge/expertise gained from the audit procedures as a foundation to complete the project. In most cases, if the Audit-Related Services are not performed by the Audit firm, the scope of the Audit Services would likely increase. The Services are typically well-defined and governed by accounting professional standards (AICPA, SEC, etc.) ---------------- -------------------------------- ------------------------------------------------- ------------------------------------- ------------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the audit period for all services and related fees pre-approved specific service reported at each regularly subcategories. Approval of the scheduled Audit Committee independent auditors as meeting. auditors for a Fund shall constitute pre approval for these services. ------------------------------------- ------------------------------------ o "One-time" pre-approval o A summary of all such for the fund fiscal year within services and related fees a specified dollar limit (including comparison to for all pre-approved specified dollar limits) specific service subcategories reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limit for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for Audit-Related Services not denoted as "pre-approved", or to add a specific service subcategory as "pre-approved" ------------------------------------- ------------------------------------ SECTION III - POLICY DETAIL, CONTINUED ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION ----------------------- --------------------------- ----------------------------------------------- III. TAX SERVICES Services which are not o Tax planning and support prohibited by the Rule, o Tax controversy assistance if an officer of the Fund o Tax compliance, tax returns, excise determines that using the tax returns and support Fund's auditor to provide o Tax opinions these services creates significant synergy in the form of efficiency, minimized disruption, or the ability to maintain a desired level of confidentiality. ----------------------- --------------------------- ----------------------------------------------- ------------------------------------- ------------------------- AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------- ------------------------- ------------------------------------- ------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year all such services and within a specified dollar limit related fees 				 (including comparison 			 to specified dollar 			 limits) reported 			 quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for tax services not denoted as pre-approved, or to add a specific service subcategory as "pre-approved" ------------------------------------- ------------------------- SECTION III - POLICY DETAIL, CONTINUED ----------------------- --------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PRE-APPROVED SERVICE SUBCATEGORIES DESCRIPTION ----------------------- --------------------------- ----------------------------------------------- IV. OTHER SERVICES Services which are not o Business Risk Management support prohibited by the Rule, o Other control and regulatory A. SYNERGISTIC, if an officer of the Fund compliance projects UNIQUE QUALIFICATIONS determines that using the Fund's auditor to provide these services creates significant synergy in the form of efficiency, minimized disruption, the ability to maintain a desired level of confidentiality, or where the Fund's auditors posses unique or superior qualifications to provide these services, resulting in superior value and results for the Fund. ----------------------- --------------------------- ----------------------------------------------- --------------------------------------- ------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------- -------------------------- o "One-time" pre-approval o A summary of for the fund fiscal year within all such services and a specified dollar limit related fees 			 (including comparison 			 to specified dollar 				 limits) reported quarterly. o Specific approval is needed to exceed the pre-approved dollar limits for these services (see general Audit Committee approval policy below for details on obtaining specific approvals) o Specific approval is needed to use the Fund's auditors for "Synergistic" or "Unique Qualifications" Other Services not denoted as pre-approved to the left, or to add a specific service subcategory as "pre-approved" ------------------------------------- -------------------------- SECTION III - POLICY DETAIL, CONTINUED ----------------------- ------------------------- ----------------------------------------------- SERVICE CATEGORY SERVICE CATEGORY SPECIFIC PROHIBITED SERVICE SUBCATEGORIES DESCRIPTION ----------------------- ------------------------- ----------------------------------------------- PROHIBITED SERVICES Services which result 1. Bookkeeping or other services in the auditors losing related to the accounting records or independence status financial statements of the audit under the Rule. client* 2. Financial information systems design and implementation* 3. Appraisal or valuation services, fairness* opinions, or contribution-in-kind reports 4. Actuarial services (i.e., setting actuarial reserves versus actuarial audit work)* 5. Internal audit outsourcing services* 6. Management functions or human resources 7. Broker or dealer, investment advisor, or investment banking services 8. Legal services and expert services unrelated to the audit 9. Any other service that the Public Company Accounting Oversight Board determines, by regulation, is impermissible ----------------------- ------------------------- ----------------------------------------------- ------------------------------------------- ------------------------------ AUDIT COMMITTEE APPROVAL POLICY AUDIT COMMITTEE REPORTING POLICY ------------------------------------------- ------------------------------ o These services are not to be o A summary of all performed with the exception of the(*) services and related services that may be permitted fees reported at each if they would not be subject to audit regularly scheduled procedures at the audit client (as Audit Committee meeting defined in rule 2-01(f)(4)) level will serve as continual the firm providing the service. confirmation that has 				 not provided any restricted services. ------------------------------------------- ------------------------------ -------------------------------------------------------------------------------- GENERAL AUDIT COMMITTEE APPROVAL POLICY: o For all projects, the officers of the Funds and the Fund's auditors will each make an assessment to determine that any proposed projects will not impair independence. o Potential services will be classified into the four non-restricted service categories and the "Approval of Audit, Audit-Related, Tax and Other Services" Policy above will be applied. Any services outside the specific pre-approved service subcategories set forth above must be specifically approved by the Audit Committee. o At least quarterly, the Audit Committee shall review a report summarizing the services by service category, including fees, provided by the Audit firm as set forth in the above policy. -------------------------------------------------------------------------------- (2) Disclose the percentage of services described in each of paragraphs (b) through (d) of this Item that were approved by the audit committee pursuant to paragraph (c)(7)(i)(C) of Rule 2-01 of Regulation S-X. Non-Audit Services Beginning with non-audit service contracts entered into on or after May 6, 2003, the effective date of the new SEC pre-approval rules, the Fund's audit committee is required to pre-approve services to affiliates defined by SEC rules to the extent that the services are determined to have a direct impact on the operations or financial reporting of the Trust. For the years ended August 31, 2013 and 2012, there were no services provided to an affiliate that required the Fund's audit committee pre-approval. (f) If greater than 50 percent, disclose the percentage of hours expended on the principal accountants engagement to audit the registrant's financial statements for the most recent fiscal year that were attributed to work performed by persons other than the principal accountant's full-time, permanent employees. N/A (g) Disclose the aggregate non-audit fees billed by the registrants accountant for services rendered to the registrant, and rendered to the registrants investment adviser (not including any sub-adviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the adviser that provides ongoing services to the registrant for each of the last two fiscal years of the registrant. The aggregate non-audit fees for the Trust and affiliates, as previously defined, totaled approximately $16,262 in 2013 and $33,070 in 2012. (h) Disclose whether the registrants audit committee of the board of trustees has considered whether the provision of non-audit services that were rendered to the registrants investment adviser (not including any subadviser whose role is primarily portfolio management and is subcontracted with or overseen by another investment adviser), and any entity controlling, controlled by, or under common control with the investment adviser that provides ongoing services to the registrant that were not pre-approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. The Trust's audit committee of the Board of Trustees has considered whether the provision of non-audit services that were rendered to the Affiliates (as defined) that were not pre- approved pursuant to paragraph (c)(7)(ii) of Rule 2-01 of Regulation S-X is compatible with maintaining the principal accountant's independence. ITEM 5. AUDIT COMMITTEE OF LISTED REGISTRANTS (a) If the registrant is a listed issuer as defined in Rule 10A-3 under the Exchange Act (17 CFR 240.10A-3), state whether or not the registrant has a separately-designated standing audit committee established in accordance with Section 3(a)(58)(A) of the Exchange Act (15 U.S.C. 78c(a)(58)(A)). If the registrant has such a committee, however designated, identify each committee member. If the entire board of directors is acting as the registrant's audit committee as specified in Section 3(a)(58)(B) of the Exchange Act (15 U.S.C. 78c(a)(58)(B)), so state. N/A (b) If applicable, provide the disclosure required by Rule 10A-3(d) under the Exchange Act (17 CFR 240.10A-3(d)) regarding an exemption from the listing standards for audit committees. N/A ITEM 6. SCHEDULE OF INVESTMENTS. File Schedule of Investments in securities of unaffiliated issuers as of the close of the reporting period as set forth in 210.1212 of Regulation S-X [17 CFR 210.12-12], unless the schedule is included as part of the report to shareholders filed under Item 1 of this Form. Included in Item 1 ITEM 7. DISCLOSURE OF PROXY VOTING POLICIES AND PROCEDURES FOR CLOSED-END MANAGEMENT INVESTMENT COMPANIES. A closed-end management investment company that is filing an annual report on this Form N-CSR must, unless it invests exclusively in non-voting securities, describe the policies and procedures that it uses to determine how to vote proxies relating to portfolio securities, including the procedures that the company uses when a vote presents a conflict between the interests of its shareholders, on the one hand, and those of the company's investment adviser; principal underwriter; or any affiliated person (as defined in Section 2(a)(3) of the Investment Company Act of 1940 (15 U.S.C. 80a-2(a)(3)) and the rules thereunder) of the company, its investment adviser, or its principal underwriter, on the other. Include any policies and procedures of the company's investment adviser, or any other third party, that the company uses, or that are used on the company's behalf, to determine how to vote proxies relating to portfolio securities. Not applicable to open-end management investment companies. ITEM 8. PORTFOLIO MANAGERS OF CLOSED-END MANAGEMENT INVESTMENT COMPANIES. (a) If the registrant is a closed-end management investment company that is filing an annual report on this Form N-CSR,provide the following information: (1) State the name, title, and length of service of the person or persons employed by or associated with the registrant or an investment adviser of the registrant who are primarily responsible for the day-to-day management of the registrant's portfolio ("Portfolio Manager"). Also state each Portfolio Manager's business experience during the past 5 years. Not applicable to open-end management investment companies. ITEM 9. PURCHASES OF EQUITY SECURITIES BY CLOSED-END MANAGEMENT INVESTMENT COMPANY AND AFFILIATED PURCHASERS. (a) If the registrant is a closed-end management investment company, in the following tabular format, provide the information specified in paragraph (b) of this Item with respect to any purchase made by or on behalf of the registrant or any affiliated purchaser, as defined in Rule 10b-18(a)(3) under the Exchange Act (17 CFR 240.10b-18(a)(3)), of shares or other units of any class of the registrant's equity securities that is registered by the registrant pursuant to Section 12 of the Exchange Act (15 U.S.C. 781). Not applicable to open-end management investment companies. ITEM 10. SUBMISSION OF MATTERS TO A VOTE OF SECURITY HOLDERS. Describe any material changes to the procedures by which shareholders may recommend nominees to the registrant's board of directors, where those changes were implemented after the registrant last provided disclosure in response to the requirements of Item 407(c)(2)(iv) of Regulation S-R(17 CFR 229.407)(as required by Item 22(b)(15)) of Schedule 14A (17 CFR 240.14a-101), or this Item. There have been no material changes to the procedures by which the shareholders may recommend nominees to the registrant's board of directors since the registrant last provided disclosure in response to the requirements of Item 407(c)(2)(iv) of Regulation S-R of Schedule 14(A) in its definitive proxy statement, or this item. ITEM 11. CONTROLS AND PROCEDURES. (a) Disclose the conclusions of the registrant's principal executive and principal financials officers, or persons performing similar functions, regarding the effectiveness of the registrant's disclosure controls and procedures (as defined in Rule 30a-3(c) under the Act (17 CFR 270.30a-3(c))) as of a date within 90 days of the filing date of the report that includes the disclosure required by this paragraph, based on the evaluation of these controls and procedures required by Rule 30a-3(b) under the Act (17 CFR 270.30(a)-3(b) and Rules 13a-15(b) or 15d-15(b) under the Exchange Act (17 CFR 240.13a-15(b) or 240.15d-15(b)). The registrant's principal executive officer and principal financial officer have concluded that the registrant's disclosure controls and procedures are effective based on the evaluation of these controls and procedures as of a date within 90 days of the filing date of this report. (b) Disclose any change in the registrant's internal control over financial reporting (as defined in Rule 30a-3(d) under the Act (17CFR 270.30a-3(d)) that occured during the second fiscal quarter of the period covered by this report that has materially affected, or is reasonably likely to materially affect, the registrant's internal control over financial reporting. There were no significant changes in the registrant's internal control over financial reporting that occurred during the second fiscal quarter of the period covered by this report that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting. The registrant's principal executive officer and principal financial officer, however, voluntarily are reporting the following information: In August of 2006 the registrant's investment adviser enhanced its internal procedures for reporting performance information required to be included in prospectuses. Those enhancements involved additional internal controls over the appropriateness of performance data generated for this purpose. Such enhancements were made following an internal review which identified prospectuses relating to certain classes of shares of a limited number of registrants where, inadvertently, performance information not reflecting the deduction of applicable sales charges was included. Those prospectuses were revised, and the revised prospectuses were distributed to shareholders. ITEM 12. EXHIBITS. (a) File the exhibits listed below as part of this Form. Letter or number the exhibits in the sequence indicated. (1) Any code of ethics, or amendment thereto, that is the subject of the disclosure required by Item 2, to the extent that the registrant intends to satisfy the Item 2 requirements through filing of an exhibit. (2) A separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2(a) under the Act (17 CFR 270.30a-2(a)) , exactly as set forth below: Filed herewith. SIGNATURES [See General Instruction F] Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized. (Registrant) Pioneer Series Trust V By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr, President Date October 30, 2013 Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated. By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr., President Date October 30, 2013 By (Signature and Title)* /s/ Mark Bradley Mark Bradley, Treasurer & Chief Accounting & Financial Officer Date October 30, 2013 * Print the name and title of each signing officer under his or her signature.